2D/3D混合Sn基钙钛矿/SnO<sub>2</sub>异质结光探测器

苏子生; 张璐; 胡跃; 姚广平; 王丽丹

doi:10.37188/CJL.20220107

您当前的位置：

首页 >

文章列表页 >

2D/3D混合Sn基钙钛矿/SnO₂异质结光探测器

器件制备及器件物理 | 更新时间：2022-08-01

- 2D/3D混合Sn基钙钛矿/SnO₂异质结光探测器
  增强出版
- Photodetectors Based on A 2D/3D Hybrid Tin Perovskite/SnO₂Heterojunction
- 发光学报 2022年43卷第7期页码：1121-1129
- 作者机构：
  
  1.泉州师范学院物理与信息工程学院福建省先进微纳光子技术与器件重点实验室，福建泉州　362000
  2.泉州师范学院化工与材料学院，福建泉州　362000
- 作者简介：
  
  [ "苏子生（1981-），男，福建闽清人，博士，教授，2009年于中国科学院长春光学精密机械与物理研究所获得博士学位，主要从事有机光电材料与器件的研究。Email: suzs@qztc. edu. cn" ]
  [ "王丽丹（1981-），女，吉林省吉林市人，博士，副教授，2011年于中国科学院长春光学精密机械与物理研究所获得博士学位，主要从事纳米半导体材料与器件的研究。" ]
- 基金信息：
  
  福建省自然科学基金面上项目(2019J01729;2020J01778);泉州市科技计划(2020C025R)
- DOI：10.37188/CJL.20220107
  中图分类号： O475.31;O482.7
- 纸质出版日期：2022-07-05，
  
  收稿日期：2022-03-26，
  
  修回日期：2022-04-13，
扫描看全文
苏子生,张璐,胡跃等.2D/3D混合Sn基钙钛矿/SnO₂异质结光探测器[J].发光学报,2022,43(07):1121-1129.

SU Zi-sheng,ZHANG Lu,HU Yue,et al.Photodetectors Based on A 2D/3D Hybrid Tin Perovskite/SnO₂Heterojunction[J].Chinese Journal of Luminescence,2022,43(07):1121-1129.
苏子生,张璐,胡跃等.2D/3D混合Sn基钙钛矿/SnO₂异质结光探测器[J].发光学报,2022,43(07):1121-1129. DOI： 10.37188/CJL.20220107.

SU Zi-sheng,ZHANG Lu,HU Yue,et al.Photodetectors Based on A 2D/3D Hybrid Tin Perovskite/SnO₂Heterojunction[J].Chinese Journal of Luminescence,2022,43(07):1121-1129. DOI： 10.37188/CJL.20220107.

摘要

制备了平面结构2D/3D混合钙钛矿（PEA）

0.15

0.85

SnI

/SnO

异质结光探测器。研究发现，SnO

薄膜的引入可以调控（PEA）

0.15

0.85

SnI

薄膜的晶体生长过程，有助于获得致密的连续薄膜。在520 nm单色光辐照下，器件的响应度高达3.19×10

A/W，相应的探测率为6.39×10

Jones。在808 nm单色光辐照下，器件的响应度和探测器率也可分别达到1.70×10

A/W和7.28×10

Jones。相关性能明显高于（PEA）

0.15

0.85

SnI

单层薄膜光探测器。器件性能的提高一方面是由于钙钛矿薄膜表面形貌的改善，提高了器件的吸收效率和载流子收集效率；另一方面是由于（PEA）

0.15

0.85

SnI

和SnO

之间形成了p⁃n结结构，从而有效提高了钙钛矿薄膜中的光生电子⁃空穴对的分离效率，降低了电子和空穴的复合几率。同时，（PEA）

0.15

0.85

SnI

/SnO

界面处特殊的能级结构也可诱导器件产生光电导增益。

Abstract

Planar structure photodetector based on a 2D/3D hybrid perovskite （PEA）

0.15

0.85

SnI

/SnO

heterojunction was constructed. It is found that the inserted SnO

layer can manipulate the crystal growth process of the （PEA）

0.15

0.85

SnI

film， benefiting to form a dense and continued film. Under illumination of a 520 nm monochromatic light， the device shows a high response of 3.19×10

A/W， corresponding to a detectivity of 6.39×10

Jones. While under illumination of an 808 nm monochromatic light， the device also shows a response of 1.70×10

A/W and a detectivity of 7.28×10

Jones. These performances are dramatically higher than that device based on a simple （PEA）

0.15

0.85

SnI

film.On the one hand， the improvements are attributed to the improved morphology of the perovskite film， which increases the absorption efficiency and charge carrier collection efficiency of the device；on the other hand， the formation of a p-n junction between （PEA）

0.15

0.85

SnI

and SnO

effectively increases the dissociation efficiency of the photogenerated electron-hole pairs in the perovskite and decreases the recombination probability of the electrons and holes. Moreover， the special electronic structure at the （PEA）

0.15

0.85

SnI

/SnO

interface may also trigger the device revealing a photoconduction gain.

