低热猝灭新型Sr3Ga2Ge4O14∶Sm3+橙红色荧光粉

杨伟斌; 熊飞兵; 杨寅; 周琼; 谢岚驰; 凌爽; 罗新

doi:10.37188/CJL.20220055

您当前的位置：

首页 >

文章列表页 >

低热猝灭新型Sr₃Ga₂Ge₄O₁₄∶Sm³⁺橙红色荧光粉

材料合成及性能 | 更新时间：2022-10-19

- 低热猝灭新型Sr₃Ga₂Ge₄O₁₄∶Sm³⁺橙红色荧光粉
  增强出版
- Novel Orange-red-emitting Sr₃Ga₂Ge₄O₁₄∶Sm³⁺Phosphors with Low Thermal Quenching
- 发光学报 2022年43卷第6期页码：879-890
- 作者机构：
  
  1.厦门理工学院光电与通信工程学院，福建厦门 361024
  2.厦门理工学院福建省光电技术与器件重点实验室，福建厦门 361024
- 作者简介：
  
  [ "杨伟斌（1997-），男，福建长泰人，硕士研究生，2019年于厦门理工学院获得学士学位，主要从事稀土发光材料的研究。E-mail: 543644717@qq.com" ]
  [ "熊飞兵（1976-），男，江西丰城人，博士，教授，2007年于中国科学院福建物质结构研究所获得博士学位，主要从事稀土发光材料的研究。E-mail: fbxiong@xmut.edu.cn" ]
- 基金信息：
  
  福建省自然科学基金(2020J01297)
- DOI：10.37188/CJL.20220055
  中图分类号： O482.31
- 纸质出版日期：2022-06-05，
  
  收稿日期：2022-03-03，
  
  修回日期：2022-03-20，
扫描看全文
杨伟斌,熊飞兵,杨寅等.低热猝灭新型Sr₃Ga₂Ge₄O₁₄∶Sm³⁺橙红色荧光粉[J].发光学报,2022,43(06):879-890.

YANG Wei-bin,XIONG Fei-bing,YANG Yin,et al.Novel Orange-red-emitting Sr₃Ga₂Ge₄O₁₄∶Sm³⁺Phosphors with Low Thermal Quenching[J].Chinese Journal of Luminescence,2022,43(06):879-890.
杨伟斌,熊飞兵,杨寅等.低热猝灭新型Sr₃Ga₂Ge₄O₁₄∶Sm³⁺橙红色荧光粉[J].发光学报,2022,43(06):879-890. DOI： 10.37188/CJL.20220055.

YANG Wei-bin,XIONG Fei-bing,YANG Yin,et al.Novel Orange-red-emitting Sr₃Ga₂Ge₄O₁₄∶Sm³⁺Phosphors with Low Thermal Quenching[J].Chinese Journal of Luminescence,2022,43(06):879-890. DOI： 10.37188/CJL.20220055.

摘要

采用高温固相法制备一系列新型Sr

∶

（

0~0.20）及Sr

2.88

∶0.06Sm

，0.06

（

=Li

，Na

，K

）荧光粉，通过物相形貌、荧光光谱、热稳定性及CIE色度坐标等分析手段对样品性能进行了详细研究。根据不同掺杂浓度Sr

∶

的荧光发射谱，发现Sm

最佳掺杂浓度为

0.06，其荧光浓度猝灭归因于Sm

之间的电偶极-电偶极相互作用。研究发现，通过共掺杂

（

=Li

，Na

，K

）做电荷补偿离子可以提升Sr

∶

的发光性能。此外，随着Sm

掺杂浓度提高，其荧光寿命不断减小。最后探讨了Sr

∶

的CIE色度坐标和热稳定性，其CIE色度坐标位于橙红光区域，且在423 K的发光强度大概为其室温的95%。研究表明，Sr

∶

作为新型橙红荧光粉有望应用于白光发光二极管（WLED）。

Abstract

A series of Sr

∶

（

=0-0.20）and Sr

2.88

∶0.06Sm

，0.06

（

= Li

， Na

， K

）phosphors were prepared

via

the high temperature solid-state reaction. The phase structure， crystal morphology， fluorescent spectra， temperature-dependent spectra， and CIE chromaticity coordinates of the samples were investigated. The optimal doping concentration in Sr

