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绍兴文理学院 电子工程系,浙江 绍兴,312000
纸质出版日期:2020-3-5,
网络出版日期:2019-11-19,
收稿日期:2019-10-17,
修回日期:2019-11-12,
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王浩楠, 岳小峰, 徐海洋等. 电极肖特基接触对有机光敏晶体管性能的影响[J]. 发光学报, 2020,41(3): 316-322
WANG Hao-nan, YUE Xiao-feng, XU Hai-yang etc. Influence of Electrode Schottky-contacts on Performance of Organic Phototransistor[J]. Chinese Journal of Luminescence, 2020,41(3): 316-322
王浩楠, 岳小峰, 徐海洋等. 电极肖特基接触对有机光敏晶体管性能的影响[J]. 发光学报, 2020,41(3): 316-322 DOI: 10.3788/fgxb20204103.0316.
WANG Hao-nan, YUE Xiao-feng, XU Hai-yang etc. Influence of Electrode Schottky-contacts on Performance of Organic Phototransistor[J]. Chinese Journal of Luminescence, 2020,41(3): 316-322 DOI: 10.3788/fgxb20204103.0316.
有机光敏晶体管是一种在有机场效应管结构中引入光控"栅极"的新型光探测器件,其光灵敏度、光响应度性能参数与源/漏电极和有源层的接触情况关系密切。本文通过真空蒸发法分别制备了采用金电极和铝电极的单层并五苯及酞菁铜有机光敏晶体管。研究了它们在黑暗和光照条件下的输出及转移特性。结果表明,高迁移率的并五苯有源层更适合搭配接触特性较好的金电极,该器件具有和铝电极器件相同高水平的光灵敏度~310
4
,但其光响应度是铝电极器件的13倍;而低迁移率的酞菁铜薄膜较适合搭配能够和有源层形成肖特基接触的铝电极,有利于抑制暗电流、增强激子解离效率、提高光电流,进一步使器件在获得和金电极器件同数量级光响应度的同时,其光灵敏度是金电极器件的10
2
倍。本文对光照下电极/有源层肖特基接触的能带变化做了理论分析,总结归纳了有机光敏晶体管电极材料和有源层材料的初步筛选规律。
Organic phototransistor(OPT) is made by introducing a light-controlled gate into the structure of an organic field-effect transistor(OFET)
which is a new type of photodetector. The performance parameters of OPTs
including photosensitivity(
P
) and photoresponsivity(
R
)
are closely related to the contact between source/drain electrodes and the active layer. In this paper
a single layer of pentacene and CuPc based OPT with Au and Al electrodes were prepared by vacuum evaporation respectively. Their output and transfer characteristics in dark and under illumination were studied. The results showed that Au electrodes were more suitable for high mobility pentacene active layer with better contact characteristics. The pentacene-based OPT with Au electrodes gained the same level of
P
as that with Al electrodes at around 310
4
but the
R
of the former was 13 times higher than that of the latter. While for low mobility CuPc-based OPT
Schottky contact was formed between the Al electrode and the active layer
which was beneficial for suppressing dark current
enhancing exciton dissociation efficiency and improving photocurrent. Furthermore
the CuPc-based OPT with Al electrode obtained the same order of magnitude
R
as the device with Au electrode
but the
P
of the former was 10
2
times higher than the latter. The energy band variations of the electrodes/active layer Schottky contacts under illumination were discussed in this paper. And the preliminary screening rules of the electrode materials and active layer materials for OPTs were summarized.
有机光敏晶体管光灵敏度光响应度肖特基接触
organic phototransistorphotosensitivityphotoresponsivitySchottky contact
LI J,SHI W,SHU L F,et al.. Performance enhancement of p-type organic field-effect transistor through introducing organic buffer layers[J]. J. Mater. Sci. Mater. Electron., 2015,26(11):8301-8306.
GNTHER A A,SAWATZKI M,FORMNEK P,et al.. Contact doping for vertical organic field-effect transistors[J]. Adv. Funct. Mater., 2016,26(5):768-775.
WU X H,MAO S,CHEN J H,et al.. Strategies for improving the performance of sensors based on organic field-effect transistors[J]. Adv. Mater., 2018,30(17):1705642-1-7.
LIU K,GUO Y L,LIU Y Q. Recent progress in stretchable organic field-effect transistors[J]. Sci. China Technol. Sci., 2019,62(8):1255-1276.
