溶剂热-高温煅烧法制备纳米 Gd2MoO6:Nd3+近红外发光材料

张蕤; 谢丽娟; 蔡建亮; 孟建新

doi:10.3788/fgxb20123311.1166

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溶剂热-高温煅烧法制备纳米 Gd₂MoO₆:Nd³⁺近红外发光材料

材料合成及性能研究 | 更新时间：2020-08-12

- 溶剂热-高温煅烧法制备纳米 Gd₂MoO₆:Nd³⁺近红外发光材料
- Solvothermal Preparation and Near Infrared Luminescence of Gd₂MoO₆:Nd³⁺ Nano-phosphors
- 发光学报 2012年33卷第11期页码：1166-1170
- 作者机构：
  
  1. 暨南大学化学系,广东广州,510632
  2. 暨南大学纳米化学研究所,广东广州,510632
- 作者简介：
- 基金信息：
  
  国家自然科学基金( 30670523)();中央高校基本科研业务费专项资金资助项目()
- DOI：10.3788/fgxb20123311.1166
  中图分类号： O611.4;O482.31;O614.33
- 纸质出版日期：2012-11-10，
  
  收稿日期：2012-7-2，
  
  修回日期：2012-9-6，
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张蕤, 谢丽娟, 蔡建亮, 孟建新. 溶剂热-高温煅烧法制备纳米 Gd2MoO6:Nd3+近红外发光材料[J]. 发光学报, 2012,(11): 1166-1170

ZHANG Rui, XIE Li-juan, CAI Jian-liang, Meng Jian-xin. Solvothermal Preparation and Near Infrared Luminescence of Gd2MoO6:Nd3+ Nano-phosphors[J]. Chinese Journal of Luminescence, 2012,(11): 1166-1170
张蕤, 谢丽娟, 蔡建亮, 孟建新. 溶剂热-高温煅烧法制备纳米 Gd2MoO6:Nd3+近红外发光材料[J]. 发光学报, 2012,(11): 1166-1170 DOI： 10.3788/fgxb20123311.1166.

ZHANG Rui, XIE Li-juan, CAI Jian-liang, Meng Jian-xin. Solvothermal Preparation and Near Infrared Luminescence of Gd2MoO6:Nd3+ Nano-phosphors[J]. Chinese Journal of Luminescence, 2012,(11): 1166-1170 DOI： 10.3788/fgxb20123311.1166.

摘要

采用乙二醇-水的混合溶液作为溶剂

用溶剂热法制备了Gd

MoO

:Nd

的前驱体

然后对得到的样品在800℃下煅烧1 h。使用X射线衍射仪对样品的结构进行了表征

通过近红外和可见光区的发射光谱和激发光谱以及透射电子显微镜对样品的发光性质以及形貌进行了研究。探究了煅烧温度、Nd

的掺杂浓度、pH值、乙二醇-水的配比对样品的近红外发光性能以及形貌的影响。实验结果表明

在乙二醇-水的配比为1:1

的掺杂摩尔分数为0.03

pH值为1.5

煅烧温度为800℃时

能得到分散性良好

并具有优良近红外发光性质的纳米粒子。

Abstract

MoO

:Nd

nanophosphors was prepared with a solvothermal method using glycol-water mixed solution as a solvent

then calcined at 800℃ for 1 h. The samples were tested with X-ray diffraction

transmission electron microscope

emission and excitation spectrum. Uniform Gd

MoO

:Nd

nano-spher with good dispersity and efficient near infrared emission can be achieved at a reaction temperature as low as 800℃ and pH value of 1.5. The optimized Nd

doping mole fraction is 0.03. The ratio of water to ethylene glycol is 1:1. The particle is promising in the application of fluorescence immunoassay.

关键词

溶剂热法近红外发光材料Nd3+Gd2MoO6

Keywords

solvothermal synthesisinfrared luminescenceNd3+Gd2MoO6

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