邻苯二甲酸结晶诱导荧光碳点制备及其在白光发光二极管中的应用

吕播瑞; 崔俊超; 徐文军; 秦振兴

doi:10.37188/CJL.20220003

您当前的位置：

首页 >

文章列表页 >

邻苯二甲酸结晶诱导荧光碳点制备及其在白光发光二极管中的应用

材料合成及性能 | 更新时间：2022-04-20

- 邻苯二甲酸结晶诱导荧光碳点制备及其在白光发光二极管中的应用
  增强出版
- Crystalline(phthalic acid)-induced Luminescence of Carbon Dots for White-light-emitting Diode Devices
- 发光学报 2022年43卷第4期页码：528-535
- 作者机构：
  
  1.太原科技大学　应用科学学院，山西　太原　030024
  2.山西量界数字科技有限公司，山西　太原　030021
- 作者简介：
  
  [ "吕播瑞(1986-)，男，山西朔州人，硕士，实验师，2013年于吉林大学获得硕士学位，主要从事新型发光材料的制备及应用的研究。E-mail: boruilv@tyust.edu.cn" ]
  [ "秦振兴(1982-)，男，山西长治人，博士，副教授，2013年于华南理工大学获得博士学位，主要从事新型发光材料的制备及应用的研究。E-mail: qinzx@tyust.edu.cn" ]
- 基金信息：
  
  山西省重点研发计划(201903D321111);国家自然科学基金(51502189);山西省研究生教育创新项目(2020SY441)
- DOI：10.37188/CJL.20220003
  中图分类号： O482.31
- 纸质出版日期：2022-04-01，
  
  收稿日期：2022-01-06，
  
  修回日期：2022-01-18，
- 稿件说明：
移动端阅览
吕播瑞, 崔俊超, 徐文军, 等. 邻苯二甲酸结晶诱导荧光碳点制备及其在白光发光二极管中的应用[J]. 发光学报, 2022,43(4):528-535.

BO-RUI LYU, JUN-CHAO CUI, WEN-JUN XU, et al. Crystalline(phthalic acid)-induced Luminescence of Carbon Dots for White-light-emitting Diode Devices. [J]. Chinese journal of luminescence, 2022, 43(4): 528-535.
吕播瑞, 崔俊超, 徐文军, 等. 邻苯二甲酸结晶诱导荧光碳点制备及其在白光发光二极管中的应用[J]. 发光学报, 2022,43(4):528-535. DOI： 10.37188/CJL.20220003.

BO-RUI LYU, JUN-CHAO CUI, WEN-JUN XU, et al. Crystalline(phthalic acid)-induced Luminescence of Carbon Dots for White-light-emitting Diode Devices. [J]. Chinese journal of luminescence, 2022, 43(4): 528-535. DOI： 10.37188/CJL.20220003.

摘要

通过简单的方法获得基于碳纳米点的固态荧光材料，实现该类材料在光电器件领域的应用研究有着重要的意义。然而，由于聚集诱导猝灭效应的存在，合成该类材料仍面临着严峻的挑战。本文报道了一种简单热解合成硫(S)和氮(N)共掺杂荧光碳点晶态材料的方法。优化制备条件后，获得的材料能发出耀眼的橙红色荧光，这是由于在形成碳点的同时，碳点的周围形成了以邻苯二甲酸为前体的晶态物，该晶态物对碳点形成了保护屏障，阻碍了碳点的聚集，弱化了碳点的光猝灭效应。此外，由于硫和氮的共掺杂作用，该材料发光呈现出多峰发射的特征，这赋予了该荧光材料在封装白光发光二极管方面的优势。因此，除实现发光二极管器件的橙色发光外，该材料与商用荧光粉(黄绿色的SiAlON∶Eu

和蓝色的BaMgAl

∶Eu

)相结合，在色度坐标为(0.43

0.40)时获得了相关色温约3 100 K、显色指数82的暖白光，结果表明该类荧光纳米材料在照明领域具有广阔的应用前景。

Abstract

Obtaining simply C-dots-based solid-state fluorescent materials is profound in photoelectric field

yet it is still faced with the challenge to synthesize such material due to the serious quenching effect generated by aggregation of C-dots currently. Here

a pyrolytic route to rapidly synthesize sulfur(S)

nitrogen(N)-codoped fluorescent carbon dots wrapped by the crystalline phthalate is reported. After optimizing the preparation conditions

