浏览全部资源
扫码关注微信
湖南师范大学化学化工学院 光能转换材料湖南省高校重点实验室, 湖南 长沙 410081
[ "吴家宇(1998-),男,江西吉安人,硕士研究生,2020年于江西农业大学获得学士学位,主要从事发光材料的研究。E-mail:wjy5688616@163.com" ]
[ "廉世勋(1964-),男,湖南沅陵人,博士,教授,博士生导师,2008年于湖南师范大学获得博士学位,主要从事无机发光材料(高效光能转换材料、高性能转光农膜、转光玻璃和植物生长补光灯)的研究。E-mail: sxlian@hunnu.edu.cn" ]
[ "邱忠贤(1987-),女,湖南衡阳人,博士,副教授,硕士生导师,2016年于湖南师范大学获得博士学位, 主要从事无机发光材料的设计、性能与应用的研究。E-mail: zxqiu@hunnu.edu.cn" ]
收稿日期:2022-09-04,
修回日期:2022-09-18,
纸质出版日期:2023-02-05
移动端阅览
吴家宇,张珍珍,李松等.孤立格位中的Cr3+近红外发射波长的设计与调控:以AMP2O7∶Cr3+为例[J].发光学报,2023,44(02):246-258.
WU Jiayu,ZHANG Zhenzhen,LI Song,et al.Design and Regulation of Near-infrared Emission Wavelength of Cr3+ in Isolated Lattice Sites: A Case Study of AMP2O7∶Cr3+[J].Chinese Journal of Luminescence,2023,44(02):246-258.
吴家宇,张珍珍,李松等.孤立格位中的Cr3+近红外发射波长的设计与调控:以AMP2O7∶Cr3+为例[J].发光学报,2023,44(02):246-258. DOI: 10.37188/CJL.20220320.
WU Jiayu,ZHANG Zhenzhen,LI Song,et al.Design and Regulation of Near-infrared Emission Wavelength of Cr3+ in Isolated Lattice Sites: A Case Study of AMP2O7∶Cr3+[J].Chinese Journal of Luminescence,2023,44(02):246-258. DOI: 10.37188/CJL.20220320.
近红外光谱调控对于开发新型近红外荧光粉至关重要。3d
3
电子构型的Cr
3+
具有波长可调谐的宽带近红外发光性质,是一种理想的近红外激活剂离子。由于d轨道对晶体场敏感,Cr
3+
离子发射波长强烈依赖于其配位晶体结构,明确配位结构与发光性质之间的构效关系是指导近红外荧光粉理性设计的理论基础。而实际上晶体结构复杂,影响局部配位结构性质的因素很多,难以形成明确的构效关系。
AM
P
2
O
7
(
A
=Li,K;
M
=Ga, Sc,In)系列焦磷酸盐晶体中具有孤立的[
M
O
6
]八面体结构特征,可为Cr
3+
提供孤立的配位环境,孤立格位大大减少了晶体结构的复杂性,为构效关系的建立提供了合理性保障。本文以
AM
P
2
O
7
∶Cr
3+
系列荧光粉为研究对象,Cr
3+
取代在孤立的[
M
O
6
]八面体中心格位,具有波长可调谐的近红外发光性质,其发射波长随
M
3+
和
A
+
组分变化而发生迁移,以Cr
3+
发射波长对孤立配位结构特征的依赖关系初步构建[
M
O
6
]—Cr
3+
近红外发射波长的构效关系,以期能为Cr
3+
近红外发射材料理性设计提供一些依据和思路。
Near-infrared (NIR) spectral modification is crucial for the development of NIR phosphors. With 3d
3
configuration, the Cr
3+
ion shows wavelength-controllable wide-band NIR emissions, which is an ideal NIR activator ion. Due to the sensitivity of d orbitals to crystal field, the emission wavelength of Cr
3+
strongly depends on its coordination structure. Clarifying the structure-function relationship between its coordination structure and luminescence properties is the theoretical basis to guide the rational design of NIR phosphors. In fact, limited by the complexity of the crystal structure, there are too many factors affecting the local coordination structure properties. A clarified structure-function relationship is still a serious challenge. A series of pyrophosphate crystals
AM
P
2
O
7
(
A=
Li, K;
M
=Ga, Sc, In) contain isolated [
M
O
6
] octahedron feature, which provides isolated coordination environment for Cr
3+
. The isolated coordination greatly suppresses the effect of the next-closed coordination structures and guarantees the reasonability of the related structure-function relationship. This paper studies the series of
AM
P
2
O
7
∶Cr
3+
phosphors. The Cr
3+
ions are introduced into the central site of the isolated [
M
O
6
] octahedra, which show wavelength-tunable NIR emissions depending on the composed
M
3+
and
A
+
. We build a preliminary structure-function relationship of [
M
O
6
]—NIR wavelength of Cr
3+
based on the correlation of Cr
3+
emissions and the isolated coordination structure features, which provides theoretical basis and ideas for rational design of Cr
3+
NIR emitting materials.
