浏览全部资源
扫码关注微信
1.广西科技大学 生物与化学工程学院, 广西糖资源绿色加工重点实验室, 广西 柳州 545006
2.蔗糖产业省部共建协同创新中心, 广西 南宁 530004
[ "崔美佳(1998-),女,黑龙江哈尔滨人,硕士研究生,2020年于齐齐哈尔大学获得学士学位,主要从事纳米材料的研究。E-mail:1870574051@qq.com" ]
[ "黄文艺(1975-),男,广西南宁人,博士,高级实验师,2009年于南京大学获得博士学位,主要从事纳米材料方面的研究。E-mail:hwylz18@163.com" ]
收稿日期:2022-08-22,
修回日期:2022-09-12,
纸质出版日期:2023-02-05
移动端阅览
崔美佳,黄秋梅,黄文艺等.水溶性Sm∶ZnO⁃NH2量子点荧光探针制备及其用于选择性检测多巴胺[J].发光学报,2023,44(02):374-386.
CUI Meijia,HUANG Qiumei,HUANG Wenyi,et al.Preparation of Water-soluble Sm∶ZnO-NH2 QDs Fluorescent Probe and Its Application for Selective Detection of Dopamine[J].Chinese Journal of Luminescence,2023,44(02):374-386.
崔美佳,黄秋梅,黄文艺等.水溶性Sm∶ZnO⁃NH2量子点荧光探针制备及其用于选择性检测多巴胺[J].发光学报,2023,44(02):374-386. DOI: 10.37188/CJL.20220296.
CUI Meijia,HUANG Qiumei,HUANG Wenyi,et al.Preparation of Water-soluble Sm∶ZnO-NH2 QDs Fluorescent Probe and Its Application for Selective Detection of Dopamine[J].Chinese Journal of Luminescence,2023,44(02):374-386. DOI: 10.37188/CJL.20220296.
采用3⁃氨丙基三乙氧基硅烷(APTEs)封端氧化锌量子点(ZnO QDs)的方式,制备了一种荧光性能稳定的水溶性Sm∶ZnO⁃NH
2
QDs荧光探针。通过透射电子显微镜(TEM)、X射线衍射(XRD)、X射线光电子能谱(XPS)、傅里叶变换红外光谱仪(FT⁃IR)、纳米粒度和Zeta电位仪(DLS)、稳瞬态荧光光谱仪(PL)等对材料进行表征。最优化条件下制备的该探针在水中具有良好的荧光性能,在4 ℃下贮存10 d后其荧光强度仍保留92%。基于该探针的荧光可以直接被多巴胺(DA)选择性猝灭,建立了一种选择性检测DA含量的荧光分析新方法,在50~1 600 ng/mL浓度内,该探针呈现良好的线性关系(
y
=0.4639
x
+ 0.008530,
R
2
=0.996 3),检出限(LOD)为1.08 ng/mL,具有较好的稳定性和重现性,并成功应用于人体尿液样品的检测,回收率为98.18%~107.84%。
In this paper, a water-soluble Sm∶ZnO-NH
2
QDs fluorescent probe with stable fluorescence performance was prepared by means of 3-aminopropyltriethoxysilane(APTEs) terminated zinc oxide quantum dots(ZnO QDs). Materials were characterized by transmission electron microscopy(TEM), X-ray diffraction(XRD), X-ray photoelectron spectroscopy(XPS), Fourier transform infrared spectrometer(FT-IR), nanoparticles size and Zeta potentiometers(DLS), steady transient fluorescence spectrometer(PL),
etc
. The probe prepared under optimal conditions has good fluorescence performance in water, and its fluorescence intensity remains 92% after 10 d of storage at 4 ℃. Based on the probe fluorescence can be directly quenched by dopamine(DA), a new method for fluorescence analysis for selective detection of DA content was established, and the probe showed a good linear relationship(
y
=0.46393
x
+0.008530,
R
2
=0.996 3) and a detection limit of 1.08 ng/mL within a concentration of 50-1 600 ng/mL, which had good stability and reproducibility. It was successfully applied to the detection of human urine samples, and the recovery rate was 98.18% to 107.84%.
