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1.福建师范大学 化学与材料学院, 福建 福州 350117
2.中国科学院 福建物质结构研究所, 中国科学院功能纳米结构设计与组装重点实验室, 福建省纳米材料重点实验室, 福建 福州 350002
3.中国福建光电信息科技与技术创新实验室(闽都创新实验室), 福建 福州 350108
[ "文飞(1996-),男,陕西宝鸡人,硕士研究生,2016年于江西科技师范大学获得学士学位,主要从事稀土无机纳米发光材料的可控合成、发光性能及光学性质等方面的研究。 E-mail: wenfei@fjirsm. ac. cn" ]
[ "涂大涛(1982-),男,湖北武汉人,博士,研究员,博士生导师,2011年于中国科学院福建物质结构研究所获得博士学位,主要从事稀土纳米发光材料的可控合成、光电子学及其生物应用等方面的研究。E-mail: dttu@fjirsm. ac. cn" ]
[ "陈学元(1970-),男,福建建瓯人,博士,研究员,博士生导师,1998年于中国科学院福建物质结构研究所获得博士学位,主要从事无机发光材料的电子结构、发光性能与应用等方面的 研究。 E-mail: xchen@fjirsm.ac.cn" ]
收稿日期:2023-02-17,
修回日期:2023-03-06,
纸质出版日期:2023-07-05
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文飞,涂大涛,廉纬等.稀土掺杂无序结构晶体的局域位置对称性与发光调控[J].发光学报,2023,44(07):1202-1219.
WEN Fei,TU Datao,LIAN Wei,et al.Local Site Symmetry and Luminescence Manipulation of Lanthanide Doped Disordered Crystals[J].Chinese Journal of Luminescence,2023,44(07):1202-1219.
文飞,涂大涛,廉纬等.稀土掺杂无序结构晶体的局域位置对称性与发光调控[J].发光学报,2023,44(07):1202-1219. DOI: 10.37188/CJL.20230040.
WEN Fei,TU Datao,LIAN Wei,et al.Local Site Symmetry and Luminescence Manipulation of Lanthanide Doped Disordered Crystals[J].Chinese Journal of Luminescence,2023,44(07):1202-1219. DOI: 10.37188/CJL.20230040.
稀土掺杂的无序结构晶体具有优异的下转移和上转换发光性能,通过对材料的发光调控可使其广泛应用于各种光学和光电子学领域。稀土离子的光学性质与所处的晶体场环境密切相关,因此,使用稀土离子作为灵敏的结构探针,可以确定无序结构发光材料中稀土离子掺杂的局域结构和位置对称性;同时,通过改变稀土离子掺杂的无序结构晶体的局域位置对称性也可以进行一系列发光调控。本文首先介绍了稀土离子掺杂无序结构材料的晶体学格位对称性和光谱学格位对称性;其次,系统总结了通过改变局域结构来调控稀土离子掺杂的下转移/上转换发光的最新成果,包括组分调节和外场调节;最后,深入探讨了稀土掺杂无序结构发光材料面临的挑战和发展前景。
Lanthanide ion (
Ln
3+
)-doped disordered materials exhibit excellent downshifting and upconversion luminescent properties, which can be widely used in a variety of optical and optoelectronic fields through luminescence modulation. The optical properties of
Ln
3+
ions are closely related to the local structure of crystal field. Thus, by using
Ln
3+
as a sensitive structural probe, the local structure and local site symmetry of
Ln
3+
dopants in luminescent materials can be determined. Meanwhile, it is also an effective strategy to optimize the luminescence of
Ln
3+
by modulating the local site symmetry of the
Ln
3+
-doped disordered materials. In this review, we first clarify the crystallographic lattice site symmetry and spectroscopic lattice site symmetry of
Ln
3+
-doped disordered crystals. Then, we systematically summarize the latest achievements of downshifting/upconversion luminescence manipulation by changing the microstructures around
Ln
3+
dopants, including internal composition and external field regulation. Finally, the challenges and prospects of
Ln
3+
-doped disordered luminescent materials are discussed in detail.
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