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Sn2+-Mn2+共掺杂Gd2O3-Al2O3-SiO2玻璃光致发光性能与能量传递
增强出版Photoluminescence Properties and Energy Transfer of Sn2+-Mn2+ Co-doped Gd2O3-Al2O3-SiO2 Glass
- 发光学报 2022年43卷第5期 页码：691-701
- 作者机构：
1.中国计量大学 材料与化学学院，浙江 杭州 310018
2.中国计量大学 光学与电子科技学院，浙江 杭州 310018
3.中国科学院上海硅酸盐研究所 无机功能材料与器件重点实验室，上海 201899
4.中国科学院高能物理研究所 核探测与核电子学国家重点实验室，北京 100049
- 作者简介：
[ "华哲浩(1996-)，男，浙江舟山人，硕士研究生，2019年于中国计量大学获得学士学位，主要从事闪烁玻璃应用的研究。E-mail: huazh@ihep.ac.cn" ]
[ "唐高(1981-)，男，湖南株洲人，博士，副研究员，2009年于中国科学院上海硅酸盐研究所获得博士学位，主要从事闪烁材料的研究。E-mail: gtang@cjlu.edu.cn" ]
- 基金信息：国家自然科学基金(61505193;11904345;11975220;51972291);浙江省科技厅2022年度“尖兵”研发攻关计划(2022C01046);浙江省自然科学基金(LGG22E020001);中国科学院无机功能材料与器件重点实验室开放项目(KLIFMD201808)
DOI：10.37188/CJL.20220042
中图分类号： TQ171收稿日期：2022-02-06，
修回日期：2022-02-17，
纸质出版日期：2022-05
- 稿件说明：
移动端阅览
华哲浩, 唐高, 魏钦华, 等. Sn2+-Mn2+共掺杂Gd2O3-Al2O3-SiO2玻璃光致发光性能与能量传递[J]. 发光学报, 2022,43(5):691-701.
Zhe-hao HUA, Gao TANG, Qin-hua WEI, et al. Photoluminescence Properties and Energy Transfer of Sn2+-Mn2+ Co-doped Gd2O3-Al2O3-SiO2 Glass[J]. Chinese journal of luminescence, 2022, 43(5): 691-701.
华哲浩, 唐高, 魏钦华, 等. Sn2+-Mn2+共掺杂Gd2O3-Al2O3-SiO2玻璃光致发光性能与能量传递[J]. 发光学报, 2022,43(5):691-701. DOI： 10.37188/CJL.20220042.
Zhe-hao HUA, Gao TANG, Qin-hua WEI, et al. Photoluminescence Properties and Energy Transfer of Sn2+-Mn2+ Co-doped Gd2O3-Al2O3-SiO2 Glass[J]. Chinese journal of luminescence, 2022, 43(5): 691-701. DOI： 10.37188/CJL.20220042.
摘要
通过传统的高温熔融淬火技术制备了Sn
2+
-Mn
2+
共掺杂的Gd
2
O
3
-Al
2
O
3
-SiO
2
（GAS∶0.5Sn
2+
，
y
Mn
2+
）玻璃。研究了玻璃的光致发光特性和Sn
2+
-Mn
2+
能量传递过程。在365 nm激发下，随着Mn
2+
浓度的增加（1.0%，1.5%，2.0%，2.5%，3.0%，3.5%，4.0%），玻璃中Sn
2+
的发光强度逐渐降低，而Mn
2+
的发光强度逐渐增大。Sn
2+
的衰减时间随着Mn
2+
含量的增加而减小，玻璃中产生了Sn
2+
到Mn
2+
离子的能量传递。GAS∶0.5Sn
2+
，
y
Mn
2+
玻璃的光致发光量子产率（PLQY）随着Mn
2+
含量的增加而减小，其最大值为25.48%。玻璃中Mn
2+
离子浓度达到4.0%时，其发光属于准白光发射，色坐标为（0.323，0.273）。另外，本文还研究了Sn
2+
-Mn
2+
共掺杂玻璃的发光热猝灭现象，Sn
2+
发光中心电子跃迁所需克服的热激活能约为0.23 eV。
Abstract
The Sn
2+
-Mn
2+
co-doped Gd
2
O
3
-Al
2
O
3
-SiO
2
(GAS∶0.5Sn
2+
y
Mn
2+
) glass was prepared by traditional high temperature melt-quenching technology. The photoluminescence properties of the glass and the energy transfer process of Sn
2+
-Mn
2+
were studied. Under 365 nm excitation wavelength
with the increase of Mn
2+
content(1.0%
1.5%
2.0%
2.5%
3.0%
3.5%
4.0%)
the emission intensity of the Sn
2+
center gradually decreases
and the emission intensity of the Mn
2+
center gradually increases. Moreover
the decay time of the Sn
2+
center decreases with the increase of Mn
2+
content
indicating that energy transfer from Sn
2+
to Mn
2+
ions occurs in the glass. The photoluminescence quantum yield(PLQY) decreases with the increase of Mn
2+
content
the maximum of PLQY of GAS∶0.5Sn
2+
y
Mn
2+
glass is 25.48%. When the Mn
2+
ions concentration reaches 4.0%
the chromatic coordinate of the glass is (0.323
0.273)
which is close to the standard white light emission. In addition
the thermal quenching behavior of Sn
2+
-Mn
2+
co-doped glass was also studied. The thermal activation energy required to overcome the electronic transition of the Sn
2+
emission center is approximately 0.23 eV.
关键词
Keywords
references
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