用于固态照明的Mn<sup>4+</sup>离子光谱学

BRIK Mikhail G; 马崇庚; SRIVASTAVA Alok M; PIASECKI Michal

doi:10.37188/fgxb20204109.1011

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用于固态照明的Mn⁴⁺离子光谱学

特邀综述 | 更新时间：2020-09-10

- 用于固态照明的Mn⁴⁺离子光谱学
- Mn⁴⁺ Ions for Solid State Lighting
- 发光学报 2020年41卷第9期页码：1011-1029
- 作者机构：
  
  1.重庆邮电大学理学院&“重庆邮电大学-伦敦布鲁内尔大学”交叉创新研究院, 重庆 400065
  2.塔尔图大学物理所, 爱沙尼亚塔尔图 50411
  3.琴斯托霍瓦师范大学物理所, 波兰琴斯托霍瓦 42200
  4.戴恩特里公司通用电气顾问部, 美国克利夫兰 44110
  5.东欧国立大学固态物理系, 乌克兰卢茨克 43025
- 作者简介：
  
  [ "BRIK Mikhail G (1969-), received his PhD from Kuban State University(Russia) in 1995 and his DSc(habilitation) from the Institute of Physics, Polish Academy of Sciences(Poland) in 2012. Since 2007 he is a professor at the Institute of Physics, University of Tartu, Estonia. Before that, he worked at Kyoto University(Japan) from 2003 to 2007, Weizmann Institute of Science(Israel) in 2002, Asmara University(Eritrea) from 2000 to 2001, and Kuban State University from 1995 to 2000. He is also a distinguished visiting professor at Chongqing University of Posts and Telecommunications(China) and Professor at Jan Długosz University(Poland). Since 2015 he serves as one of the editors ofOptical Materials(Elsevier). Professor Brik's scientific interests cover theoretical spectroscopy of transition metal and rare earth ions in optical materials, crystal field theory, and ab initio calculations of the physical properties of pure and doped functional compounds. He is a coeditor of two books and author of 12 book chapters and about 410 papers in international journals. According to Google Scholar(June 2020), he has more than 8 500 citations with H index 45. He received the Dragomir Hurmuzescu Award of Romanian Academy in 2006 and the State Prize of the Republic of Estonia in the field of exact sciences in 2013. In 2018 he received the state professor title from the President of Poland. E-mail:mikhail.brik@ut.ee" ]
  [ "MA Chong-geng (1980-), received his PhD from University of Science and Technology of China in 2008. He spent three years(2010-2013) as a post-doctor in University of Tartu with the financial support of European Social Fund. He was also a visiting professor at University of Verona in 2017. His area of scientific interests covers the first-principles and crystal-field design of luminescent materials. He has published one book and more than 80 papers in international journals, which attracted more than 1 600 citations(H index=21). Currently he is a full professor and the director of CQUPT-BUL Innovation Institute at Chongqing University of Posts and Telecommunications. E-mail:macg@cqupt.edu.cn" ]
  [ "SRIVASTAVA Alok M (1960-), received his PhD from in 1986 from Polytechnic University of New York, Brooklyn, New York. Dr. Srivastava began his industrial career at General Electric's (GE) Global Research Center in Niskayuna, New York, in 1989 at GE GRC he established the phosphor laboratory where he laid the groundwork for the design and development of luminescent materials. Dr. Srivastava's research describes the relationship between the synthesis, crystal structure and optical properties of luminescent ions in solids. Dr. Srivastava holds a total of 141 U.S. patents and more than 100 peer reviewed publications. In 2015 he was appointed the Editor-in-Chief of Journal of Optical Materials(Elsevier). For his pioneering research in oxide quantum splitting phosphors he was awarded the First Centennial Outstanding Achievement Award of the Luminescence and Display Materials Division of The Electrochemical Society(2004). He has served as the Chairman of the Luminescence and Display Materials group of The Electrochemical Society. In 2019, Dr. Srivastava was elected Fellow of The Electrochemical Society. Currently, Dr. Srivastava has a technical consulting firm that is based on his more than 35 years of experience and broad technical knowledge in the area of solid-state luminescence. He leverages his expertise to assist industrial and academic scientists in the fundamental understanding, design and synthesis of luminescent products. E-mail:srivastaam@outlook.com" ]
  [ "PIASECKI Michal (1957-), received his MSc in Physics(honors degree) in Institute of Physics, Nicolaus Copernicus University Torun(present A.Jablonski Institute), Ph.D. from Institute of Low Temperature and Structural Research Polish Academy of Sciences in Wroclaw(Poland) and habilitation in Zielona Gora University(Poland). Now he is working as a professor and Head of Department of Theoretical Physics of Jan Długosz University(Poland) and Lesya Ukrainka Eastern European National University(Ukraine). His research interests cover phase transitions, ferroelectricity, thermoelectricity, luminescence and non-linear optics. He conducted several EU projects utilizing ultra-UV(synchrotron) spectroscopic ellipsometry for investigations of novel photonic materials and bilateral research projects between Poland and France, Portugal, etc as partner countries. He has more than 170 publications in SCI journals, H-index=22, more than 1 900 citations. He has several awards including those from Polish Academy of Sciences -2 times; Polish Ministry of Sciences and Higher Education; Rector of Jan Długosz University. He was a visiting professor in University of Reims Champagne-Ardenne(France) and Vellore Institute of Technology, India. E-mail:m.piasecki@ujd.edu.pl" ]
- 基金信息：
  
