β-NaYF4:Yb3+/Er3+@β-NaYF4:Yb3+的上转换发光特性

相国涛; 刘小桐; 夏清; 江莎; 唐笑; 李丽; 周贤菊

doi:10.3788/fgxb20204106.0679

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β-NaYF₄:Yb³⁺/Er³⁺@β-NaYF₄:Yb³⁺的上转换发光特性

材料合成及性能 | 更新时间：2020-09-15

- β-NaYF₄:Yb³⁺/Er³⁺@β-NaYF₄:Yb³⁺的上转换发光特性
- Upconversion Luminescence Properties of β-NaYF₄:Yb³⁺/Er³⁺@β-NaYF₄:Yb³⁺
- 发光学报 2020年41卷第6期页码：679-683
- 作者机构：
  
  重庆邮电大学理学院, 重庆 400065
- 作者简介：
  
  [ "相国涛(1988－)，男，黑龙江佳木斯人，博士，副教授，2016年于中国科学院大学获得博士学位，主要从事稀土上转换发光材料的研究。E-mail: xianggt@cqupt.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(11704054);重庆市教委科学技术研究项目(KJZD-K201800602)
- DOI：10.3788/fgxb20204106.0679
  中图分类号： O482.31
- 纸质出版日期：2020-6，
  
  收稿日期：2020-4-8，
  
  录用日期：2020-4-16
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相国涛, 刘小桐, 夏清, 等. β-NaYF₄:Yb³⁺/Er³⁺@β-NaYF₄:Yb³⁺的上转换发光特性[J]. 发光学报, 2020,41(6):679-683.

Guo-tao XIANG, Xiao-tong LIU, Qing XIA, et al. Upconversion Luminescence Properties of β-NaYF₄:Yb³⁺/Er³⁺@β-NaYF₄:Yb³⁺[J]. Chinese Journal of Luminescence, 2020,41(6):679-683.
相国涛, 刘小桐, 夏清, 等. β-NaYF₄:Yb³⁺/Er³⁺@β-NaYF₄:Yb³⁺的上转换发光特性[J]. 发光学报, 2020,41(6):679-683. DOI： 10.3788/fgxb20204106.0679.

Guo-tao XIANG, Xiao-tong LIU, Qing XIA, et al. Upconversion Luminescence Properties of β-NaYF₄:Yb³⁺/Er³⁺@β-NaYF₄:Yb³⁺[J]. Chinese Journal of Luminescence, 2020,41(6):679-683. DOI： 10.3788/fgxb20204106.0679.

摘要

利用溶剂热法制备了β-NaYF

：20%Yb

/2%Er

核颗粒和β-NaYF

：20%Yb

/2%Er

@β-NaYF

：

%Yb

（

=0，20，50，70，100）核壳结构纳米颗粒。在未包覆β-NaYF

前，核纳米颗粒的尺寸约为30 nm；在包覆β-NaYF

壳层后，纳米颗粒的尺寸增加至40 nm左右，并且上转换绿光和红光分别提高了14倍和25倍。上转换发光强度能够增强如此之多是因为包覆的壳层有效地抑制了处于激发态的Yb

与纳米颗粒表面缺陷之间的能量传递过程。随着壳层中Yb

掺杂浓度的提高，纳米颗粒的尺寸并未发生明显变化，一直保持在40 nm左右。但是，纳米颗粒的上转换发光强度却随着Yb

浓度的提高而明显减弱。由于在980 nm波长的激光辐照时，大部分980 nm的光子会被纳米颗粒壳层中的Yb

所吸收，能够被核中的Yb

所吸收的980 nm光子数目非常少。然而，由于壳层中的Yb

距离核颗粒中的Er

较远，使得二者之间的能量传递效率非常低，从而大大降低了纳米颗粒的上转换发光强度。

Abstract

In this work

a solvothermal process was used to synthesize the β-NaYF

:20%Yb

/2%Er

core nanoparticles(NPs) and β-NaYF

:20%Yb

/2%Er

@β-NaYF

%Yb

(

100) core-shell NPs. The size of the core NPs and core-shell NPs is about 30 nm and 40 nm respectively

implying that the thickness of the layer is 5 nm. After coating a β-NaYF

shell without Yb

doping

the upconversion(UC) intensity is increased with a factor of 14 and 25 for green emission and red emission respectively

resulting from the suppression of deexcitation of Yb

ions by the core-shell structure. However

the UC intensity is decreased dramatically with the increasing Yb

ions concentration in the shell

due to the inefficient energy transfer process between the Yb

ions in the shell and the Er

ions in the core caused by the large distance between them. As the β-NaYF

shell completely converts to β-NaYbF

the UC intensity decreased 98.8% and 99.4% for green and red emission

respectively.

关键词

稀土离子上转换发光能量传递β-NaYF4

Keywords

rare earthupconversionenergy transferβ-NaYF4

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