杨丹,张丽,杨盛谊,等. 基于垂直晶体管结构的低电压并五苯光电探测器[J]. 物理学报, 2015,64(10):108503-1-6. YANG D,ZHANG L,YANG S Y,et al.. Low-voltage pentacene photodetector based on a vertical transistor configuration[J]. Acta Phys. Sinica, 2015,64(10):108503-1-6. (in Chinese)
SMITHSON C S,WU Y L,WIGGLESWORTH T,et al.. A more than six orders of magnitude UV-responsive organic field-effect transistor utilizing a benzothiophene semiconductor and Disperse Red 1 for enhanced charge separation[J]. Adv. Mater., 2015,27(2):228-233.
郑亚开,韦一,孙磊,等. 衬底温度对TiOPc光敏有机场效应管的影响[J]. 发光学报, 2016,37(6):725-730. ZHENG Y K,WEI Y,SUN L,et al.. Substrate temperature dependent performance of photoresponsive organic field effect transistors based on titanyl-phthalocyanine[J]. Chin. J. Lumin., 2016,37(6):725-730. (in Chinese)
WANG X H,ZHAO F S,XUE Z,et al.. Highly sensitive polymer phototransistor based on the synergistic effect of chemical and physical blending in D (Donor)-A (Acceptor) copolymers[J]. Adv. Electron. Mater., 2019,5(6):1900174.
PENG Y Q,HUANG F B,ZHANG J P,et al.. Broad spectral response photosensitive organic field-effect transistors realized by the hybrid planar-bulk heterojunction composed of three molecules with complementary optical absorption[J]. Org. Electron., 2017,43:27-32.
LEE M Y,HONG J,LEE E K,et al.. Highly flexible organic nanofiber phototransistors fabricated on a textile composite for wearable photosensors[J]. Adv. Funct. Mater., 2016,26(9):1445-1453.
DU L L,LUO X,ZHAO F Y,et al.. Toward facile broadband high photoresponse of fullerene based phototransistor from the ultraviolet to the near-infrared region[J]. Carbon, 2016,96:685-694.
TANG L L,PENG Y Z,ZHOU Z,et al.. High-performance organic-inorganic hybrid perovskite thin-film field-effect transistors[J]. Appl. Phys. A, 2018,124:624-1-7.
JEONG J,NAM S,KIM H,et al.. Inverted organic photodetectors with ZnO electron-collecting buffer layers and polymer bulk heterojunction active layers[J]. IEEE J. Sel. Top. Quant. Electron., 2014,20(6):3805207-1-7.
YAO B,LI Y L,WEN Z W,et al.. Correlating optimal electrode buffer layer thickness with the surface roughness of the active layer in organic phototransistors[J]. Synth. Met., 2014,193:35-40.
PENG Y Q,LV W L,YAO B,et al.. Improved performance of photosensitive field-effect transistors based on palladium phthalocyanine by utilizing Al as source and drain electrodes[J]. IEEE Trans. Electron Devices, 2013,60(3):1208-1212.
LEE C T,LIN Y M. Performance improvement mechanisms of pentacene-based organic thin-film transistors using TPD buffer layer[J]. Org. Electron., 2013,14(8):1952-1957.
SIRRINGHAUS H. 25th anniversary article:organic field-effect transistors:the path beyond amorphous silicon[J]. Adv. Mater., 2014,26(9):1319-1335.
FROLOVA L A,REZVANOVA A A,SHIRINIAN V Z,et al.. OFET-Based memory devices operating via optically and electrically modulated charge separation between the semiconductor and 1,2-bis (Hetaryl) ethene dielectric layers[J]. Adv. Electron. Mater., 2016,2(3):1500219-1-6.
SARANYA G,NAIR S,NATARAJAN V,et al.. A theoretical study of structural and electronic properties of pentacene/Al(100) interface[J]. J. Mol. Graph. Model., 2012,38:334-341.
DAO T T,MATSUSHIMA T,FRIEDLEIN R,et al.. Controllable threshold voltage of a pentacene field-effect transistor based on a double-dielectric structure[J]. Org. Electron., 2013,14(8):2007-2013.
PENG Y Q,LV W L,YAO B,et al.. High performance near infrared photosensitive organic field-effect transistors realized by an organic hybrid planar-bulk heterojunction[J]. Org. Electron., 2013,14(4):1045-1051.
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