ENSAFI A A , ZAKERY M , REZAEI B . An optical sensor with specific binding sites for the detection of thioridazine hydrochloride based on ZnO-QDs coated with molecularly imprinted polymer [J]. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. , 2019 , 206 : 460 - 465 . doi: 10.1016/j.saa.2018.08.040 http://dx.doi.org/10.1016/j.saa.2018.08.040
ROSHINI A , JAGADEESAN S , ARIVAZHAGAN L , et al . pH-sensitive tangeretin-ZnO quantum dots exert apoptotic and anti-metastatic effects in metastatic lung cancer cell line [J]. Mat. Sci. Eng.: C, 2018 , 92: 477 - 488 . doi: 10.1016/j.msec.2018.06.073 http://dx.doi.org/10.1016/j.msec.2018.06.073
YE Y F . Photoluminescence property adjustment of ZnO quantum dots synthesized via sol‑gel method [J]. J. Mater. Sci.: Mater. Electron. , 2018 , 29 ( 6 ): 4967 - 4974 . doi: 10.1007/s10854-017-8457-2 http://dx.doi.org/10.1007/s10854-017-8457-2
BADILLI U , MOLLARASOULI F , BAKIRHAN N K , et al . Role of quantum dots in pharmaceutical and biomedical analysis, and its application in drug delivery [J]. TrAC Trends Anal. Chem. , 2020 , 131 : 116013-1 - 12 . doi: 10.1016/j.trac.2020.116013 http://dx.doi.org/10.1016/j.trac.2020.116013
WOLSKA E , KASZEWSKI J , KIEBIK P , et al . Rare earth activated ZnO nanoparticles as biomarkers [J]. Opt. Mater. , 2014 , 36 ( 10 ): 1655 - 1659 . doi: 10.1016/j.optmat.2013.12.032 http://dx.doi.org/10.1016/j.optmat.2013.12.032
MATSUYAMA K , IHSAN N , IRIE K , et al . Bioimaging application of highly luminescent silica-coated ZnO-nanoparticle quantum dots with biotin [J]. J. Colloid Interface Sci. , 2013 , 399 : 19 - 25 . doi: 10.1016/j.jcis.2013.02.047 http://dx.doi.org/10.1016/j.jcis.2013.02.047
张佳楠 , 常开文 , 李琼 , 等 . 半导体聚合物纳米荧光探针的制备及生物应用研究进展 [J]. 发光学报 , 2015 , 36 ( 7 ): 725 - 737 . doi: 10.3788/fgxb20153607.0725 http://dx.doi.org/10.3788/fgxb20153607.0725
ZHANG J N , CHANG K W , LI Q , et al . Preparation, regulation and biological application of fluorescent semiconducting polymer dots [J]. Chin. J. Lumin. , 2015 , 36 ( 7 ): 725 - 737 . (in Chinese) . doi: 10.3788/fgxb20153607.0725 http://dx.doi.org/10.3788/fgxb20153607.0725
LUO C , HOU C Y , ZHANG Q H , et al . A noise-reduced broad-spectrum photodetector based on reagent-free electrophoretic assembled flexible ZnO/rGO films [J]. Appl. Surf. Sci. , 2019 , 469 : 113 - 117 . doi: 10.1016/j.apsusc.2018.11.012 http://dx.doi.org/10.1016/j.apsusc.2018.11.012
SUN Y J , YANG H Y , ZHAO Z T , et al . Fabrication of ZnO quantum dots@SnO 2 hollow nanospheres hybrid hierarchical structures for effectively detecting formaldehyde [J]. Sens. Actuators B: Chem. , 2020 , 318 : 128222-1 - 10 . doi: 10.1016/j.snb.2020.128222 http://dx.doi.org/10.1016/j.snb.2020.128222
