浏览全部资源
扫码关注微信
1.暨南大学 信息科学技术学院, 新能源技术研究院, 广东 广州 510632
2.五邑大学 智能制造学部, 广东 江门 529020
[ "谢光起(1998-),男,广西钦州人,硕士研究生,2020年于中南民族大学获得学士学位,主要从事新型钙钛矿太阳能电池的研究。 E-mail: 1227393032@qq. com" ]
[ "马梦恩(1995-),男,河南周口人,博士研究生,2020年于河南大学获得硕士学位,主要从事大面积钙钛矿太阳能电池的相关研究。E-mail: mengenma@jnu. edu. cn" ]
[ "杨恢东(1967-),男,湖南邵阳人,博士,教授,2003年于南开大学获得博士学位,主要从事半导体纳米材料制备、光电特性及其应用等方面的研究。E-mail: tyanghd@jnu. edu. cn" ]
[ "刘冲(1989-),男,河北保定人,博士,副研究员,2020年于暨南大学获得博士学位,主要从事新型钙钛矿太阳电池(涉及全无机钙钛矿太阳电池、大面积涂布和组件开发等领域)的研发。E-mail: chongliu@jnu. edu. cn" ]
收稿日期:2022-12-14,
修回日期:2022-12-29,
纸质出版日期:2023-06-05
移动端阅览
谢光起,马梦恩,杨丹妮等.双自组装单分子层修饰氧化镍制备高效率钙钛矿太阳电池及组件[J].发光学报,2023,44(06):1023-1031.
XIE Guangqi,MA Mengen,YANG Danni,et al.Co-assembled Monolayers Modified Nickel Oxide for High Efficient Perovskite Solar Cells and Modules[J].Chinese Journal of Luminescence,2023,44(06):1023-1031.
谢光起,马梦恩,杨丹妮等.双自组装单分子层修饰氧化镍制备高效率钙钛矿太阳电池及组件[J].发光学报,2023,44(06):1023-1031. DOI: 10.37188/CJL.20220414.
XIE Guangqi,MA Mengen,YANG Danni,et al.Co-assembled Monolayers Modified Nickel Oxide for High Efficient Perovskite Solar Cells and Modules[J].Chinese Journal of Luminescence,2023,44(06):1023-1031. DOI: 10.37188/CJL.20220414.
氧化镍(NiO
x
)作为无机p型半导体,常用于倒置钙钛矿太阳能电池(PSCs)中的空穴传输层(HTL),但本身存在的高缺陷密度和与钙钛矿不相匹配的能级排布限制了PSCs的能量转换效率。本文通过引入双自组装单分子层修饰氧化镍界面,钝化氧化镍材料自身缺陷,改善能级匹配,促进了界面处光生载流子的提取和传输,提高了PSCs的开路电压(
V
oc
)和填充因子(FF),最终将刮涂氧化镍基PSCs的效率提升到20.38%,而且未封装的器件在氮气氛围中用85 ℃老化1 000 h后仍维持原始效率的96%。更重要的是,我们以此制备了孔径面积为60.84 cm
2
、由13节子电池串联而成的钙钛矿组件,效率达到了17.04%。
Nickel oxide (NiO
x
), an inorganic p-type semiconductor, is commonly used as the hole transporting layer (HTL) for inverted perovskite solar cells (PSCs). However, the high defect density of NiO
x
and mismatched energy levels with the perovskite layer strongly limit the efficiency of PSCs. In this work, the co-assembled monolayer is introduced to modify the interface of NiO
x
, which was demonstrated to passivate the defects and improve the energy level alignment, leading to the enhancement of charge extraction and transmission at the interface. Finally, the blade-coated PSCs yield a power conversion efficiency of 20.38% due to the improvement on open circuit voltage (
V
oc
) and filling factor (FF). Moreover, the device without encapsulation can maintain 96% of the initial efficiency after aging at 85 ℃ for 1 000 h in nitrogen atmosphere. More importantly, we have fabricated a perovskite solar module with an aperture area of 60.84 cm
2
, which is composed of 13 sub cells in series, and the efficiency has reached 17.04%.
