基于香豆素的荧光传感器及其对次氯酸根的快速检测

程晓红; 阮志军; 钟志成; 李望南

doi:10.3788/fgxb20183908.1182

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基于香豆素的荧光传感器及其对次氯酸根的快速检测

发光学应用及交叉前沿 | 更新时间：2020-08-12

- 基于香豆素的荧光传感器及其对次氯酸根的快速检测
- Rapid-responsive Fluorescent Probes Based on Coumarin Dye for Sensitive Detection of Hypochlorite
- 发光学报 2018年39卷第8期页码：1182-1191
- 作者机构：
  
  1. 湖北文理学院低维光电材料与器件湖北省重点实验室,湖北襄阳,441053
  2. 黄冈师范学院化学化工学院催化材料制备及应用湖北省重点实验室, 湖北黄冈 438000
- 作者简介：
- 基金信息：
  
  国家自然科学基金（21502047）();湖北省自然科学基金（2017CFB295）资助项目()
- DOI：10.3788/fgxb20183908.1182
  中图分类号： O622.4
- 纸质出版日期：2018-8-5，
  
  网络出版日期：2018-4-8，
  
  收稿日期：2017-11-16，
  
  修回日期：2018-3-4，
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程晓红, 阮志军, 钟志成等. 基于香豆素的荧光传感器及其对次氯酸根的快速检测[J]. 发光学报, 2018,39(8): 1182-1191

CHENG Xiao-hong, RUAN Zhi-jun, ZHONG Zhi-cheng etc. Rapid-responsive Fluorescent Probes Based on Coumarin Dye for Sensitive Detection of Hypochlorite[J]. Chinese Journal of Luminescence, 2018,39(8): 1182-1191
程晓红, 阮志军, 钟志成等. 基于香豆素的荧光传感器及其对次氯酸根的快速检测[J]. 发光学报, 2018,39(8): 1182-1191 DOI： 10.3788/fgxb20183908.1182.

CHENG Xiao-hong, RUAN Zhi-jun, ZHONG Zhi-cheng etc. Rapid-responsive Fluorescent Probes Based on Coumarin Dye for Sensitive Detection of Hypochlorite[J]. Chinese Journal of Luminescence, 2018,39(8): 1182-1191 DOI： 10.3788/fgxb20183908.1182.

摘要

本文报道了两个基于香豆素染料的次氯酸根荧光传感器（化合物C2和C4），可在不同条件下实现对次氯酸根的快速响应。利用次氯酸独特的氧化性，传感器C2和C4均可实现对次氯酸根的高选择性检测。在化合物C2的溶液中加入次氯酸根之后，溶液的荧光光谱表现出极大的荧光猝灭，这有利于在检测过程中产生明显的荧光信号输出。不同的是，化合物C4则对次氯酸根表现出明显的荧光增强响应。

Abstract

Taking advantage of the special oxidation property of hypochlorite

two novel coumarin-type fluorescent probes (compound C2 and C4) were synthesized for the rapid detection of ClO

. By virtue of its special oxidation property

both probes displayed high selectivity for ClO

over other anions. Upon the addition of ClO

anion

probe C2 displays extraordinary fluorescence quenching

which is beneficial to the production of a high signal output during detection process. Differently

probe C4 displays apparent enhancement in fluorescence emission spectra.

关键词

传感器次氯酸根荧光选择性快速检测

Keywords

probehypochloritefluorescenceselectivityrapid detection

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