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全无机钙钛矿CsPb
X 3热稳定性研究进展Research Progress on Thermal Stability of All Inorganic Perovskite CsPb
X 3- 发光学报 2020年41卷第8期 页码：926-939
- 作者机构：
广东工业大学 物理与光电工程学院, 广东 广州 510006
- 作者简介：
[ "练惠旺(1996-), 男, 广东惠州人, 硕士研究生, 2019年于广东工业大学获得学士学位, 主要从事钙钛矿水热稳定性方面的研究。E-mail:hwlian@sina.cn" ]
[ "李杨(1984-), 男, 山东淄博人, 博士, 教授, 博士研究生导师, 2014年于华南理工大学获得博士学位, 主要从事无机固体发光材料缺陷调控, 特别是长余辉材料的设计、机理及应用的研究。E-mail:lychris@sina.com" ]
- 基金信息：国家自然科学基金(51602063);广东省自然科学基金(2019A030310444);广州市科技计划(2019A1515011688)
DOI：10.37188/fgxb20204108.0926
中图分类号： O482.31纸质出版日期：2020-8，
收稿日期：2020-5-15，
录用日期：2020-6-4
扫 描 看 全 文
练惠旺, 康茹, 陈星中, 等. 全无机钙钛矿CsPb
X 3热稳定性研究进展[J]. 发光学报, 2020,41(8):926-939.Hui-wang LIAN, Ru KANG, Xing-zhong CHEN, et al. Research Progress on Thermal Stability of All Inorganic Perovskite CsPb
X 3[J]. Chinese Journal of Luminescence, 2020,41(8):926-939.练惠旺, 康茹, 陈星中, 等. 全无机钙钛矿CsPb
X 3热稳定性研究进展[J]. 发光学报, 2020,41(8):926-939. DOI： 10.37188/fgxb20204108.0926.Hui-wang LIAN, Ru KANG, Xing-zhong CHEN, et al. Research Progress on Thermal Stability of All Inorganic Perovskite CsPb
X 3[J]. Chinese Journal of Luminescence, 2020,41(8):926-939. DOI： 10.37188/fgxb20204108.0926.
摘要
凭借高量子效率、带隙可调、制备简单、高吸光系数和高耐缺陷性的优点，全无机钙钛矿（CsPb
X
3
，
X
=Cl，Br，I）材料在光电和光伏器件领域展现出较出色的应用前景。然而，现有材料热稳定性的不足降低了这些应用的耐久性和可靠性。本综述从全无机钙钛矿材料温度相关的热分解过程入手，有针对性地阐述了全无机钙钛矿热稳定性增强策略，并展示了迄今报道的高可靠性全无机钙钛矿光电和光伏器件的性能参数和应用领域。最后对今后发展热稳定全无机钙钛矿材料存在的机遇进行了展望。
Abstract
In virtue of the high photoluminescence quantum yield(PLQY)
tunable bandgap
facile synthesis
strong light-absorption ability and high defect tolerance
all inorganic perovskites CsPb
X
3
(
X
=Cl
Br
I) hold a great promise in optoelectronic and photovoltaic fields
such as solid-state lighting
lasing
solar cell
and display
etc
. Despite the impressive achievements
the existing inorganic perovskites still receive strong criticism for the lack of thermal stability. This is because their poor thermal stability will observably reduce the durability
reliability
and long-term stability of optoelectronic devices. Herein
in this review
the influence of temperature on the stability of inorganic perovskites is discussed. The reasons behind the thermal decomposition of inorganic perovskites including the desorption of the surface ligands and phase transition under high temperatures are analyzed as well. Subsequently
the recent strategies towards enhancing the thermal stability of CsPb
X
3
such as ions doping
surface passivation
and composite structure
are emphatically reviewed. Furthermore
the performance parameters of optoelectronic perovskites-devices with high reliability reported so far are presented. Finally
we summarize and prospect the challenge and opportunity for future development of thermally stable inorganic perovskite CsPb
X
3
.
关键词
全无机钙钛矿热稳定性CsPbX3
Keywords
all inorganic perovskitethermal stabilityCsPbX3
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