∶

was

=0.06， and the concentration quenching could be ascribed to the dipole-dipole interaction between Sm

ions. The luminescent emission intensities of Sr

∶

were greatly enhanced by co-doped

（

=Li

， Na

， K

）ions as charge compensator. The fluorescent decay lifetime became shorter when increasing Sm

concentration. The CIE chromaticity coordinates and thermal stability properties of Sr

∶

were discussed. The CIE chromaticity coordinates of Sr

∶

were located within the orange-red spectral region and the luminescent emission intensities could remain 95% of that at room temperature. All these results indicated that Sr

∶

could be a potential candidate as a novel orange-red emitting component applied in white light emitting diode（WLED）.

关键词

Sr3Ga2Ge4O14Sm3+电荷补偿剂光致发光白光发光二极管（WLED）

Keywords

Sr3Ga2Ge4O14Sm3+charge compensatorphotoluminescencewhite light emitting diode（WLED）

references

XIA Z G，LIU Q L. Progress in discovery and structural design of color conversion phosphors for LEDs ［J］. Prog. Mater. Sci.， 2016，84：59-117. doi: 10.1016/j.pmatsci.2016.09.007http://dx.doi.org/10.1016/j.pmatsci.2016.09.007

YE S，XIAO F，PAN Y X，et al. Phosphors in phosphor-converted white light-emitting diodes：recent advances in materials，techniques and properties ［J］. Mater. Sci. Eng. R Rep.， 2010，71（1）：1-34. doi: 10.1016/j.mser.2010.07.001http://dx.doi.org/10.1016/j.mser.2010.07.001

SCHUBERT E F，KIM J K. Solid-state light sources getting smart ［J］. Science， 2005，308（5726）：1274-1278. doi: 10.1126/science.1108712http://dx.doi.org/10.1126/science.1108712

胡盼，丁慧，刘永福，等. YAG∶Ce3+在激光照明应用中的研究进展［J］. 发光学报， 2020，41（12）：1504-1528. doi: 10.37188/CJL.20200249http://dx.doi.org/10.37188/CJL.20200249

HU P，DING H，LIU Y F，et al. Recent progress of YAG∶Ce3+ for white laser diode lighting application ［J］. Chin. J. Lumin.， 2020，41（12）：1504-1528. （in Chinese）. doi: 10.37188/CJL.20200249http://dx.doi.org/10.37188/CJL.20200249

ZHU H M，LIN C C，LUO W Q，et al. Highly efficient non-rare-earth red emitting phosphor for warm white light-emitting diodes ［J］. Nat. Commun.， 2014，5（1）：4312-1-10. doi: 10.1038/ncomms5312http://dx.doi.org/10.1038/ncomms5312

GUPTA S K，SUDARSHAN K，KADAM R M. Tunable white light emitting Sr2V2O7∶Bi3+ phosphors：role of bismuthion ［J］. Mater. Des.， 2017，130：208-214. doi: 10.1016/j.matdes.2017.05.056http://dx.doi.org/10.1016/j.matdes.2017.05.056

KIM Y H，VISWANATH N S M，UNITHRATTIL S，et al. Phosphor plates for high-power LED applications：challenges and opportunities toward perfect lighting ［J］. ECS J. Solid State Sci. Technol.， 2017，7（1）：R3134-R3147. doi: 10.1149/2.0181801jsshttp://dx.doi.org/10.1149/2.0181801jss

张立振，王子豪，黄娇. 高长径比Eu3+掺杂Y2O3荧光陶瓷纤维的制备及其发光性能［J］. 发光学报， 2021，42（12）：1891-1899. doi: 10.37188/cjl.20210297http://dx.doi.org/10.37188/cjl.20210297

