单颗粒稀土纳米晶的三基色上转换发光

孙剑飞; 闫东; 刘禄

doi:10.3788/fgxb20204101.0001

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单颗粒稀土纳米晶的三基色上转换发光

材料合成及性能 | 更新时间：2020-08-12

- 单颗粒稀土纳米晶的三基色上转换发光
- Three-primary-color Upconversion in Single Lanthanide Based Nanoparticle
- 发光学报 2020年41卷第1期页码：1-8
- 作者机构：
  
  1. 黑龙江大学建筑工程学院, 黑龙江哈尔滨 150080
  2. 哈尔滨工程大学物理与光电工程学院, 黑龙江哈尔滨 150001
- 作者简介：
- 基金信息：
  
  哈尔滨工程大学111引智计划（B13015）();中央高校基本科研业务项目（3072019CF2516）资助()
- DOI：10.3788/fgxb20204101.0001
  中图分类号： O433.4;O432.1+2
- 收稿日期：2019-09-03，
  
  修回日期：2019-10-12，
  
  网络出版日期：2019-10-15，
  
  纸质出版日期：2020-01-05
- 稿件说明：
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孙剑飞, 闫东, 刘禄. 单颗粒稀土纳米晶的三基色上转换发光[J]. 发光学报, 2020,41(1): 1-8

SUN Jian-fei, YAN Dong, LIU Lu. Three-primary-color Upconversion in Single Lanthanide Based Nanoparticle[J]. Chinese Journal of Luminescence, 2020,41(1): 1-8
孙剑飞, 闫东, 刘禄. 单颗粒稀土纳米晶的三基色上转换发光[J]. 发光学报, 2020,41(1): 1-8 DOI： 10.3788/fgxb20204101.0001.

SUN Jian-fei, YAN Dong, LIU Lu. Three-primary-color Upconversion in Single Lanthanide Based Nanoparticle[J]. Chinese Journal of Luminescence, 2020,41(1): 1-8 DOI： 10.3788/fgxb20204101.0001.

摘要

可调谐发光颜色的上转换荧光纳米粒子具有广阔的应用前景。本文设计并成功合成了结构紧凑的多层核-壳纳米颗粒。在不同波段激光的泵浦下，该颗粒中不同壳层分别产生红、绿、蓝3种颜色的上转换荧光。光谱测试结果表明，样品三基色发光的颜色纯度较好，并且可以实现全色域的颜色实时调节。此外，还测试了样品发光强度与泵浦功率之间的依赖关系，用于研究其中的上转换发光机理。这种在单颗粒水平上具有全色域可调发光的紧凑核-壳结构纳米晶体在多通道生物检测及成像、超高分辨率显示器件、高端防伪应用等领域显示出巨大的潜力。

Abstract

Upconversion nanocrystals capable of tunable emitting color have shown wide application prospects. In this paper

we designed and successfully synthesized compact multi-layer core-shell nanocrystals. Different layers in a nanocrystal respectively produce upconversion luminescence with red

green and blue color

excited by various lasers. The emitting color with high purity can be further tuned in real-time within full color range. In addition

the luminescence intensity dependences on the pump power were recorded and used to investigate the luminescence mechanisms. The proposed compact core-shell nanocrystal with tunable color in a single nanoparticle shows great potentials for the applications such as bio-detection and imaging

display devices with ultrahigh resolution and advanced anti-counterfeiting.

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references

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