应用于钙钛矿太阳能电池中金属氧化物电子传输材料的研究进展

朱立华; 商雪妮; 雷凯翔; 郑士建; 戴其林; 陈聪; 宋宏伟

doi:10.3788/fgxb20204105.0481

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应用于钙钛矿太阳能电池中金属氧化物电子传输材料的研究进展

特邀综述 | 更新时间：2020-09-21

- 应用于钙钛矿太阳能电池中金属氧化物电子传输材料的研究进展
- Research Progress of Metal Oxide Electron Transporting Materials Applied in Perovskite Solar Cells
- 发光学报 2020年41卷第5期页码：481-497
- 作者机构：
  
  1.河北工业大学材料科学与工程学院, 天津 300130
  2.Department of Chemistry, Physics and Atmospheric Sciences, Jackson State University, Jackson, Mississippi, MS 39217, USA
  3.吉林大学电子科学与工程学院集成光电子学国家重点联合实验室, 吉林长春 130012
- 作者简介：
  
  [ "朱立华(1994-)，男，河北秦皇岛人，硕士研究生，2018年于河北建筑工程学院获得学士学位，主要从事钙钛矿太阳能电池中新型电子传输材料的开发与研究。E-mail: E-mail:ZHULIHUA94@163.com" ]
  [ "陈聪(1990-)，男，吉林长春人，博士，副教授，2019年于吉林大学获得博士学位，主要从事高效与长时稳定的钙钛矿太阳能电池的研究。E-mail:chencong@hebut.edu.cn" ]
  [ "宋宏伟(1967-), 男，黑龙江阿城人，博士，教授，博士研究生导师，1996年于中国科学院长春物理研究所获得博士学位，主要从事稀土发光材料物理、光电子及生物应用的研究。E-mail:songhw@jlu.edu.cn " ]
- 基金信息：
  
  国家重点研发计划(2016YFC0207101);国家自然科学基金(51771201)
- DOI：10.3788/fgxb20204105.0481
  中图分类号： TM914.4
- 收稿：2020-03-01，
  
  修回：2020-4-2，
  
  录用：2020-4-2，
  
  纸质出版：2020-05
- 稿件说明：
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朱立华, 商雪妮, 雷凯翔, 等. 应用于钙钛矿太阳能电池中金属氧化物电子传输材料的研究进展[J]. 发光学报, 2020,41(5):481-497.

Li-hua ZHU, Xue-ni SHANG, Kai-xiang LEI, et al. Research Progress of Metal Oxide Electron Transporting Materials Applied in Perovskite Solar Cells[J]. Chinese Journal of Luminescence, 2020, 41(5): 481-497.
朱立华, 商雪妮, 雷凯翔, 等. 应用于钙钛矿太阳能电池中金属氧化物电子传输材料的研究进展[J]. 发光学报, 2020,41(5):481-497. DOI： 10.3788/fgxb20204105.0481.

Li-hua ZHU, Xue-ni SHANG, Kai-xiang LEI, et al. Research Progress of Metal Oxide Electron Transporting Materials Applied in Perovskite Solar Cells[J]. Chinese Journal of Luminescence, 2020, 41(5): 481-497. DOI： 10.3788/fgxb20204105.0481.

摘要

基于有机金属卤化铅钙钛矿材料作为光活性层的太阳能电池（PSCs）已经获得了25.2%的认证效率，是除硅基太阳能电池外被认为最有可能实现商业化的太阳能电池之一。电子传输层是PSCs器件结构的最基本组成之一，其构成材料与光活性层的成膜质量、界面电荷的快速提取以及能级匹配等密切相关。因而，电子传输材料在PSCs的光伏性能及稳定性调控方面发挥着重要作用。本文对应用在PSCs中的金属氧化物电子传输材料进行了回顾与总结，着重强调了材料的纳米结构与制备工艺、半导体特性与分类以及掺杂与界面修饰等方面的研究进展，并对其今后的发展进行了展望。

Abstract

Perovskite solar cells (PSCs) based on organic metal halide perovskite materials as photoactive layer have been obtained a certified power conversion efficiency of 25.2% and are considered to be one of the most commercially viable solar cells. In the device structure of PSCs

the electron transporting layer is one of the most basic components. The selection of the electron transporting materials is closely related to the film quality of the photoactive layer

the rapid extraction of interface charge and the matching of bandgaps. Therefore

the electron transporting materials play an important role in the regulating the photovoltaic performance and stability of PSCs. This paper reviews and summarizes the research progress of metal oxide electron transporting materials applied in PSCs

emphasizes the nanostructure and preparation process

photoelectric characteristics and classification

doping and surface modification of metal oxide electron transport materials

and looks forward to its future development.

关键词

Keywords

references

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