关键词

光探测器Sn基钙钛矿异质结2D/3D混合结构SnO2

Keywords

photodetectorSn perovskiteheterojunction2D/3D hybrid structureSnO2

references

STRANKS S D，EPERON G E，GRANCINI G，et al. Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber ［J］. Science， 2013，342（6156）：341-344. doi: 10.1126/science.1243982http://dx.doi.org/10.1126/science.1243982

XING G C，MATHEWS N，SUN S Y，et al. Long-range balanced electron- and hole-transport lengths in organic-inorganic CH3NH3PbI3 ［J］. Science， 2013，342（6156）：344-347. doi: 10.1126/science.1243167http://dx.doi.org/10.1126/science.1243167

DONG Y H，ZOU Y S，SONG J Z，et al. Recent progress of metal halide perovskite photodetectors ［J］. J. Mater. Chem. C， 2017，5（44）：11369-11394. doi: 10.1039/c7tc03612dhttp://dx.doi.org/10.1039/c7tc03612d

MIAO J L，ZHANG F J. Recent progress on highly sensitive perovskite photodetectors ［J］. J. Mater. Chem. C， 2019，7（7）：1741-1791. doi: 10.1039/c8tc06089dhttp://dx.doi.org/10.1039/c8tc06089d

GU H，CHEN S C，ZHENG Q D. Emerging perovskite materials with different nanostructures for photodetectors ［J］. Adv. Opt. Mater.， 2020，9（5）：2001637-1-32. doi: 10.1002/adom.202001637http://dx.doi.org/10.1002/adom.202001637

DONG R，FANG Y J，CHAE J，et al. High-gain and low-driving-voltage photodetectors based on organolead triiodide perovskites ［J］. Adv. Mater.， 2015，27（11）：1912-1918. doi: 10.1002/adma.201405116http://dx.doi.org/10.1002/adma.201405116

LI S X，ZHANG G P，XIA H，et al. Template-confined growth of Ruddlesden-Popper perovskite micro-wire arrays for stable polarized photodetectors ［J］. Nanoscale， 2019，11（39）：18272-18281. doi: 10.1039/c9nr05396dhttp://dx.doi.org/10.1039/c9nr05396d

SHI Z J，GUO J，CHEN Y H，et al. Lead-free organic-inorganic hybrid perovskites for photovoltaic applications：recent advances and perspectives ［J］. Adv. Mater.， 2017，29（16）：1605005-1-28. doi: 10.1002/adma.201605005http://dx.doi.org/10.1002/adma.201605005

LI Y，SHI Z F，LIANG W Q，et al. Recent advances toward environment-friendly photodetectors based on lead-free metal halide perovskites and perovskite derivatives ［J］. Mater.Horiz.， 2021，8（5）：1367-1389. doi: 10.1039/d0mh01567ahttp://dx.doi.org/10.1039/d0mh01567a

ZHANG M M，ZHANG Z G，CAO H H，et al. Recent progress in inorganic tin perovskite solar cells ［J］. Mater. Today Energy， 2022，23：100891-1-16. doi: 10.1016/j.mtener.2021.100891http://dx.doi.org/10.1016/j.mtener.2021.100891

WANG F，MA JL，XIE F Y，et al. Organic cation-dependent degradation mechanism of organotin halide perovskites ［J］. Adv. Funct. Mater.， 2016，26（20）：3417-3423. doi: 10.1002/adfm.201505127http://dx.doi.org/10.1002/adfm.201505127

KUMAR M H，DHARANI S，LEONG W L，et al. Lead-free halide perovskite solar cells with high photocurrents realized through vacancy modulation ［J］. Adv. Mater.， 2014，26（41）：7122-7127. doi: 10.1002/adma.201401991http://dx.doi.org/10.1002/adma.201401991

MARSHALL K P，WALKER M，WALTON R I，et al. Enhanced stability and efficiency in hole-transport-layer-free CsSnI3 perovskite photovoltaics ［J］. Nat. Energy， 2016，1（12）：16178-1-9. doi: 10.1038/nenergy.2016.178http://dx.doi.org/10.1038/nenergy.2016.178

YAO H H，ZHOU F G，LI Z Z，et al. Strategies for improving the stability of tin-based perovskite （ASnX3） solar cells ［J］. Adv. Sci.， 2020，7（10）：1903540-1-17. doi: 10.1002/advs.201903540http://dx.doi.org/10.1002/advs.201903540