  Chongqing Innovation and Entrepreneurship Programs for Returned Overseas Chinese Sch
- DOI：10.37188/fgxb20204109.1011
  中图分类号：
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BRIK Mikhail G, 马崇庚, SRIVASTAVA Alok M, 等. 用于固态照明的Mn⁴⁺离子光谱学[J]. 发光学报, 2020,41(9):1011-1029.

BRIK Mikhail G, Chong-geng MA, SRIVASTAVA Alok M, et al. Mn⁴⁺ Ions for Solid State Lighting[J]. Chinese Journal of Luminescence, 2020,41(9):1011-1029.
BRIK Mikhail G, 马崇庚, SRIVASTAVA Alok M, 等. 用于固态照明的Mn⁴⁺离子光谱学[J]. 发光学报, 2020,41(9):1011-1029. DOI： 10.37188/fgxb20204109.1011.

BRIK Mikhail G, Chong-geng MA, SRIVASTAVA Alok M, et al. Mn⁴⁺ Ions for Solid State Lighting[J]. Chinese Journal of Luminescence, 2020,41(9):1011-1029. DOI： 10.37188/fgxb20204109.1011.

摘要

Mn,4+,离子激活的荧光粉在固态照明领域作为红光发射的热点载体正日益受到关注。我们针对当前研究热度撰写了Mn,4+,离子光谱学的回顾，并在回顾中聚焦了许多对红色荧光粉商业研制有价值的重要基础研究点。这些研究点涵盖了如何理解自由和晶场状态下Mn,4+,离子的能级结构以及Mn,4+,发射波长对基质的依赖关系。此外，我们就如何实验调控Mn,4+,离子掺杂型荧光粉的发射波长和发光强度给出了许多实际可行的建议。更为重要的是，我们收集并讨论了100多种荧光粉基质中Mn,4+,离子光谱学参数，对它们的理解将会为未来Mn,4+,掺杂型红色荧光粉的实验开发奠定基础。

Abstract

Phosphors activated with Mn,4+, ion are gaining prominence in the field of solid-state lighting as generators of red photon. In the present review, we focus on several important points that are fundamentally important to produce a commercially useful phosphor. This includes an understanding of the Mn,4+, energy levels in the free state and in the crystal fields and of the host dependent variations in the Mn,4+, emission wavelength. Additionally, we formulate several practical recommendations on how to tune the emission wavelength and emission intensity of Mn,4+,-doped phosphors. The main spectroscopic parameters of the Mn,4+, ion in more than 100 phosphor materials are collected and discussed.

关键词

Mn4+离子红色荧光粉白光LED

Keywords

Mn4+ ionsred phosphorswhite LED

references

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用于固态照明的Mn4+离子光谱学

Mn4+ Ions for Solid State Lighting

DOI：10.37188/fgxb20204109.1011

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用于固态照明的Mn⁴⁺离子光谱学

Mn⁴⁺ Ions for Solid State Lighting