JUNG H , CHO W , YOO R , et al . Highly selective real-time detection of breath acetone by using ZnO quantum dots with a miniaturized gas chromatographic column [J]. Sens. Actuators B: Chem. , 2018 , 274 : 527 - 532 . doi: 10.1016/j.snb.2018.07.144 http://dx.doi.org/10.1016/j.snb.2018.07.144
LI L , ZHAI T Y , BANDO Y , et al . Recent progress of one-dimensional ZnO nanostructured solar cells [J]. Nano Energy , 2012 , 1 ( 1 ): 91 - 106 . doi: 10.1016/j.nanoen.2011.10.005 http://dx.doi.org/10.1016/j.nanoen.2011.10.005
VANHEUSDEN K , WARREN W L , SEAGER C H , et al . Mechanisms behind green photoluminescence in ZnO phosphor powders [J]. J. Appl. Phys. , 1996 , 79 ( 10 ): 7983 - 7990 . doi: 10.1063/1.362349 http://dx.doi.org/10.1063/1.362349
XIONG H M , SHCHUKIN D G , MÖHWALD H , et al . Sonochemical synthesis of highly luminescent zinc oxide nanoparticles doped with magnesium(II) [J]. Angew. Chem. Int. Ed. , 2009 , 48 ( 15 ): 2727 - 2731 . doi: 10.1002/anie.200805590 http://dx.doi.org/10.1002/anie.200805590
HUANG W Y , LV X W , TAN J L , et al . Regulable preparation of the oxygen vacancy of ZnO QDs and their fluorescence performance [J]. J. Mol. Struct. , 2019 , 1195 : 653 - 658 . doi: 10.1016/j.molstruc.2019.05.105 http://dx.doi.org/10.1016/j.molstruc.2019.05.105
JAGGI N , RATHEE N . Samarium 3+ -doped CdSe quantum dots for improved electro-optical properties [J]. Mater. Today: Proc. , 2019 , 16 : 201 - 205 . doi: 10.1016/j.matpr.2019.05.246 http://dx.doi.org/10.1016/j.matpr.2019.05.246
YANG J H , LI X , LANG J H , et al . Effects of mineralizing agent on the morphologies and photoluminescence properties of Eu 3+ -doped ZnO nanomaterials [J]. J. Alloys Compd. , 2011 , 509 ( 41 ): 10025 - 10031 . doi: 10.1016/j.jallcom.2011.08.021 http://dx.doi.org/10.1016/j.jallcom.2011.08.021
LU G , YU G H , KONG X , et al . Porphyrin/MoS 2 film for ultrasensitive dopamine detection [J]. Inorg. Chem. Commun. , 2019 , 110 : 107591-1 - 5 . doi: 10.1016/j.inoche.2019.107591 http://dx.doi.org/10.1016/j.inoche.2019.107591
BEREZHNOV A V , FEDOTOVA E I , SERGEEV A I , et al . Dopamine controls neuronal spontaneous calcium oscillations via astrocytic signal [J]. Cell Calcium , 2021 , 94 : 102359 . doi: 10.1016/j.ceca.2021.102359 http://dx.doi.org/10.1016/j.ceca.2021.102359
IMMANUEL S , APARNA T K , SIVASUBRAMANIAN R . A facile preparation of Au-SiO 2 nanocomposite for simultaneous electrochemical detection of dopamine and uric acid [J]. Surf. Interfaces , 2019 , 14 : 82 - 91 . doi: 10.1016/j.surfin.2018.11.010 http://dx.doi.org/10.1016/j.surfin.2018.11.010
WEI X , ZHANG Z D , WANG Z H . A simple dopamine detection method based on fluorescence analysis and dopamine polymerization [J]. Microchem. J. , 2019 , 145 : 55 - 58 . doi: 10.1016/j.microc.2018.10.004 http://dx.doi.org/10.1016/j.microc.2018.10.004
