CaLuBO4:Tb3+荧光粉的制备及发光性质

孙晓园; 范小暄; 何俊杰; 吕启松; 姜光远; 邓昀; 骆永石; 吴春雷

doi:10.3788/fgxb20204103.0265

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CaLuBO₄:Tb³⁺荧光粉的制备及发光性质

材料合成及性能 | 更新时间：2020-08-12

- CaLuBO₄:Tb³⁺荧光粉的制备及发光性质
- Preparation and Photoluminescence Properties of CaLuBO₄: Tb³⁺ Phosphor
- 发光学报 2020年41卷第3期页码：265-270
- 作者机构：
  
  1. 长春师范大学物理学院,吉林长春,130032
  2. 中国科学院长春光学精密机械与物理研究所发光学及应用国家重点实验室, 吉林长春 130033
  3. 牡丹江师范学院理学院, 黑龙江牡丹江 157012
- 作者简介：
- 基金信息：
  
  长春师范学院自然科学基金（[2015]006）资助项目()
- DOI：10.3788/fgxb20204103.0265
  中图分类号： O482.31
- 纸质出版日期：2020-3-5，
  
  网络出版日期：2019-12-30，
  
  收稿日期：2019-12-17，
  
  修回日期：2019-12-29，
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孙晓园, 范小暄, 何俊杰等. CaLuBO4:Tb3+荧光粉的制备及发光性质[J]. 发光学报, 2020,41(3): 265-270

SUN Xiao-yuan, FAN Xiao-xuan, HE Jun-jie etc. Preparation and Photoluminescence Properties of CaLuBO4: Tb3+ Phosphor[J]. Chinese Journal of Luminescence, 2020,41(3): 265-270
孙晓园, 范小暄, 何俊杰等. CaLuBO4:Tb3+荧光粉的制备及发光性质[J]. 发光学报, 2020,41(3): 265-270 DOI： 10.3788/fgxb20204103.0265.

SUN Xiao-yuan, FAN Xiao-xuan, HE Jun-jie etc. Preparation and Photoluminescence Properties of CaLuBO4: Tb3+ Phosphor[J]. Chinese Journal of Luminescence, 2020,41(3): 265-270 DOI： 10.3788/fgxb20204103.0265.

摘要

采用高温固相反应法合成了不同Tb

掺杂浓度的CaLuBO

荧光粉，研究了样品的晶体结构和发光性质。在紫外光激发下，样品的发射光谱由Tb

离子的

（

=6，5，4）和

（

'=6，5，4，3）特征发射组成，其中位于545 nm和554 nm附近的

跃迁发射强度最大。荧光粉的激发光谱是由位于紫外区的Tb

的4f-5d和f-f跃迁构成的。研究了Tb

浓度对样品发光性质的影响。测量并分析了CaLuBO

荧光粉的

能级和

能级荧光寿命。结果表明，CaLuBO

是一种适于紫外激发的新型黄绿光荧光粉。

Abstract

The phosphors CaLuBO

were synthesized through the solid-state reaction technique. The structure

photoluminescence properties of these phosphors were described. Upon excitation with UV light excitation

the photoluminescence emission spectra could be assigned to the transitions of Tb

from

(

4) and

(

'=6

3). The two strong emissions peaked at 545 nm and 554 nm

which arose from the

of Tb

respectively. The photoluminescence excitation spectra show a broad 4f-5d band and f

f transitions in UV region. The dependence of photoluminescence intensities on Tb

concentration was studied. The luminescence lifetimes of

and

energy level were measured and analysed

respectively. The CaLuBO

phosphor is a novel yellow-green emitting phosphor suitable for ultraviolet light excitation.

关键词

荧光粉光致发光荧光寿命

Keywords

phosphorphotoluminescencefluorescence lifetime

references

张亮亮,张家骅,郝振东,等. Cr3+掺杂的宽带近红外荧光粉及其研究进展[J]. 发光学报, 2019,40(12):1449-1459. ZHANG L L,ZHANG J H,HAO Z D,et al.. Recent progress on Cr3+ doped broad band NIR phosphors[J]. Chin. J. Lumin., 2019,40(12):1449-1459. (in Chinese)

刘行仁. CRT、VFD及FED显示器用的荧光粉的进展[J]. 液晶与显示, 1996,11(1):61-68. LIU X R. Progress of the phosphors for CRT、VFD and FED displays[J]. Chin. J. Liq. Cryst. Disp., 1996,11(1):61-68. (in Chinese)

ZHANG C H,LIU Y F,ZHANG J H,et al.. A single-phase Ba9Lu2Si6O24:Eu2+,Ce3+,Mn2+ phosphor with tunable full-color emission for NUV-based white LED applications[J]. Mater. Res. Bull., 2016,80:288-294.