KOJIMA A , TESHIMA K , SHIRAI Y , et al . Organometal halide perovskites as visible-light sensitizers for photovoltaic cells [J]. J. Am. Chem. Soc. , 2009 , 131 ( 17 ): 6050 - 6051 . doi: 10.1021/ja809598r http://dx.doi.org/10.1021/ja809598r
PARK J , KIM J , YUN H S , et al . Controlled growth of perovskite layers with volatile alkylammonium chlorides [J]. Nature , 2023 , 616 ( 7958 ): 724 - 730 . doi: 10.1038/s41586-023-05825-y http://dx.doi.org/10.1038/s41586-023-05825-y
BOYD C C , SHALLCROSS R C , MOOT T , et al . Overcoming redox reactions at perovskite-nickel oxide interfaces to boost voltages in perovskite solar cells [J]. Joule , 2020 , 4 ( 8 ): 1759 - 1775 . doi: 10.1016/j.joule.2020.06.004 http://dx.doi.org/10.1016/j.joule.2020.06.004
DI GIROLAMO D , DI GIACOMO F , MATTEOCCI F , et al . Progress, highlights and perspectives on NiO in perovskite photovoltaics [J]. Chem. Sci. , 2020 , 11 ( 30 ): 7746 - 7759 . doi: 10.1039/d0sc02859b http://dx.doi.org/10.1039/d0sc02859b
GŁOWIENKA D , ZHANG D , DI GIACOMO F , et al . Role of surface recombination in perovskite solar cells at the interface of HTL/CH 3 NH 3 PbI 3 [J]. Nano Energy , 2020 , 67 : 104186-1 - 11 . doi: 10.1016/j.nanoen.2019.104186 http://dx.doi.org/10.1016/j.nanoen.2019.104186
CHEN W , ZHOU Y C , CHEN G C , et al . Alkali chlorides for the suppression of the interfacial recombination in inverted planar perovskite solar cells [J]. Adv. Energy Mater. , 2019 , 9 ( 19 ): 1803872-1-10 . doi: 10.1002/aenm.201803872 http://dx.doi.org/10.1002/aenm.201803872
NIU Q L , DENG Y K , CUI D Q , et al . Enhancing the performance of perovskite solar cells via interface modification [J]. J. Mater. Sci. , 2019 , 54 ( 22 ): 14134 - 14142 . doi: 10.1007/s10853-019-03898-7 http://dx.doi.org/10.1007/s10853-019-03898-7
WANG T , CHENG Z D , ZHOU Y L , et al . Highly efficient and stable perovskite solar cells via bilateral passivation layers [J]. J. Mater. Chem. A , 2019 , 7 ( 38 ): 21730 - 21739 . doi: 10.1039/c9ta08084h http://dx.doi.org/10.1039/c9ta08084h
WANG T , DING D , ZHENG H , et al . Efficient inverted planar perovskite solar cells using ultraviolet/ozone-treated NiO x as the hole transport layer [J]. Sol. RRL , 2019 , 3 ( 6 ): 1900045 . doi: 10.1002/solr.201900045 http://dx.doi.org/10.1002/solr.201900045
SINGH N , TAO Y T . Effect of surface modification of nickel oxide hole-transport layer via self-assembled monolayers in perovskite solar cells [J]. Nano Sel. , 2021 , 2 ( 12 ): 2390 - 2399 . doi: 10.1002/nano.202100004 http://dx.doi.org/10.1002/nano.202100004
ZHU T , SU J , LABAT F , et al . Interfacial engineering through chloride-functionalized self-assembled monolayers for high-performance perovskite solar cells [J]. ACS Appl. Mater. Interfaces , 2019 , 12 ( 1 ): 744 - 752 . doi: 10.1021/acsami.9b18034 http://dx.doi.org/10.1021/acsami.9b18034
SUN J J , SHOU C H , SUN J S , et al . NiO x -seeded self-assembled monolayers as highly hole-selective passivating contacts for efficient inverted perovskite solar cells [J]. Sol. RRL , 2021 , 5 ( 11 ): 2100663-1-8 . doi: 10.1002/solr.202100663 http://dx.doi.org/10.1002/solr.202100663
DENG X , QI F , LI F Z , et al . Co-assembled monolayers as hole-selective contact for high-performance inverted perovskite solar cells with optimized recombination loss and long-term stability [J]. Angew. Chem. Int. Ed. , 2022 , 61 ( 30 ): e202203088 - 1 - 8 . doi: 10.1002/anie.202203088 http://dx.doi.org/10.1002/anie.202203088
LI L D , WANG Y R , WANG X Y , et al . Flexible all-perovskite tandem solar cells approaching 25% efficiency with molecule-bridged hole-selective contact [J]. Nat. Energy , 2022 , 7 ( 8 ): 708 - 717 . doi: 10.1038/s41560-022-01045-2 http://dx.doi.org/10.1038/s41560-022-01045-2
XIAO M Y , LU T Y , LIN T , et al . Understanding molecular structures of buried interfaces in halide perovskite photovoltaic devices nondestructively with sub-monolayer sensitivity using sum frequency generation vibrational spectroscopy [J]. Adv. Energy Mater. , 2020 , 10 ( 26 ): 1903053-1-10 . doi: 10.1002/aenm.201903053 http://dx.doi.org/10.1002/aenm.201903053