ZHANG L Z，WANG Z H，HUANG J，et al. Fabrication and photoluminescence properties of Eu3+ doped Y2O3 ceramic fiber with high aspect ratio ［J］. Chin. J. Lumin.， 2021，42（12）：1891-1899. （in Chinese）. doi: 10.37188/cjl.20210297http://dx.doi.org/10.37188/cjl.20210297

UHEDA K，HIROSAKI N，YAMAMOTO Y，et al. Luminescence properties of a red phosphor，CaAlSiN3∶Eu2+，for white light-emitting diodes ［J］. Electrochem. Solid State Lett.， 2006，9（4）：H22-H25. doi: 10.1149/1.2173192http://dx.doi.org/10.1149/1.2173192

TAKAHASHI T，ADACHI S. Mn4+-activated red photoluminescence in K2SiF6 phosphor ［J］. J. Electrochem. Soc.， 2008，155（12）：E183-E188. doi: 10.1149/1.2993159http://dx.doi.org/10.1149/1.2993159

XIONG F B，GUO D S，LIN H F，et al. High-color-purity red-emitting phosphors RE2WO6∶Pr3+ （RE=Y，Gd） for blue LED ［J］. J. Alloys Compd.， 2015，647：1121-1127. doi: 10.1016/j.jallcom.2015.06.143http://dx.doi.org/10.1016/j.jallcom.2015.06.143

孙雷，张毅，胡兴凯，等. LED用KZn4（BO3）3∶Eu3+荧光粉的合成与发光性能研究［J］. 液晶与显示， 2014，29（6）：893-900. doi: 10.3788/YJYXS20142906.0893http://dx.doi.org/10.3788/YJYXS20142906.0893

SUN L，ZHANG Y，HU X K，et al. Synthesis and photoluminescence properties of KZn4（BO3）3∶Eu3+ red-emitting phosphor ［J］. Chin. J. Liq. Cryst. Disp.， 2014，29（6）：893-900. （in Chinese）. doi: 10.3788/YJYXS20142906.0893http://dx.doi.org/10.3788/YJYXS20142906.0893

BOLEK P，ZELER J，BRITES C D S，et al. Ga-modified YAG∶Pr3+ dual-mode tunable luminescencethermometers ［J］. Chem. Eng. J.， 2021，421：129764-1-13. doi: 10.1016/j.cej.2021.129764http://dx.doi.org/10.1016/j.cej.2021.129764

LIANG S S，LI G G，DANG P P，et al. Cation substitution induced adjustment on lattice structure and photoluminescence properties of Mg14Ge5O24∶Mn4+：optimized emission for w-LED and thermometry applications ［J］. Adv. Opt. Mater.， 2019，7（12）：1900093-1-15. doi: 10.1002/adom.201900093http://dx.doi.org/10.1002/adom.201900093

LIANG S S，HUANG D C，HU J，et al. A highly efficient red emitting phosphor with enhanced blue-light absorption through a local crystal field regulation strategy ［J］. Chem. Eng. J.， 2022，429：132231-1-10. doi: 10.1016/j.cej.2021.132231http://dx.doi.org/10.1016/j.cej.2021.132231

KAMINSKII A A，BELOKONEVA E L，MILL B V，et al. Pure and Nd3+-doped Ca3Ga2Ge4O14 and Sr3Ga2Ge4O14 single crystals，their structure，optical，spectral luminescence，electromechanical properties，and stimulated emission ［J］. Phys. Status Solidi （A）， 1984，86（1）：345-362. doi: 10.1002/pssa.2210860139http://dx.doi.org/10.1002/pssa.2210860139

WU A H，DING J X，XU J Y，et al. Effect of Nd doping on structural and thermal properties of Sr3Ga2Ge4O14 crystals ［J］. Mater. Charact.， 2008，59（7）：979-982. doi: 10.1016/j.matchar.2007.08.005http://dx.doi.org/10.1016/j.matchar.2007.08.005

DUDKA A P，MILL B V. Crystal-structure refinement of Sr3Ga2Ge4O14 ［J］. Crystallogr. Rep.， 2012，57（1）：49-56. doi: 10.1134/s1063774511030084http://dx.doi.org/10.1134/s1063774511030084

李兆，曹静，王永锋. BaWO4∶Sm3+红色荧光粉的微波合成及发光性能研究［J］. 中国稀土学报， 2020，38（2）：139-143.

