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中国计量大学 光电材料与器件研究所, 浙江 杭州 310018
[ "温一诺(1997-),女,河北承德人,硕士研究生,2020年于湖北文理学院获得学士学位,主要从事稀土离子掺杂荧光材料温度传感特性的研究。 E-mail: ynuo_wen@163.com" ]
[ "陈亮(1981-),男,河南南阳人,博士,教授,2012年于南京理工大学获得博士学位,主要从事稀土离子掺杂荧光材料温度传感特性的研究。 E-mail: Lchen@cjlu.edu.cn" ]
纸质出版日期:2023-04-05,
收稿日期:2022-09-27,
修回日期:2022-10-16,
移动端阅览
温一诺,陈彦伶,付杰等.Bi3+、Eu3+共掺双钙钛矿Gd2ZnTiO6荧光粉制备及其温度传感性能[J].发光学报,2023,44(04):615-626.
WEN Yinuo,CHEN Yanling,FU Jie,et al.Preparation and Temperature Sensing Properties of Bi3+, Eu3+ Co-doped Double Perovskite Gd2ZnTiO6 Phosphor[J].Chinese Journal of Luminescence,2023,44(04):615-626.
温一诺,陈彦伶,付杰等.Bi3+、Eu3+共掺双钙钛矿Gd2ZnTiO6荧光粉制备及其温度传感性能[J].发光学报,2023,44(04):615-626. DOI: 10.37188/CJL.20220341.
WEN Yinuo,CHEN Yanling,FU Jie,et al.Preparation and Temperature Sensing Properties of Bi3+, Eu3+ Co-doped Double Perovskite Gd2ZnTiO6 Phosphor[J].Chinese Journal of Luminescence,2023,44(04):615-626. DOI: 10.37188/CJL.20220341.
采用高温固相法制备了一系列具有双发射中心的Gd
2 (1-
x-y
)
ZnTiO
6
∶
x
Bi
3+
,
y
Eu
3+
荧光粉。采用X射线衍射、扫描电子显微镜、荧光光谱、寿命衰减曲线和变温发射光谱等方法,系统地研究了该材料的结构、发光性能和温度传感特性。在Gd
2
ZnTiO
6
∶Bi
3+
,Eu
3+
荧光粉中,Bi
3+
和Eu
3+
离子占据了Gd
3+
离子的位置。在紫外激发下,Eu
3+
的激发光谱和Bi
3+
的发射光谱存在光谱重叠,表明从Bi
3+
到Eu
3+
可能存在能量传递。通过荧光强度比技术探究了Bi
3+
蓝光发射与Eu
3+
红光发射的不同温度响应特性。在293~473 K温度范围内,测得Gd
2
ZnTiO
6
∶Bi
3+
,Eu
3+
荧光粉的最大相对温度灵敏度为1.133%·K
-1
,最大绝对灵敏度为0.73 %·K
-1
。因此,Gd
2
ZnTiO
6
∶Bi
3+
,Eu
3+
荧光粉是一种有潜力的非接触式光学测温材料。
A series of Gd
2 (1
-x-y
)
ZnTiO
6
∶
x
Bi
3+
,
y
Eu
3+
phosphors with dual emission centers were prepared by high-temperature solid phase method. The structure, luminescence properties and temperature sensing characteristics of the material were systematically studied by X-ray diffraction, scanning electron microscopy, fluorescence spectroscopy, lifetime decay curve and variable temperature emission spectroscopy, respectively. In Gd
2
ZnTiO
6
∶Bi
3+
,Eu
3+
phosphor, Bi
3+
and Eu
3+
ions occupy Gd
3+
ion position. Under UV excitation, the excitation spectra of Eu
3+
and emission spectra of Bi
3+
overlap, indicating that there may be energy transfer from Bi
3+
to Eu
3+
. The fluorescence intensity ratio technique was used to explore the different temperature response characteristics of Bi
3+
blue light emission and Eu
3+
red light emission. In the temperature range of 293-473 K, the maximum relative temperature sensitivity of Gd
2
ZnTiO
6
∶Bi
3+
,Eu
3+
phosphors was 1.133%·K
-1
, and the maximum absolute sensitivity value was 0.73%·K
-1
, respectively. Therefore, Gd
2
ZnTiO
6
∶Bi
3+
,Eu
3+
phosphor is a potential non-contact optical temperature measurement material.
Gd2ZnTiO6∶Bi3+,Eu3+双钙钛矿荧光能量传递光学测温荧光强度比
Gd2ZnTiO6∶Bi3+,Eu3+double perovskitefluorescence energy transferoptical thermometryfluorescence intensity ratio
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