WEI Y , DANG P P , DAI Z , et al . Advances in near-infrared luminescent materials without Cr 3+ : crystal structure design, luminescence properties, and applications [J]. Chem. Mater. , 2021 , 33 ( 14 ): 5496 - 5526 . doi: 10.1021/acs.chemmater.1c01325 http://dx.doi.org/10.1021/acs.chemmater.1c01325
WANG Y Z , XIANG J Y , TANG Y , et al . A review of the application of near-infrared spectroscopy(NIRS) in forestry [J]. Appl. Spectrosc. Rev. , 2022 , 57 ( 4 ): 300 - 317 . doi: 10.1080/05704928.2021.1875481 http://dx.doi.org/10.1080/05704928.2021.1875481
FU X P , YING Y B . Food safety evaluation based on near infrared spectroscopy and imaging: a review [J]. Crit. Rev. Food Sci. Nutr. , 2016 , 56 ( 11 ): 1913 - 1924 . doi: 10.1080/10408398.2013.807418 http://dx.doi.org/10.1080/10408398.2013.807418
程丽娟 , 刘贵珊 , 万国玲 , 等 . 可见/近红外高光谱成像技术对长枣中葡萄糖含量的无损检测 [J]. 发光学报 , 2019 , 40 ( 8 ): 1055 - 1063 . doi: 10.3788/fgxb20194008.1055 http://dx.doi.org/10.3788/fgxb20194008.1055
CHENG L J , LIU G S , WAN G L , et al . Non-destructive detective of glucose contect in Lingwu jujube by Vis/NIR hyperspectral imaging technology [J]. Chin. J. Lumin. , 2019 , 40 ( 8 ): 1055 - 1063 . (in Chinese) . doi: 10.3788/fgxb20194008.1055 http://dx.doi.org/10.3788/fgxb20194008.1055
SAKUDO A . Near-infrared spectroscopy for medical applications: current status and future perspectives [J]. Clin. Chim. Acta , 2016 , 455 : 181 - 188 . doi: 10.1016/j.cca.2016.02.009 http://dx.doi.org/10.1016/j.cca.2016.02.009
刘映雪 , 朱福荣 . 近红外光的可视化及其应用 [J]. 液晶与显示 , 2021 , 36 ( 1 ): 78 - 104 . doi: 10.37188/CJLCD.2020-0287 http://dx.doi.org/10.37188/CJLCD.2020-0287
LIU Y S , ZHU F R . Visualization of near-infrared light and applications [J]. Chin. J. Liq. Cryst. Disp. , 2021 , 36 ( 1 ): 78 - 104 . (in English) . doi: 10.37188/CJLCD.2020-0287 http://dx.doi.org/10.37188/CJLCD.2020-0287
SCHUBERT E F , KIM J K . Solid-state light sources getting smart [J]. Science , 2005 , 308 ( 5726 ): 1274 - 1278 . doi: 10.1126/science.1108712 http://dx.doi.org/10.1126/science.1108712
张亮亮 , 张家骅 , 郝振东 , 等 . Cr 3+ 掺杂的宽带近红外荧光粉及其研究进展 [J]. 发光学报 , 2019 , 40 ( 12 ): 1449 - 1459 . doi: 10.3788/fgxb20194012.1449 http://dx.doi.org/10.3788/fgxb20194012.1449
ZHANG L L , ZHANG J H , HAO Z D , et al . Recent progress on Cr 3+ doped broad band NIR phosphors [J]. Chin. J. Lumin. , 2019 , 40 ( 12 ): 1449 - 1459 . (in Chinese) . doi: 10.3788/fgxb20194012.1449 http://dx.doi.org/10.3788/fgxb20194012.1449
FILIPPO R , TARALLI E , RAJTERI M . LEDs: sources and intrinsically bandwidth-limited detectors [J]. Sensors , 2017 , 17 ( 7 ): 1673-1-12 . doi: 10.3390/s17071673 http://dx.doi.org/10.3390/s17071673