LI Z，CAO J，WANG Y F. Preparation of BaWO4∶Sm3+ red phosphor by microwave method and its luminescent properties ［J］. J. Chin. Soc. Rare Earths， 2020，38（2）：139-143. （in Chinese）

HUA Y B，YU J S. Synthesis and luminescence properties of reddish-orange-emitting Ca2GdNbO6∶Sm3+ phosphors with good thermal stability for high CRI white applications ［J］. Ceram. Int.， 2021，47（5）：6059-6067. doi: 10.1016/j.ceramint.2020.10.181http://dx.doi.org/10.1016/j.ceramint.2020.10.181

SHU S，WANG Y，KE Y E，et al. NaCaTiTaO6∶Sm3+：a novel orange-red-emitting tantalate phosphor with excellent thermal stability and high color purity for white LEDs ［J］. J. Alloys Compd.， 2020，848：156359-1-9. doi: 10.1016/j.jallcom.2020.156359http://dx.doi.org/10.1016/j.jallcom.2020.156359

CHEN S G，WANG Y，ZHAO B K，et al. Luminescence properties of novel orange-red-emitting Gd2InSbO7∶Sm3+ phosphor with high color purity for W-LEDs ［J］. J. Lumin.， 2021，237：118148-1-9. doi: 10.1016/j.jlumin.2021.118148http://dx.doi.org/10.1016/j.jlumin.2021.118148

杨敬伟，李旭，焦典，等. 共掺碱金属对白光LEDs用SrBPO5∶Sm3+荧光粉发光的增强作用［J］. 无机材料学报， 2016，31（8）：876-880. doi: 10.15541/jim20150623http://dx.doi.org/10.15541/jim20150623

YANG J W，LI X，JIAO D，et al. Enhancing luminescence of SrBPO5∶Sm3+ phosphor by codoping alkali metal for white LEDs ［J］. J. Inorg. Mater.， 2016，31（8）：876-880. （in Chinese）. doi: 10.15541/jim20150623http://dx.doi.org/10.15541/jim20150623

FAN J，ZHANG W T，DAI S Y，et al. Effect of charge compensators A+ （A = Li，Na and K） on luminescence enhancement of Ca3Sr3（PO4）4∶Sm3+ orange-red phosphors ［J］. Ceram. Int.， 2018，44（16）：20028-20033. doi: 10.1016/j.ceramint.2018.07.276http://dx.doi.org/10.1016/j.ceramint.2018.07.276

ZHANG W T，CHENG L，ZHOU D S，et al. Luminescence enhancement of Cd2V2O7∶Re3+ （Re = Pr，Sm） red phosphors through Li+ ions charge compensation ［J］. Ceram. Int.， 2018，44（5）：5420-5425. doi: 10.1016/j.ceramint.2017.12.171http://dx.doi.org/10.1016/j.ceramint.2017.12.171

SONG Y Y，GUO N，LI J，et al. Photoluminescence and temperature sensing of lanthanide Eu3+ and transition metal Mn4+ dual-doped antimoniate phosphor through site-beneficial occupation ［J］. Ceram. Int.， 2020，46（14）：22164-22170. doi: 10.1016/j.ceramint.2020.05.293http://dx.doi.org/10.1016/j.ceramint.2020.05.293

CAO G，RABENBERG L K，NUNN C M，et al. Formation of quantum-size semiconductor particles in a layered metal phosphonate host lattice ［J］. Chem. Mater.， 1991，3（1）：149-156. doi: 10.1021/cm00013a032http://dx.doi.org/10.1021/cm00013a032

庹娟，王林香，叶颖，等. 金属离子Li+，Na+，K+，Ca2+，Ba2+掺杂Lu2O3∶Pr3+荧光粉的制备及发光特性研究［J］. 发光学报， 2018，39（3）：307-314. doi: 10.3788/fgxb20183903.0307http://dx.doi.org/10.3788/fgxb20183903.0307