the composite emits a dazzling orange-red fluorescence due to the crystal structured by phthalic acid precursor around the single C-dots during the formation of C-dots

and the formation of crystal creates a barrier to avoid the aggregation of C-dots. In addition

the emission of such composite is characteristic of the multipeaks due to the co-doping of sulfur and nitrogenelements

endowing it an advantage to fabricate white-light-emitting diode. As a result

it achieves a warm-white light with the correlated color temperature(CCT)~3 100 K

color rendering index(CRI)~82 at the chromaticity coordinates of (0.43

0.40) combined with the commercial phosphors besides of the light emitting diode with an orange light

endowing such fluorescent nanomaterials broad prospect in the photoelectric industry.

关键词

碳点硫氮共掺杂结晶诱导发光二极管

Keywords

C-dotssulfur and nitrogen co-dopingcrystalline-inducedLED

references

YANG H Y, LIU Y L, GUO Z Y, et al. Hydrophobic carbon dots with blue dispersed emission and red aggregation-induced emission [J]. Nat. Commun., 2019, 10(1):1789-1-11.

NIU X Q, SONG T B, XIONG H M. Large scale synthesis of red emissive carbon dots powder by solid state reaction for fingerprint identification [J]. Chin. Chem. Lett., 2021, 32(6):1953-1956.

徐冀健, 曲丹, 安丽, 等. 红光/近红外发射碳点制备、光学调控与应用 [J]. 发光学报, 2021, 42(12):1837-1851.

XU J J, QU D, AN L, et al. Preparation,optical control and application of red/near infrared emitting carbon dots [J]. Chin.J.Lumin., 2021, 42(12):1837-1851. (in Chinese)

BAKER S N, BAKER G A. Luminescent carbon nanodots:emergent nanolights [J]. Angew. Chem. Int. Ed., 2010, 49(38):6726-6744.

孟维雪, 杨柏, 卢思宇. 从碳点到碳化聚合物点：发展和挑战 [J]. 发光学报, 2021, 42(8):1075-1094.

MENG W X, YANG B, LU S Y. From carbon dots to carbonized polymer dots:development and challenges [J]. Chin.J.Lumin., 2021, 42(8):1075-1094. (in Chinese)

YUAN K, ZHANG X H, LI X, et al. Great enhancement of red emitting carbon dots with B/Al/Ga doping for dual mode anti-counterfeiting [J]. Chem. Eng. J., 2020, 397:125487-1-9.

LI H Y, ZHANG Z X, DING J, et al. Diamond-like carbon structure-doped carbon dots:a new class of self-quenching-resistant solid-state fluorescence materials toward light-emitting diodes [J]. Carbon, 2019, 149:342-349.

XU M H, XU S S, YANG Z, et al. Hydrophilic and blue fluorescent N-doped carbon dots from tartaric acid and various alkylol amines under microwave irradiation [J]. Nanoscale, 2015, 7(38):15915-15923.

GONG X J, LU W J, LIU Y, et al. Low temperature synthesis of phosphorous and nitrogen co-doped yellow fluorescent carbon dots for sensing and bioimaging [J]. J. Mater. Chem. B, 2015, 3(33):6813-6819.

ZENG Y W, MA D K, WANG W, et al. N,S co-doped carbon dots with orange luminescence synthesized through polymerization and carbonization reaction of amino acids [J]. Appl. Surf. Sci., 2015, 342:136-143.

DONG Y Q, PANG H C, YANG H B, et al. Carbon-based dots co-doped with nitrogen and sulfur for high quantum yield and excitation-independent emission [J]. Angew. Chem.Int. Ed., 2013, 52(30):7800-7804.

SHEN J, SHANG S M, CHEN X Y, et al. Highly fluorescent N,S-co-doped carbon dots and their potential applications as antioxidants and sensitive probes for Cr(Ⅵ) detection [J]. Sens. Actuators B Chem., 2017, 248:92-100.

QU D, SUN Z C, ZHENG M, et al. Three colors emission from S,N co-doped graphene quantum dots for visible light H2production and bioimaging [J]. Adv. Opt. Mater., 2015, 3(3):360-367.

MIAO X, YAN X L, QU D, et al. Red emissive sulfur,nitrogen codoped carbon dots and their application in ion detection and theraonostics [J]. ACS Appl. Mater.Interfaces, 2017, 9(22):18549-18556.