KADAM V V , BALAKRISHNAN R M , PONNAN ETTIYAPPAN J , et al . Sensing of p -nitrophenol in aqueous solution using zinc oxide quantum dots coated with APTES [J]. Environ. Nanotechnol. , Monit. Manage., 2021 , 16 : 100474 . doi: 10.1016/j.enmm.2021.100474 http://dx.doi.org/10.1016/j.enmm.2021.100474
ZHOU T , SU Z , TU Y F , et al . Determination of dopamine based on its enhancement of gold-silver nanocluster fluorescence [J]. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. , 2021 , 252 : 119519-1 - 6 . doi: 10.1016/j.saa.2021.119519 http://dx.doi.org/10.1016/j.saa.2021.119519
HANNAH S , AL-HATMI M , GRAY L , et al . Low-cost, thin-film, mass-manufacturable carbon electrodes for detection of the neurotransmitter dopamine [J]. Bioelectrochemistry , 2020 , 133 : 107480-1 - 9 . doi: 10.1016/j.bioelechem.2020.107480 http://dx.doi.org/10.1016/j.bioelechem.2020.107480
XU B B , SU Y Y , LI L , et al . Thiol-functionalized single-layered MoS 2 nanosheet as a photoluminescence sensing platform via charge transfer for dopamine detection [J]. Sens. Actuators B: Chem. , 2017 , 246 : 380 - 388 . doi: 10.1016/j.snb.2017.02.110 http://dx.doi.org/10.1016/j.snb.2017.02.110
ZHAO D , SONG H J , HAO L Y , et al . Luminescent ZnO quantum dots for sensitive and selective detection of dopamine [J]. Talanta , 2013 , 107 : 133 - 139 . doi: 10.1016/j.talanta.2013.01.006 http://dx.doi.org/10.1016/j.talanta.2013.01.006
HUANG W Y , BAI D W , LI L J , et al . The synthesis of ultrasmall ZnO@PEG nanoparticles and its fluorescence properties [J]. J. Sol⁃Gel. Sci. Technol. , 2015 , 74 ( 3 ): 718 - 725 . doi: 10.1007/s10971-015-3653-0 http://dx.doi.org/10.1007/s10971-015-3653-0
黄秋梅 , 吕晓威 , 谭嘉麟 , 等 . Sm掺杂ZnO QDs的制备及其荧光性能研究 [J]. 无机盐工业 , 2020 , 52 ( 8 ): 30 - 35 . doi: 10.11962/1006-4990.2019-0498 http://dx.doi.org/10.11962/1006-4990.2019-0498
HUANG Q M , LÜ X W , TAN J L , et al . Preparation of Sm doped ZnO QDs and its fluorescence performance [J]. Inorg. Chem. Ind. , 2020 , 52 ( 8 ): 30 - 35 . (in Chinese) . doi: 10.11962/1006-4990.2019-0498 http://dx.doi.org/10.11962/1006-4990.2019-0498
CAGLAR Y , CAGLAR M , ILICAN S . XRD, SEM, XPS studies of Sb doped ZnO films and electrical properties of its based Schottky diodes [J]. Optik , 2018 , 164 : 424 - 432 . doi: 10.1016/j.ijleo.2018.03.017 http://dx.doi.org/10.1016/j.ijleo.2018.03.017
WANG D D , XING G Z , YANG J H , et al . Dependence of energy transfer and photoluminescence on tailored defects in Eu-doped ZnO nanosheets-based microflowers [J]. J. Alloys Compd. , 2010 , 504 ( 1 ): 22 - 26 . doi: 10.1016/j.jallcom.2010.05.105 http://dx.doi.org/10.1016/j.jallcom.2010.05.105
THOOL G S , ARUNAKUMARI M , SINGH A K , et al . Shape tunable synthesis of Eu- and Sm- doped ZnO microstructures: a morphological evaluation [J]. Bull. Mater. Sci. , 2015 , 38 ( 6 ): 1519 - 1525 . doi: 10.1007/s12034-015-0967-z http://dx.doi.org/10.1007/s12034-015-0967-z