王巍,李一,宁平凡,等. 广色域钙钛矿量子点/荧光粉转换白光LED[J]. 发光学报, 2018,39(5):627-632. WANG W,LI Y,NING P F,et al.. Perovskite quantum dot/powder phosphor converted white light LEDs with wide color gamut[J]. Chin. J. Lumin., 2018,39(5):627-632. (in Chinese)

王娟娟,袁曦明,李予晋,等. 共沉淀法制备PDP用红色荧光粉(Y,Gd)BO3:Eu3+的正交实验研究[J]. 液晶与显示, 2009,24(5):645-649. WANG J J,YUAN X M,LI Y J,et al.. Preparation of red phosphor (Y,Gd)BO3:Eu3+ by coprecipitation method with orthogonal test[J]. Chin. J. Liq. Cryst. Disp., 2009,24(5):645-649. (in Chinese)

付作岭,董晓睿,盛天琦,等. 纳米晶体中稀土离子的发光性质及其变化机理研究[J]. 中国光学, 2015,8(1):139-146. FU Z L,DONG X R,SHENG T Q,et al.. Luminescene properties and various mechanisms of rare earth ions in the nanocrystals[J]. Chin. Opt., 2015,8(1):139-146. (in Chinese)

NAIR G B,DHOBLE S J. Assessment of electron-vibrational interaction (EVI) parameters of YAG:Ce3+,TAG:Ce3+ and LuAG:Ce3+ garnet phosphors by spectrum fitting method[J]. Spectrochim. Acta Part A:Mol. Biomol. Spectrosc., 2017,173:822-826.

徐文,陈旭,宋宏伟. 稀土离子上转换发光中的局域电磁场调控[J]. 发光学报, 2018,39(1):1-26. XU W,CHEN X,SONG H W. Manipulation of local electromagnetic field in upconversion luminescence of rare earth ions[J]. Chin. J. Lumin., 2018,39(1):1-26. (in Chinese)

周青超,柏泽龙,鲁路,等. 白光LED远程荧光粉技术研究进展与展望[J]. 中国光学, 2015,8(3):313-328. ZHOU Q C,BAI Z L,LU L,et al.. Remote phosphor technology for white LED applications:advances and prospects[J]. Chin. Opt., 2015,8(3):313-328. (in Chinese)

洪广言. 稀土发光材料[M]. 北京:科学出版社, 2011:6-8. HONG G Y. Fundamental and Application of Rare Earth Luminescent Materials[M]. Beijing:Science Press, 2011:6-8. (in Chinese)

HAO Z D,ZHANG J H,ZHANG X,et al.. An intense blue-emitting phosphor for near-ultraviolet pumped white-light-emitting diodes:Ce3+-activated -Ca2SiO4[J]. J. Lumin., 2014,152:40-43.

唐靓,叶慧琪,肖东. 溶胶-凝胶法制备YAG:Ce,Yb纳米荧光粉及其发光性质研究[J]. 发光学报, 2018,39(8):1051-1058. TANG L,YE H Q,XIAO D. YAG:Ce,Yb nano-phosphor synthesized by sol-gel method and its luminescence properties[J]. Chin. J. Lumin., 2018,39(8):1051-1058. (in Chinese)

ZHANG L L,ZHANG J H,ZHANG X,et al.. Site distortion in Li2SrSiO4:influence on Pr3+ emission and application in wLED[J]. J. Lumin., 2016,180:158-162.

闫宏,宋婷,张猛,等. 高性能X射线影像存储12CaO7Al2O3:Pr3+荧光粉的微结构及光学特性[J]. 发光学报, 2018,39(7):895-902. YAN H,SONG T,ZHANG M,et al.. Microstructure and optical properties of 12CaO7Al2O3:Pr3+ phosphors for high quality X-ray imaging[J]. Chin. J. Lumin., 2018,39(7):895-902. (in Chinese)

WANG B H,WANG Z H,LIU Y G,et al.. Crystal structure tailoring and luminescence tuning of Sr1-xBaxAl2Si2O8:Eu2+ phosphors for white-light-emitting diodes[J]. J. Alloys Compd., 2019,776:554-559.