LIU C , YANG Y Z , ZHANG C L , et al . Tailoring C 60 for efficient inorganic CsPbI 2 Br perovskite solar cells and modules [J]. Adv. Mater. , 2020 , 32 ( 8 ): 1907361-1-9 . doi: 10.1002/adma.201907361 http://dx.doi.org/10.1002/adma.201907361
GAO Y Y , LIU C , XIE Y , et al . Can nanosecond laser achieve high-performance perovskite solar modules with aperture area efficiency over 21%? [J]. Adv. Energy Mater. , 2022 , 12 ( 41 ): 2202287-1-8 . doi: 10.1002/aenm.202202287 http://dx.doi.org/10.1002/aenm.202202287
AL-ASHOURI A , MAGOMEDOV A , ROSS M , et al . Conformal monolayer contacts with lossless interfaces for perovskite single junction and monolithic tandem solar cells [J]. Energy Environ. Sci. , 2019 , 12 ( 11 ): 3356 - 3369 . doi: 10.1039/c9ee02268f http://dx.doi.org/10.1039/c9ee02268f
KIM S Y , CHO S J , BYEON S E , et al . Self-assembled monolayers as interface engineering nanomaterials in perovskite solar cells [J]. Adv. Energy Mater. , 2020 , 10 ( 44 ): 2002606-1-21 . doi: 10.1002/aenm.202002606 http://dx.doi.org/10.1002/aenm.202002606
ALI F , ROLDÁN-CARMONA C , SOHAIL M , et al . Applications of self-assembled monolayers for perovskite solar cells interface engineering to address efficiency and stability [J]. Adv. Energy Mater. , 2020 , 10 ( 48 ): 2002989-1-24 . doi: 10.1002/aenm.202002989 http://dx.doi.org/10.1002/aenm.202002989
BULLIARD X , IHN S G , YUN S , et al . Enhanced performance in polymer solar cells by surface energy control [J]. Adv. Funct. Mater. , 2010 , 20 ( 24 ): 4381 - 4387 . doi: 10.1002/adfm.201000960 http://dx.doi.org/10.1002/adfm.201000960
LI F M , SHEN Z T , WENG Y J , et al . Novel electron transport layer material for perovskite solar cells with over 22% efficiency and long-term stability [J]. Adv. Funct. Mater. , 2020 , 30 ( 45 ): 2004933-1-9 . doi: 10.1002/adfm.202004933 http://dx.doi.org/10.1002/adfm.202004933
邹宇 , 李昭 , 陈衡慧 , 等 . NaTFSI界面修饰对平面TiO 2 基钙钛矿太阳能电池的影响 [J]. 发光学报 , 2021 , 42 ( 5 ): 682 - 690 . doi: 10.37188/cjl.20210045 http://dx.doi.org/10.37188/cjl.20210045
ZOU Y , LI Z , CHEN H H , et al . Effect of interfacial modification for TiO 2 -based planar perovskite solar cells using NaTFSI [J]. Chin. J. Lumin. , 2021 , 42 ( 5 ): 682 - 690 . (in Chinese) . doi: 10.37188/cjl.20210045 http://dx.doi.org/10.37188/cjl.20210045
ZHU X J , DU M Y , FENG J S , et al . High-efficiency perovskite solar cells with imidazolium-based ionic liquid for surface passivation and charge transport [J]. Angew. Chem. Int. Ed. , 2021 , 60 ( 8 ): 4238 - 4244 . doi: 10.1002/anie.202010987 http://dx.doi.org/10.1002/anie.202010987
LI W Z , ZHANG C L , MA Y P , et al . In situ induced core/shell stabilized hybrid perovskites via gallium(Ⅲ) acetylacetonate intermediate towards highly efficient and stable solar cells [J]. Energy Environ. Sci. , 2018 , 11 ( 2 ): 286 - 293 . doi: 10.1039/c7ee03113k http://dx.doi.org/10.1039/c7ee03113k
MA J , LIN Z H , GUO X , et al . Low-temperature solution-processed ZnO electron transport layer for highly efficient and stable planar perovskite solar cells with efficiency over 20% [J]. Sol. RRL , 2019 , 3 ( 7 ): 1900096 . doi: 10.1002/solr.201900096 http://dx.doi.org/10.1002/solr.201900096
WANG Q , CHUEH C C , ZHAO T , et al . Effects of self-assembled monolayer modification of nickel oxide nanoparticles layer on the performance and application of inverted perovskite solar cells [J]. ChemSusChem , 2017 , 10 ( 19 ): 3794 - 3803 . doi: 10.1002/cssc.201701262 http://dx.doi.org/10.1002/cssc.201701262
CHEN H , YE F , TANG W T , et al . A solvent- and vacuum-free route to large-area perovskite films for efficient solar modules [J]. Nature , 2017 , 550 ( 7674 ): 92 - 95 . doi: 10.1038/nature23877 http://dx.doi.org/10.1038/nature23877
0
浏览量
472
下载量
0
CSCD
关联资源
相关文章
相关作者
相关机构