CAO D H，STOUMPOS C C，YOKOYAMA T，et al. Thin films and solar cells based on semiconducting two-dimensional Ruddlesden-Popper （CH3（CH2）3NH3）2（CH3NH3）n-1SnnI3n+1 perovskites ［J］. ACS Energy Lett.， 2017，2（5）：982-990. doi: 10.1021/acsenergylett.7b00202http://dx.doi.org/10.1021/acsenergylett.7b00202

WANG H L，CHEN Y，LIM E，et al. High-performance lead-free two-dimensional perovskite photo transistors assisted by ferroelectric dielectrics ［J］. J. Mater. Chem. C， 2018，6（46）：12714-12720. doi: 10.1039/c8tc04691chttp://dx.doi.org/10.1039/c8tc04691c

QIAN L，SUN Y L，WU M M，et al. A lead-free two-dimensional perovskite for a high-performance flexible photoconductor and a light-stimulated synaptic device ［J］. Nanoscale， 2018，10（15）：6837-6843. doi: 10.1039/c8nr00914ghttp://dx.doi.org/10.1039/c8nr00914g

杨洁，皮明雨，张丁可，等. 低维钙钛矿光电探测器研究进展［J］. 发光学报， 2021，42（6）：755-773. doi: 10.37188/CJL.20210033http://dx.doi.org/10.37188/CJL.20210033

YANG J，PI M Y，ZHANG D K，et al. Recent progress on low-dimensional perovskite photodetectors ［J］. Chin. J. Lumin.， 2021，42（6）：755-773. （in Chinese）. doi: 10.37188/CJL.20210033http://dx.doi.org/10.37188/CJL.20210033

CHEN Y N，SUN Y，PENG J J，et al. 2D Ruddlesden-Popper perovskites for optoelectronics ［J］. Adv. Mater.， 2018，30（2）：1703487-1-15. doi: 10.1002/adma.201703487http://dx.doi.org/10.1002/adma.201703487

ZHANG F，LU H P，TONG J H，et al. Advances in two-dimensional organic-inorganic hybrid perovskites ［J］. Energy Environ. Sci.， 2020，13（4）：1154-1186. doi: 10.1039/c9ee03757hhttp://dx.doi.org/10.1039/c9ee03757h

RAN C X，XI J，GAO W Y，et al. Bilateral interface engineering toward efficient 2D-3D bulk heterojunction tin halide lead-free perovskite solar cells ［J］. ACS Energy Lett.， 2018，3（3）：713-721. doi: 10.1021/acsenergylett.8b00085http://dx.doi.org/10.1021/acsenergylett.8b00085

SHAO S Y，LIU J，PORTALE G，et al. Highly reproducible Sn-based hybrid perovskite solar cells with 9% efficiency ［J］. Adv. Energy Mater.， 2018，8（4）：1702019-1-10. doi: 10.1002/aenm.201702019http://dx.doi.org/10.1002/aenm.201702019

JIANG X Y，WANG F，WEI Q，et al. Ultra-high open-circuit voltage of tin perovskite solar cells via an electron transporting layer design ［J］. Nat. Commun.， 2020，11（1）：1245-1-7. doi: 10.1038/s41467-020-15078-2http://dx.doi.org/10.1038/s41467-020-15078-2

QIU J，XIA Y D，ZHENG Y T，et al. 2D Intermediate suppression for efficient Ruddlesden-Popper（RP） phase lead-free perovskite solar cells ［J］. ACS Energy Lett.， 2019，4（7）：1513-1520. doi: 10.1021/acsenergylett.9b00954http://dx.doi.org/10.1021/acsenergylett.9b00954

NISHIMURA K，KAMARUDIN M A，HIROTANI D，et al. Lead-free tin-halide perovskite solar cells with 13% efficiency ［J］. Nano Energy， 2020，74：104858-1-10. doi: 10.1016/j.nanoen.2020.104858http://dx.doi.org/10.1016/j.nanoen.2020.104858

QIAN L，SUN Y L，SUN M X，et al. 2D Perovskite microsheets for high-performance photodetectors ［J］. J. Mater. Chem. C， 2019，7（18）：5353-5358. doi: 10.1039/c9tc00138ghttp://dx.doi.org/10.1039/c9tc00138g

YANG Y，ZHANG H F，HOU S M，et al. Sn-based quasi-two-dimensional organic-inorganic hybrid halide perovskite for high-performance photodetectors ［J］. Appl. Phys. Lett.， 2021，119（16）：161106-1-7. doi: 10.1063/5.0068273http://dx.doi.org/10.1063/5.0068273

FU Q D，WANG X L，LIU F C，et al. Ultrathin Ruddlesden-Popper perovskite heterojunction for sensitive photodetection ［J］. Small， 2019，15（39）：e1902890-1-7. doi: 10.1002/smll.201902890http://dx.doi.org/10.1002/smll.201902890