GAO D, ZHAO H, CHEN X, et al. Recent advance in red-emissive carbon dots and their photoluminescent mechanisms [J]. Mater. Today Chem., 2018, 9:103-113.

DING H, WEI J S, XIONG H M. Nitrogen and sulfur co-doped carbon dots with strong blue luminescence [J]. Nanoscale, 2014, 6(22):13817-13823.

LI C J, WANG Y Q, ZHANG X J, et al. Red fluorescent carbon dots with phenylboronic acid tags for quick detection of Fe(Ⅲ) in PC12 cells [J]. J. Colloid Interface Sci., 2018, 526:487-496.

LI H X, SU D D, GAO H, et al. Design of red emissive carbon dots:robust performance for analytical applications in pesticide monitoring [J]. Anal. Chem., 2020, 92(4):3198-3205.

MIAO X, QU D, YANG D X, et al. Synthesis of carbon dots with multiple color emission by controlled graphitization and surface functionalization [J]. Adv. Mater., 2018, 30(1):1704740-1-8.

ZHOU D, LI D, JING P T, et al. Conquering aggregation-induced solid-state luminescence quenching of carbon dots through a carbon dots-triggered silica gelation process [J]. Chem. Mater., 2017, 29(4):1779-1787.

CHAO D Y, CHEN J X, DONG Q, et al. Ultrastable and ultrasensitive pH-switchable carbon dots with high quantum yield for water quality identification,glucose detection,and two starch-based solid-state fluorescence materials [J]. Nano Res., 2020, 13(11):3012-3018.

MA Y S, ZHANG X M, BAI J L, et al. Facile,controllable tune of blue shift or red shift of the fluorescence emission of solid-state carbon dots [J]. Chem. Eng. J., 2019, 374:787-792.

TIAN Z, ZHANG X T, LI D, et al. Full-color inorganic carbon dot phosphors for white-light-emitting diodes [J]. Adv. Opt. Mater., 2017, 5(19):1700416-1-9.

CHEN Y H, ZHENG M T, XIAO Y, et al. A self-quenching-resistant carbon-dot powder with tunable solid-state fluorescence and construction of dual-fluorescence morphologies for white light-emission [J]. Adv. Mater., 2016, 28(2):312-318.

LI J Y, WANG B L, ZHANG H Y, et al. Carbon dots-in-matrix boosting intriguing luminescence properties and applications [J]. Small, 2019, 15(32):1805504-1-16.

WANG H, SUN C, CHEN X R, et al. Excitation wavelength independent visible color emission of carbon dots [J]. Nanoscale, 2017, 9(5):1909-1915.

ZHAN Y, LIN L F, CHEN M, et al. Facile synthesis of a terephthalic acid-based organic fluorophore with strong and color-tunable emission in both solution and solid states for LED applications [J]. ACS Appl. Mater. Interfaces, 2018, 10(39):33390-33398.

WANG H J, YU T T, CHEN H L, et al. A self-quenching-resistant carbon dots powder with tunable solid-state fluorescence and their applications in light-emitting diodes and fingerprints detection [J]. Dyes Pigm., 2018, 159:245-251.

FAN R J, SUN Q, ZHANG L, et al. Photoluminescent carbon dots directly derived from polyethylene glycol and their application for cellular imaging [J]. Carbon, 2014, 71:87-93.

HU X H, AN X Q, LI L L. Easy synthesis of highly fluorescent carbon dots from albumin and their photoluminescent mechanism and biological imaging applications [J]. Mater. Sci. Eng. C, 2016, 58:730-736.

GAO F, MA S Y, LI J, et al. Rational design of highquality citric acid-derived carbon dots by selecting efficient chemical structure motifs [J]. Carbon, 2017, 112:131-141.

ZHAN Y, SHANG B, CHEN M, et al. One-step synthesis of silica-coated carbon dots with controllable solid-state fluorescence for white light-emitting diodes [J]. Small, 2019, 15(24):1901161-1-9.

YANG J, LIU Y, WANG J, et al. Visual multiple color emission of solid-state carbon dots [J]. J. Mater. Chem. C, 2019, 7(25):7806-7811.

浏览量

326

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

氮和硼元素共掺杂对碳点荧光的调控机制

晶相对碳点多色发光的调制及其在白光发光二极管器件中的应用

植物生长LED用Sr₂MgAl₂₂O₃₆∶Mn⁴⁺荧光玻璃的制备与发光性质

InGaN/GaN多量子阱蓝光LED外延片的变温光致发光谱