XIA Z G , LIU Q L . Progress in discovery and structural design of color conversion phosphors for LEDs [J]. Prog. Mater. Sci. , 2016 , 84 : 59 - 117 . doi: 10.1016/j.pmatsci.2016.09.007 http://dx.doi.org/10.1016/j.pmatsci.2016.09.007
王长建 , 乔旭升 , 樊先平 . 蓝光LED激发Cr 3+ 掺杂宽带近红外荧光粉研究进展 [J]. 发光学报 , 2022 , 43 ( 12 ): 1855 - 1870 . doi: 10.37188/cjl.20220271 http://dx.doi.org/10.37188/cjl.20220271
WANG C J , QIAO X S , FAN X P . Research progress on blue LED excited Cr 3+ doped phosphors with broad-band near- infrared luminescence [J]. Chin. J. Lumin. , 2022 , 43 ( 12 ): 1855 - 1870 . (in Chinese) . doi: 10.37188/cjl.20220271 http://dx.doi.org/10.37188/cjl.20220271
CHEN X H , SONG E H , ZHOU Y Y , et al . Distorted octahedral site occupation-induced high-efficiency broadband near-infrared emission in LiScGe 2 O 6 ∶Cr 3+ phosphor [J]. J. Mater. Chem. C , 2021 , 9 ( 39 ): 13640 - 13646 . doi: 10.1039/D1TC03057D http://dx.doi.org/10.1039/D1TC03057D
XU X X , SHAO Q Y , YAO L Q , et al . Highly efficient and thermally stable Cr 3+ -activated silicate phosphors for broadband near-infrared LED applications [J]. Chem. Eng. J. , 2020 , 383 : 123108-1 - 8 . doi: 10.1016/j.cej.2019.123108 http://dx.doi.org/10.1016/j.cej.2019.123108
DE GUZMAN G N A , RAJENDRAN V , BAO Z , et al . Multi-site cation control of ultra-broadband near-infrared phosphors for application in light-emitting diodes [J]. Inorg. Chem. , 2020 , 59 ( 20 ): 15101 - 15110 . doi: 10.1021/acs.inorgchem.0c02055 http://dx.doi.org/10.1021/acs.inorgchem.0c02055
SHAO Q Y , DING H , YAO L Q , et al . Photoluminescence properties of a ScBO 3 ∶Cr 3+ phosphor and its applications for broadband near-infrared LEDs [J]. RSC Adv. , 2018 , 8 ( 22 ): 12035 - 12042 . doi: 10.1039/c8ra01084f http://dx.doi.org/10.1039/c8ra01084f
YAO L Q , SHAO Q Y , XU X X , et al . Broadband emission of single-phase Ca 3 Sc 2 Si 3 O 12 ∶Cr 3+ / Ln 3+ ( Ln =Nd, Yb, Ce) phosphors for novel solid-state light sources with visible to near-infrared light output [J]. Ceram. Int. , 2019 , 45 ( 11 ): 14249 - 14255 . doi: 10.1016/j.ceramint.2019.04.133 http://dx.doi.org/10.1016/j.ceramint.2019.04.133
ZHANG L L , ZHANG S , HAO Z D , et al . A high efficiency broad-band near-infrared Ca 2 LuZr 2 Al 3 O 12 ∶Cr 3+ garnet phosphor for blue LED chips [J]. J. Mater. Chem. C , 2018 , 6 ( 18 ): 4967 - 4976 . doi: 10.1039/C8TC01216D http://dx.doi.org/10.1039/C8TC01216D
ZHAO F Y , CAI H , SONG Z , et al . Structural confinement for Cr 3+ activators toward efficient near-infrared phosphors with suppressed concentration quenching [J]. Chem. Mater. , 2021 , 33 ( 10 ): 3621 - 3630 . doi: 10.1021/acs.chemmater.1c00441 http://dx.doi.org/10.1021/acs.chemmater.1c00441