ZHANG Y J,ZHANG H,DONG P P,et al.. Synthesis,structure and photoluminescence properties of (Sr,Ca)AlSiN3:Eu2+ phosphor for white light emitting diodes with controllable optical performance[J]. J. Mater. Sci.:Mater. Electron., 2017,28(1):86-93.

ZHONG J S,CHEN D Q,YUAN Y J,et al.. Synthesis and spectroscopic investigation of Ba3La6(SiO4)6:Eu2+ green phosphors for white light-emitting diodes[J]. Chem. Eng. J., 2017,309:795-801.

LI J,CHEN L,ZHANG J H,et al.. Photoluminescence properties of a novel red-emitting phosphor Eu3+ activated scandium molybdate for white light emitting diodes[J]. Mater. Res. Bull., 2016,83:290-293.

HUANG C H,CHEN C T,GUO S Q,et al.. Luminescence and theoretical calculations of novel red-emitting NaYPO4F:Eu3+ phosphor for LED applications[J]. J. Alloys Compd., 2017,712:225-232.

ZHOU L Y,HUANG J L,YI L H,et al.. Luminescent properties of Ba3Gd(BO3)3:Eu3+ phosphor for white LED applications[J]. J. Rare Earths, 2009,27(1):54-57.

孙雷,张毅,胡兴凯,等. LED用KZn4(BO3)3:Eu3+荧光粉的合成与发光性能研究[J]. 液晶与显示, 2014,29(6):893-900. SUN L,ZHANG Y,HU X K,et al.. Synthesis and photoluminescence properties of KZn4(BO3)3:Eu3+ red-emitting phosphor[J]. Chin. J. Liq. Cryst. Disp., 2014,29(6):893-900. (in Chinese)

张家骅,吕伟,郝振东,等. 利用能量传递实现可调全色单一白光BaMg2Al6Si9O30:Eu2+,Tb3+,Mn2+荧光粉(特邀)[J]. 中国光学, 2012,5(3):203-208. ZHANG J H,L W,HAO Z D,et al.. Color-tunable white-light emitting BaMg2Al6Si9O30:Eu2+,Tb3+,Mn2+ phosphors via energy transfer (Invited)[J]. Chin. Opt., 2012,5(3):203-208. (in Chinese)

RAO B V,RAMBABU U,BUDDHUDU S. Analysis of green luminescent Tb3+:Ca4GdO(BO3)3 powder phosphor[J]. Phys. B:Condens. Matter, 2007,391(2):339-343.

ZHANG R,WANG X. Preparation and luminescent characteristics of Sr3RE2(BO3)4:Dy3+ (RE=Y,La,Gd) phosphors for white LED[J]. J. Alloys Compd., 2011,509(4):1197-1200.

LENG J,TANG J,XIE W Y,et al.. Impact of pH and urea content on size and luminescence of upconverting Y2O3:Yb,Er nanophosphors[J]. Mater. Res. Bull., 2018,100:171-177.

王林香,庹娟,叶颖,等. Li+,Zn2+,Mg2+掺杂Lu2O3:Er3+荧光粉的制备及发光特性[J]. 中国光学, 2019,12(1):112-121. WANG L X,TUO J,YE Y,et al.. Preparation and luminescence properties of Li+,Zn2+,Mg2+ doped Lu2O3:Er3+ phosphors[J]. Chin. Opt., 2019,12(1):112-121. (in Chinese)

YAN X,FERN G R,WITHNALL R,et al.. Contrasting behaviour of the co-activators in the luminescence spectra of Y2O2S:Tb3+,Er3+ nanometre sized particles under UV and red light excitation[J]. Nanoscale, 2013,5(3):1091-1096.

ZHAO W Y,AN S L,FAN B,et al.. Cathodoluminescent properties of the green phosphor Sr3Gd(BO3)3:Tb3+[J]. Opt. Mater., 2012,34(7):1124-1127.

林惠红,梁宏斌,苏锵,等. Sr2Mg(BO3)2:Tb3+的真空紫外发光性质[J]. 光谱学与光谱分析, 2011,31(7):1743-1746. LIN H H,LIANG H B,SU Q,et al.. Luminescence of Sr2Mg(BO3)2:Tb3+ under vacuum ultraviolet excitation[J]. Spectrosc. Spect. Anal., 2011,31(7):1743-1746. (in Chinese)

洪广言. 稀土发光材料[M]. 北京:科学出版社, 2011:160. HONG G Y. Fundamental and Application of Rare Earth Luminescent Materials[M]. Beijing:Science Press, 2011:160. (in Chinese)

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