AHMED M A M , MWANKEMWA B S , CARLESCHI E , et al . Effect of Sm doping ZnO nanorods on structural optical and electrical properties of Schottky diodes prepared by chemical bath deposition [J]. Mater. Sci. Semicond. Process. , 2018 , 79 : 53 - 60 . doi: 10.1016/j.mssp.2018.02.003 http://dx.doi.org/10.1016/j.mssp.2018.02.003
HAN N , WU X F , CHAI L Y , et al . Counterintuitive sensing mechanism of ZnO nanoparticle based gas sensors [J]. Sens. Actuators B: Chem. , 2010 , 150 ( 1 ): 230 - 238 . doi: 10.1016/j.snb.2010.07.009 http://dx.doi.org/10.1016/j.snb.2010.07.009
AHMED M A , COETSEE L , MEYER W E , et al . Influence (Ce and Sm) co-doping ZnO nanorods on the structural, optical and electrical properties of the fabricated Schottky diode using chemical bath deposition [J]. J. Alloys Compd. , 2019 , 810: 15 1929-1-10 . doi: 10.1016/j.jallcom.2019.151929 http://dx.doi.org/10.1016/j.jallcom.2019.151929
崔葆 , 黄秋梅 , 戎西林 , 等 . 开关式氧化锌量子点荧光探针制备及其特异性检测Cu 2+ 应用 [J]. 发光学报 , 2022 , 43 ( 4 ): 620 - 632 . doi: 10.37188/cjl.20210408 http://dx.doi.org/10.37188/cjl.20210408
CUI B , HUANG Q M , RONG X L , et al . Preparation of switchable ZnO-NH 2 QDs fluorescent probe and its application in specific detection of Cu 2+ [J]. Chin. J. Lumin. , 2022 , 43 ( 4 ): 620 - 632 . (in Chinese) . doi: 10.37188/cjl.20210408 http://dx.doi.org/10.37188/cjl.20210408
SINGH J , SINGH R C . Enhancement of optical, dielectric and transport properties of (Sm, V) co-doped ZnO system and structure-property correlations [J]. Ceram. Int. , 2021 , 47 ( 8 ): 10611 - 10627 . doi: 10.1016/j.ceramint.2020.12.174 http://dx.doi.org/10.1016/j.ceramint.2020.12.174
ZOU T , XING X X , YANG Y , et al . Water-soluble ZnO quantum dots modified by (3-aminopropyl)triethoxysilane: the promising fluorescent probe for the selective detection of Cu 2+ ion in drinking water [J]. J. Alloys Compd. , 2020 , 825 : 153904-1 - 11 . doi: 10.1016/j.jallcom.2020.153904 http://dx.doi.org/10.1016/j.jallcom.2020.153904
SUN L W , SHI H Q , LI W N , et al . Lanthanum-doped ZnO quantum dots with greatly enhanced fluorescent quantum yield [J]. J. Mater. Chem. , 2012 , 22 ( 17 ): 8221 - 8227 . doi: 10.1039/c2jm00040g http://dx.doi.org/10.1039/c2jm00040g
TALLURI B , PRASAD E , THOMAS T . Impact of solvent on the formation and optical properties of digestively ripened, ultra-small ( r < 2 nm) copper oxide quantum dots [J]. J. Mol. Liq. , 2018 , 265 : 771 - 778 . doi: 10.1016/j.molliq.2018.05.069 http://dx.doi.org/10.1016/j.molliq.2018.05.069
GHIMIRE S , BIJU V . Relations of exciton dynamics in quantum dots to photoluminescence, lasing, and energy harvesting [J]. J. Photochem. Photobiol. C: Photochem. Rev. , 2018 , 34 : 137 - 151 . doi: 10.1016/j.jphotochemrev.2018.01.004 http://dx.doi.org/10.1016/j.jphotochemrev.2018.01.004