ZHANG Z C , MA C G , GAUTIER R , et al . Structural confinement toward giant enhancement of red emission in Mn 2+ -based phosphors [J]. Adv. Funct. Mater. , 2018 , 28 ( 41 ): 1804150-1-7 . doi: 10.1002/adfm.201804150 http://dx.doi.org/10.1002/adfm.201804150
YAO L Q , SHAO Q Y , HAN S Y , et al . Enhancing near-infrared photoluminescence intensity and spectral properties in Yb 3+ codoped LiScP 2 O 7 ∶Cr 3+ [J]. Chem. Mater. , 2020 , 32 ( 6 ): 2430 - 2439 . doi: 10.1021/acs.chemmater.9b04934 http://dx.doi.org/10.1021/acs.chemmater.9b04934
YUAN C X , LI R Y , LIU Y F , et al . Efficient and broadband LiGaP 2 O 7 ∶Cr 3+ phosphors for smart near-infrared light-emitting diodes [J]. Laser Photonics Rev. , 2021 , 15 ( 11 ): 2100227-1-8 . doi: 10.1002/lpor.202100227 http://dx.doi.org/10.1002/lpor.202100227
ZHANG H S , ZHONG J Y , ZHANG X L , et al . Achieving an ultra-broadband infrared emission through efficient energy transfer in LiInP 2 O 7 ∶Cr 3+ ,Yb 3+ phosphor [J]. J. Alloys Compd. , 2022 , 894 : 162386-1 - 8 . doi: 10.1016/j.jallcom.2021.162386 http://dx.doi.org/10.1016/j.jallcom.2021.162386
ZHONG J Y , LI C J , ZHAO W R , et al . Accessing high-power near-infrared spectroscopy using Cr 3+ -substituted metal phosphate phosphors [J]. Chem. Mater. , 2022 , 34 ( 1 ): 337 - 344 . doi: 10.1021/acs.chemmater.1c03671 http://dx.doi.org/10.1021/acs.chemmater.1c03671
ZHAO F Y , CAI H , ZHANG S Y , et al . Octahedron-dependent near-infrared luminescence in Cr 3+ -activated phosphors [J]. Mater. Today Chem. , 2022 , 23 : 100704-1 - 8 . doi: 10.1016/j.mtchem.2021.100704 http://dx.doi.org/10.1016/j.mtchem.2021.100704
LIU T Y , CAI H , MAO N , et al . Efficient near-infrared pyroxene phosphor LiInGe 2 O 6 ∶Cr 3+ for NIR spectroscopy application [J]. J. Am. Ceram. Soc. , 2021 , 104 ( 9 ): 4577 - 4584 . doi: 10.1111/jace.17856 http://dx.doi.org/10.1111/jace.17856
ADACHI S . Spectroscopy of Cr 3+ activator: Tanabe-Sugano diagram and Racah parameter analysis [J]. J. Lumin. , 2021 , 232 : 117844-1 - 7 . doi: 10.1016/j.jlumin.2020.117844 http://dx.doi.org/10.1016/j.jlumin.2020.117844
ADACHI S . Luminescence spectroscopy of 3d 3 (Mn 4+ , Cr 3+ ) ions in multiple octahedral-site phosphors [J]. ECS J. Solid State Sci. Technol. , 2022 , 11 ( 4 ): 046002-1-9 . doi: 10.1149/2162-8777/ac63e4 http://dx.doi.org/10.1149/2162-8777/ac63e4
ADACHI S . Luminescence spectroscopy of Cr 3+ in an oxide: a strong or weak crystal-field phosphor? [J]. J. Lumin. , 2021 , 234 : 117965-1 - 4 . doi: 10.1016/j.jlumin.2021.117965 http://dx.doi.org/10.1016/j.jlumin.2021.117965
