Pr<sup>3+</sup>掺杂红色长余辉发光材料研究进展

吕雪杰; 许杰; 林航; 林世盛; 王元生

doi:10.37188/CJL.20210414

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Pr³⁺掺杂红色长余辉发光材料研究进展

特邀综述 | 更新时间：2022-04-07

- Pr³⁺掺杂红色长余辉发光材料研究进展
  增强出版
- Research Progress on Pr³⁺ Doped Red Persistent Luminescent Materials
- 发光学报 2022年43卷第3期页码：327-340
- 作者机构：
  
  1.福州大学　化学学院，福建　福州　350108
  2.中国科学院　福建物质结构研究所，中国科学院功能纳米结构设计与组装重点实验室，福建　福州　350002
- 作者简介：
  
  吕雪杰(1997-)，男，河南南阳人，硕士研究生，2019年于沈阳建筑大学获得学士学位，主要从事光功能玻璃陶瓷的研究。E-mail: lvxuejie@fjirsm.ac.cn
  许杰(1996-)，男，山西临汾人，硕士研究生，2018年于上海电力学院获得学士学位，主要从事光功能玻璃陶瓷的研究。E-mail: xujie@fjirsm.ac.cn
  林航(1983-)，男，福建福州人，博士，研究员，博士生导师，2011年于中国科学院福建物质结构研究所获得博士学位，主要从事光功能玻璃陶瓷的研究。E-mail: lingh@fjirsm.ac.cn
- 基金信息：
  
  国家自然科学基金(51972303;51872288;U2005213);福建省自然科学基金(2020H0035)
- DOI：10.37188/CJL.20210414
  中图分类号： O482.31
- 收稿：2021-12-29，
  
  修回：2022-01-14，
  
  纸质出版：2022-03
- 稿件说明：
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吕雪杰, 许杰, 林航, 等. Pr³⁺掺杂红色长余辉发光材料研究进展[J]. 发光学报, 2022,43(3):327-340. DOI: 10.37188/CJL.20210414.

Xue-jie LYU, Jie XU, Hang LIN, et al. Research Progress on Pr³⁺ Doped Red Persistent Luminescent Materials[J]. Chinese Journal of Luminescence, 2022, 43(3): 327-340. DOI: 10.37188/CJL.20210414.
吕雪杰, 许杰, 林航, 等. Pr³⁺掺杂红色长余辉发光材料研究进展[J]. 发光学报, 2022,43(3):327-340. DOI: 10.37188/CJL.20210414. DOI：

Xue-jie LYU, Jie XU, Hang LIN, et al. Research Progress on Pr³⁺ Doped Red Persistent Luminescent Materials[J]. Chinese Journal of Luminescence, 2022, 43(3): 327-340. DOI: 10.37188/CJL.20210414. DOI：

摘要

掺杂长余辉发光材料因其稳定高效的红色持久性发光而备受关注。近年来，Pr

掺杂红色长余辉发光材料的基础研究和应用探索均取得了长足的进步。本文总结了Pr

离子发光特性与电荷迁移带位置的关系，概述了最近报道的发光材料体系，讨论了余辉性能的优化途径，介绍了相关材料在信息加密、交流发光二极管(AC-LED)、生物成像、应力传感等新领域的应用。最后，指出了目前Pr

掺杂红色长余辉发光材料研究中仍存在的问题，并对其未来的研究方向进行了展望。

Abstract

doped afterglow materials have attracted much attention due to their stable and efficient red persistent luminescence. In recent years

the basic research and application exploration of Pr

doped red afterglow materials have made great progress. This paper summarizes the relationship between luminescence characteristics of Pr

ions and position of intervalence charge transfer band

overviews the recently reported luminescent material systems

discusses the optimization method to improve persistent luminesc

ence performance

and introduces the burgeoning application directions of the related materials in information encryption

AC-LED

biological imaging

and stress-sensing. Finally

the existing problems in the research of Pr

doped red afterglow luminescent materials are pointed out

and the future research directions of Pr

doped red afterglow luminescent materials are prospected.

关键词

Keywords

references

XU J , TANABE S . Persistent luminescence instead of phosphorescence: history,mechanism,and perspective [J ] . J. Lumin. , 2019 , 205 : 581 - 620 .

LI Y , GECEVICIUS M , QIU J R . Long persistent phosphors-from fundamentals to applications [J ] . Chem. Soc. Rev. , 2016 , 45 ( 8 ): 2090 - 2136 .