HARANATH D , SAHAI S , JOSHI A G , et al . Investigation of confinement effects in ZnO quantum dots [J]. Nanotechnology , 2009 , 20 ( 42 ): 425701-1-7 . doi: 10.1088/0957-4484/20/42/425701 http://dx.doi.org/10.1088/0957-4484/20/42/425701
MOGHADDAM E , YOUZBASHI A A , KAZEMZADEH A , et al . Photoluminescence investigation of ZnO quantum dots surface modified with silane coupling agent as a capping agent [J]. J. Lumin. , 2015 , 168 : 158 - 162 . doi: 10.1016/j.jlumin.2015.08.008 http://dx.doi.org/10.1016/j.jlumin.2015.08.008
WANG Z Y , WANG X Y , ZHU X S , et al . Fabrication of non-destructive and enhanced electrochemiluminescence interface for reusable detection of cell-released dopamine [J]. Sens. Actuators B: Chem. , 2019 , 285 : 438 - 444 . doi: 10.1016/j.snb.2019.01.087 http://dx.doi.org/10.1016/j.snb.2019.01.087
SHERVEDANI R K , AMINI A . Direct electrochemistry of dopamine on gold—Agaricus bisporus laccase enzyme electrode: characterization and quantitative detection [J]. Bioelectrochemistry , 2012 , 84 : 25 - 31 . doi: 10.1016/j.bioelechem.2011.10.004 http://dx.doi.org/10.1016/j.bioelechem.2011.10.004
SCHÖNING M J , JACOBS M , MUCK A , et al . Amperometric PDMS/glass capillary electrophoresis-based biosensor microchip for catechol and dopamine detection [J]. Sens. Actuators B: Chem. , 2005 , 108 ( 1-2 ): 688 - 694 . doi: 10.1016/j.snb.2004.11.032 http://dx.doi.org/10.1016/j.snb.2004.11.032
QIN X , YUAN C L , SHI R , et al . Colorimetric detection of dopamine based on iodine-mediated etching of gold nanorods [J]. Chin. J. Anal. Chem. , 2021 , 49 ( 1 ): 60 - 67 . doi: 10.1016/s1872-2040(20)60073-1 http://dx.doi.org/10.1016/s1872-2040(20)60073-1
LI F , GAO J , LI Y J , et al . Selective and sensitive determination of celastrol in traditional Chinese medicine based on molecularly imprinted polymers modified Mn-doped ZnS quantum dots optosensing materials [J]. Colloids Surf . B: Biointerfaces, 2020 , 190 : 110929-1 - 9 . doi: 10.1016/j.colsurfb.2020.110929 http://dx.doi.org/10.1016/j.colsurfb.2020.110929
HAGHANI S K , ENSAFI A A , KAZEMIFARD N , et al . Development of a selective and sensitive chlorogenic acid fluorimetric sensor using molecularly imprinted polymer ZnO quantum dots [J]. IEEE Sens. J. , 2020 , 20 ( 11 ): 5691 - 5697 . doi: 10.1109/jsen.2020.2972040 http://dx.doi.org/10.1109/jsen.2020.2972040
HE K , SHEN C , ZHU Y Q , et al . Stable luminescent CsPbI 3 quantum dots passivated by (3-Aminopropyl)triethoxysilane [J]. Langmuir , 2020 , 36 ( 34 ): 10210 - 10217 . doi: 10.1021/acs.langmuir.0c01688 http://dx.doi.org/10.1021/acs.langmuir.0c01688
0
浏览量
273
下载量
2
CSCD
关联资源
相关文章
相关作者
相关机构