FANG M H , LEAÑO J L JR , LIU R S . Control of narrow-band emission in phosphor materials for application in light-emitting diodes [J]. ACS Energy Lett. , 2018 , 3 ( 10 ): 2573 - 2586 . doi: 10.1021/acsenergylett.8b01408 http://dx.doi.org/10.1021/acsenergylett.8b01408
ROBINSON K , GIBBS G V , RIBBE P H . Quadratic elongation: a quantitative measure of distortion in coordination polyhedra [J]. Science , 1971 , 172 ( 3983 ): 567 - 570 . doi: 10.1126/science.172.3983.567 http://dx.doi.org/10.1126/science.172.3983.567
MENG X Y , WANG Z J , QIU K L , et al . Design of a novel near-infrared phosphor by controlling the cationic coordination environment [J]. Cryst. Growth Des. , 2018 , 18 ( 8 ): 4691 - 4700 . doi: 10.1021/acs.cgd.8b00672 http://dx.doi.org/10.1021/acs.cgd.8b00672
GAO T Y , ZHUANG W D , LIU R H , et al . Design and control of the luminescence in Cr 3+ -doped NIR phosphors via crystal field engineering [J]. J. Alloys Compd. , 2020 , 848 : 156557-1 - 9 . doi: 10.1016/j.jallcom.2020.156557 http://dx.doi.org/10.1016/j.jallcom.2020.156557
HE F Q , SONG E H , ZHOU Y Y , et al . A general ammonium salt assisted synthesis strategy for Cr 3+ ‐doped hexafluorides with highly efficient near infrared emissions [J]. Adv. Funct. Mater. , 2021 , 31 ( 36 ): 2103743-1-11 . doi: 10.1002/adfm.202103743 http://dx.doi.org/10.1002/adfm.202103743
姬海鹏 , 张宗涛 , XU Jian , 等 . Mn 4+ 激活氧氟化物红光荧光粉的研究进展 [J]. 无机材料学报 , 2020 , 35 ( 8 ): 847 - 856 . doi: 10.15541/jim20190554 http://dx.doi.org/10.15541/jim20190554
JI H P , ZHANG Z T , XU J , et al . Advance in red-emitting Mn 4+ -activated oxyfluoride phosphors [J]. J. Inorg. Mater. , 2020 , 35 ( 8 ): 847 - 856 . (in Chinese) . doi: 10.15541/jim20190554 http://dx.doi.org/10.15541/jim20190554
姬海鹏 . 荧光粉中激活剂离子掺杂格位分析 [J]. 发光学报 , 2022 , 43 ( 1 ): 26 - 41 . doi: 10.37188/CJL.20210309 http://dx.doi.org/10.37188/CJL.20210309
JI H P . Analysis of site-occupation of activator in phosphors [J]. Chin. J. Lumin. , 2022 , 43 ( 1 ): 26 - 41 . (in Chinese) . doi: 10.37188/CJL.20210309 http://dx.doi.org/10.37188/CJL.20210309
TRUEBA A , GARCÍA-LASTRA J M , GARCIA-FERNANDEZ P , et al . Cr 3+ -doped fluorides and oxides: role of internal fields and limitations of the Tanabe-Sugano approach [J]. J. Phys. Chem. A , 2011 , 115 ( 46 ): 13399 - 13406 . doi: 10.1021/jp207249w http://dx.doi.org/10.1021/jp207249w
ZHOU Y X , YI S P , FANG Z X , et al . Research on a new type of near-infrared phosphor Li 2 MgZrO 4 ∶Cr 3+ - synthesis, crystal structure, photoluminescence and thermal stability [J]. Opt. Mater. , 2021 , 117 : 111209-1 - 7 . doi: 10.1016/j.optmat.2021.111209 http://dx.doi.org/10.1016/j.optmat.2021.111209
0
浏览量
412
下载量
7
CSCD
关联资源
相关文章
相关作者
相关机构