TUO J，WANG L X，YE L，et al. Preparation and luminescence properties of Lu2O3∶Pr3+ phosphors codoped with Li+，Na+，K+，Ca2+，Ba2+ ions ［J］. Chin. J. Lumin.， 2018，39（3）：307-314. （in Chinese）. doi: 10.3788/fgxb20183903.0307http://dx.doi.org/10.3788/fgxb20183903.0307

MA Y Y，CHEN S G，CHE J Z，et al. Effect of charge compensators（Li+，Na+，K+） on the luminescence properties of Sr3TeO6∶Eu3+ red phosphor ［J］. Ceram. Int.， 2021，47（6）：8518-8527. doi: 10.1016/j.ceramint.2020.11.219http://dx.doi.org/10.1016/j.ceramint.2020.11.219

BLASSE G. Energy transfer in oxidic phosphors ［J］. Philips Res. Rep.， 1969，24（2）：131-144.

DEXTER D L. A theory of sensitized luminescence in solids ［J］. J. Chem. Phys.， 1953，21（5）：836-850. doi: 10.1063/1.1699044http://dx.doi.org/10.1063/1.1699044

XIA Z G，ZHOU J，MAO Z Y. Near UV-pumped green-emitting Na3（Y，Sc）Si3O9∶Eu2+ phosphor for white-emitting diodes ［J］. J. Mater. Chem. C， 2013，1（37）：5917-5924. doi: 10.1039/c3tc30897ahttp://dx.doi.org/10.1039/c3tc30897a

INOKUTI M，HIRAYAMA F. Influence of energy transfer by the exchange mechanism on donor luminescence ［J］. J. Chem. Phys.， 1965，43（6）：1978-1989. doi: 10.1063/1.1697063http://dx.doi.org/10.1063/1.1697063

WANG J X，XIE Y，GUO J L，et al. Abnormal thermal quenching behavior and optical properties of a novel apatite-type NaCa3Bi（PO4）3F∶Sm3+ orange-red-emitting phosphor for w-LED applications ［J］. Ceram. Int.， 2021，47（20）：28167-28177. doi: 10.1016/j.ceramint.2021.06.203http://dx.doi.org/10.1016/j.ceramint.2021.06.203

BERGSTRAND J，LIU Q Y，HUANG B R，et al. On the decay time of upconversion luminescence ［J］. Nanoscale， 2019，11（11）：4959-4969. doi: 10.1039/c8nr10332ahttp://dx.doi.org/10.1039/c8nr10332a

ĆIRIĆ A，STOJADINOVIĆ S，SEKULIĆ M，et al. JOES：an application software for Judd-Ofelt analysis from Eu3+ emission spectra ［J］. J. Lumin.， 2019， 205：351-356. doi: 10.1016/j.jlumin.2018.09.048http://dx.doi.org/10.1016/j.jlumin.2018.09.048

MCCAMY C S. Correlated color temperature as an explicit function of chromaticity coordinates ［J］. Color. Res. Appl.， 1992，17（2）：142-144. doi: 10.1002/col.5080170211http://dx.doi.org/10.1002/col.5080170211

GENG X，XIE Y，MA Y Y，et al. Abnormal thermal quenching and application for w-LEDs：double perovskite Ca2InSbO6∶Eu3+ red-emitting phosphor ［J］. J. Alloys Compd.， 2020，847：156249-1-12. doi: 10.1016/j.jallcom.2020.156249http://dx.doi.org/10.1016/j.jallcom.2020.156249

ARRHENIUS S. Über die dissociationswärme und den einfluss der temperatur auf den dissociationsgrad der elektrolyte ［J］. Z. Phys. Chem.， 1889，4（1）：96-116. doi: 10.1515/zpch-1889-0408http://dx.doi.org/10.1515/zpch-1889-0408