MA C，SHI Y M，HU W J，et al. Heterostructured WS2/CH3NH3PbI3 photoconductors with suppressed dark current and enhanced photodetectivity ［J］. Adv. Mater.， 2016，28（19）：3683-3689. doi: 10.1002/adma.201600069http://dx.doi.org/10.1002/adma.201600069

LIU H，ZHANG X W，ZHANG L Q，et al. A high-performance photodetector based on an inorganic perovskite-ZnO heterostructure ［J］. J. Mater. Chem. C， 2017，5（25）：6115-6122. doi: 10.1039/c7tc01998jhttp://dx.doi.org/10.1039/c7tc01998j

WU H R，SU Z S，JIN F M，et al. Improved performance of perovskite photodetectors based on a solution-processed CH3NH3PbI3/SnO2 heterojunction ［J］. Org. Electron.， 2018，57：206-210. doi: 10.1016/j.orgel.2018.03.018http://dx.doi.org/10.1016/j.orgel.2018.03.018

HUANG L K，SUN X M，LI C，et al. UV-sintered low-temperature solution-processed SnO2 as robust electron transport layer for efficient planar heterojunction perovskite solar cells ［J］. ACS Appl. Mater. Interfaces， 2017，9（26）：21909-21920. doi: 10.1021/acsami.7b04392http://dx.doi.org/10.1021/acsami.7b04392

LIU C K，TAI Q D，WANG N X，et al. Sn-based perovskite for highly sensitive photodetectors ［J］. Adv. Sci.， 2019，6（17）：1900751-1-8. doi: 10.1002/advs.201900751http://dx.doi.org/10.1002/advs.201900751

LIU C K，TAI Q D，WANG N X，et al. Lead-free perovskite/organic semiconductor vertical heterojunction for highly sensitive photodetectors ［J］. ACS Appl. Mater. Interfaces， 2020，12（16）：18769-18776. doi: 10.1021/acsami.0c01202http://dx.doi.org/10.1021/acsami.0c01202

CHEN C，ZHANG X Q，WU G，et al. Visible-light ultrasensitive solution-prepared layered organic-inorganic hybrid perovskite field-effect transistor ［J］. Adv. Opt. Mater.， 2017，5（2）：1600539-1-5. doi: 10.1002/adom.201600539http://dx.doi.org/10.1002/adom.201600539

WANG L D，XIAO Y M. Substrate depended chemical composition segregation and electrical property of perovskite films ［J］. J. Alloys Compd.， 2022，902：163797. doi: 10.1016/j.jallcom.2022.163797http://dx.doi.org/10.1016/j.jallcom.2022.163797

ZHAO Y C，ZHOU W K，ZHOU X，et al. Quantification of light-enhanced ionic transport in lead iodide perovskite thin films and its solar cell applications ［J］. Light Sci. Appl.， 2017，6（5）：e16243-1-8. doi: 10.1038/lsa.2016.243http://dx.doi.org/10.1038/lsa.2016.243

TAKAHASHI Y，HASEGAWA H，TAKAHASHI Y，et al. Hall mobility in tin iodide perovskite CH3NH3SnI3：evidence for a doped semiconductor ［J］. J. Solid State Chem.， 2013， 205：39-43. doi: 10.1016/j.jssc.2013.07.008http://dx.doi.org/10.1016/j.jssc.2013.07.008

SONG J X，ZHENG E Q，BIAN J，et al. Low-temperature SnO2-based electron selective contact for efficient and stable perovskite solar cells ［J］. J. Mater. Chem. A， 2015，3（20）：10837-10844. doi: 10.1039/c5ta01207dhttp://dx.doi.org/10.1039/c5ta01207d

TOSADO G A，ZHENG E J，YU Q M. Tuning cesium-guanidinium in formamidinium tin triiodide perovskites with an ethylenediammonium additive for efficient and stable lead-free perovskite solar cells ［J］. Mater. Adv.， 2020，1（9）：3507-3517. doi: 10.1039/d0ma00520ghttp://dx.doi.org/10.1039/d0ma00520g

浏览量

136

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

n⁃Ga₂O₃/p⁃GaAs异质结日盲紫外探测器制备

直接型卤素钙钛矿X射线探测器结构设计研究进展

SnO₂∶Zn纳米晶光阳极对染料敏化太阳能电池光电性能的影响

PbSe/TiO₂同轴异质结纳米管的制备及光催化性能

2D/3D混合Sn基钙钛矿/SnO2异质结光探测器

Photodetectors Based on A 2D/3D Hybrid Tin Perovskite/SnO2 Heterojunction

DOI：10.37188/CJL.20220107

摘要

Abstract

关键词

Keywords

references

2D/3D混合Sn基钙钛矿/SnO₂异质结光探测器

Photodetectors Based on A 2D/3D Hybrid Tin Perovskite/SnO₂Heterojunction