YANG Z F，XU D H，SUN J Y. Synthesis and luminescence properties of Ba3Lu（PO4）3∶Sm3+ phosphor for white light-emitting diodes ［J］. Opt. Express， 2017，25（8）：A391-A401. doi: 10.1364/oe.25.00a391http://dx.doi.org/10.1364/oe.25.00a391

GUO Q F，ZHAO C L，LIAO L B，et al. Luminescence investigations of novel orange-red fluorapatite KLaSr3（PO4）3F∶Sm3+ phosphors with high thermal stability ［J］. J. Am. Ceram. Soc.， 2017，100（5）：2221-2231. doi: 10.1111/jace.14751http://dx.doi.org/10.1111/jace.14751

田少华，乔峥，孙明生. 白光LEDs用颜色可调型荧光粉Ca9Al（PO4）7∶Tb3+，Sm3+的发光及能量传递［J］. 发光学报， 2019，40（12）：1469-1477. doi: 10.3788/fgxb20194012.1469http://dx.doi.org/10.3788/fgxb20194012.1469

TIAN S H，QIAO Z，SUN M S. Luminescence and energy transfer of tunable emission phosphor Ca9Al（PO4）7∶Tb3+，Sm3+ for white LEDs ［J］. Chin. J. Lumin.， 2019，40（12）：1469-1477. （in Chinese）. doi: 10.3788/fgxb20194012.1469http://dx.doi.org/10.3788/fgxb20194012.1469

LI L，TANG X H，JIANG Z Q，et al. NaBaLa2（PO4）3：a novel host lattice for Sm3+-doped phosphor materials emitting reddish-orange light ［J］. J. Alloys Compd.， 2017，701：515-523. doi: 10.1016/j.jallcom.2017.01.171http://dx.doi.org/10.1016/j.jallcom.2017.01.171

JI C Y，HUANG Z，TIAN X Y，et al. Sm3+/Pr3+ biactivated Ca3Y2Ge3O12∶0.04Sm3+∶Pr3+ red phosphor with high thermal stability for low correlated temperature WLED ［J］. J. Lumin.， 2021，232：117775-1-8. doi: 10.1016/j.jlumin.2020.117775http://dx.doi.org/10.1016/j.jlumin.2020.117775

LI Z H，HUA Y B，OU G C. Synthesis red-emitting Ca2LaNbO6∶xSm3+ phosphors for good color-rendering-index white-LED devices ［J］. Optik， 2021，233：166595-1-8. doi: 10.1016/j.ijleo.2021.166595http://dx.doi.org/10.1016/j.ijleo.2021.166595

LI L，FU S K，ZHENG Y F，et al. Near-ultraviolet and blue light excited Sm3+ doped Lu2MoO6 phosphor for potential solid state lighting and temperature sensing ［J］. J. Alloys Compd.， 2018，738：473-483. doi: 10.1016/j.jallcom.2017.12.169http://dx.doi.org/10.1016/j.jallcom.2017.12.169

王雨，王潇慧，李桂芳. NaLaMgWO6∶Sm3+荧光材料的制备及其热稳定性与发光性能［J］. 硅酸盐学报， 2020，48（3）：447-454.

WANG Y，WANG X H，LI G F. Synthesis，thermal stability and photoluminescence properties of NaLaMgWO6∶Sm3+ phosphors ［J］. J. Chin. Ceram. Soc.， 2020，48（3）：447-454. （in Chinese）

GUPTA B K，HARANATH D，SAINI S，et al. Synthesis and characterization of ultra-fine Y2O3∶Eu3+ nanophosphors for luminescent security ink applications ［J］. Nanotechnology， 2010，21（5）：055607-1-8. doi: 10.1088/0957-4484/21/5/055607http://dx.doi.org/10.1088/0957-4484/21/5/055607

浏览量

160

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

12CaO·7Al₂O₃/5CaO·3Al₂O₃：Sm³⁺新型红色荧光粉的制备及发光性质

深紫外AlGaN基多量子阱结构中载流子辐射复合的局域特征

Sr₆Lu₂Al₄O₁₅∶Tb³⁺荧光粉的发光特性

一维光子晶体带边态模式调控的胶体量子点发光性能