VAN DEN EECKHOUT K , POELMAN D , SMET P F . Persistent luminescence in non-Eu 2+ -doped compounds:a review [J ] . Materials ( Basel ) , 2013 , 6 ( 7 ): 2789 - 2818 .

ZHUANG Y X , KATAYAMA Y , UEDA J , et al . A brief review on red to near-infrared persistent luminescence in transition-metal-activated phosphors [J ] . Opt. Mater. , 2014 , 36 ( 11 ): 1907 - 1912 .

BOUTINAUD P , PINEL E , DUBOIS M , et al . UV-to-red relaxation pathways in CaTiO 3 ∶Pr 3+ [J ] . J. Lumin. , 2005 , 111 ( 1-2 ): 69 - 80 .

JIA W Y , JIA D D , RODRIGUEZ T , et al . UV excitation and trapping centers in CaTiO 3 ∶Pr 3+ [J ] . J. Lumin. , 2006 , 119-120 : 13 - 18 .

ABDUKAYUM A , YANG C X , ZHAO Q , et al . Gadolinium complexes functionalized persistent luminescent nanoparticles as a multimodal probe for near-infrared luminescence and magnetic resonance imaging in vivo [J ] . Anal. Chem. , 2014 , 86 ( 9 ): 4096 - 4101 .

LI Y , LI Y Y , SHARAFUDEEN K , et al . A strategy for developing near infrared long-persistent phosphors:taking M AlO 3 ∶Mn 4+ ,Ge 4+ ( M =La,Gd) as an example [J ] . J. Mater. Chem. C , 2014 , 2 ( 11 ): 2019 - 2027 .

LI Z J , ZHANG Y J , ZHANG H W , et al . Long-lasting phosphorescence functionalization of mesoporous silica nanospheres by CaTiO 3 ∶Pr 3+ for drug delivery [J ] . Microporous Mesoporous Mater. , 2013 , 176 : 48 - 54 .

ZHENG W X , WU H Y , JU G F , et al . Crystal field modulation-control,bandgap engineering and shallow/deep traps tailoring-guided design of a color-tunable long-persistent phosphor (Ca,Sr)Ga 4 O 7 ∶Mn 2+ ,Bi 3+ [J ] . Dalton Trans. , 2019 , 48 ( 1 ): 253 - 265 .

PEDROSO C C S , CARVALHO J M , RODRIGUES L C V , et al . Rapid and energy-saving microwave-assisted solid-state synthesis of Pr 3+ -,Eu 3+ -,or Tb 3+ -doped Lu 2 O 3 persistent luminescence materials [J ] . ACS Appl. Mater. Interfaces , 2016 , 8 ( 30 ): 19593 - 19604 .

QU B Y , ZHANG B , WANG L , et al . Mechanistic study of the persistent luminescence of CaAl 2 O 4 ∶Eu,Nd [J ] . Chem. Mater. , 2015 , 27 ( 6 ): 2195 - 2202 .

LIEPINA V , MILLERS D , SMITS K . Tunneling luminescence in long lasting afterglow of SrAl 2 O 4 ∶Eu,Dy [J ] . J. Lumin. , 2017 , 185 : 151 - 154 .

杨志平 , 刘冲 , 郭智 , 等 . 红色Y 2 O 2 S∶Eu 3+ 磷光材料的沉淀法制备和发光性能研究 [J ] . 河北大学学报(自然科学版) , 2004 , 24 ( 6 ): 585 - 588 .

YANG Z P , LIU C , GUO Z , et al . Preparation and characterization of Y 2 O 2 S∶Eu 3+ phosphors by co-precipitation method [J ] . J. Hebei Univ. ( Nat. Sci. Ed. ) , 2004 , 24 ( 6 ): 585 - 588 . (in Chinese)

刘冲 , 杨志平 , 李旭 , 等 . 燃烧法制备(Ca 1- x Sr x )S∶Eu 2+ 红色荧光粉的发光性能研究 [J ] . 河北大学学报(自然科学版) , 2008 , 28 ( 5 ): 466 - 470 .

LIU C , YANG Z P , LI X , et al . Study on the luminescent properties of (Ca 1- x Sr x )S∶Eu 2+ phosphor formed by combustion [J ] . J. Hebei Univ. ( Nat. Sci. Ed. ) , 2008 , 28 ( 5 ): 466 - 470 . (in Chinese)

KOJIMA Y , AOYAGI K , YASUE T . Afterglow mechanism and thermoluminescence of red-emitting CaS∶Eu 2+ ,Pr 3+ phosphor with incorporated Li + ion upon visible light irradiation [J ] . J. Lumin. , 2007 , 126 ( 2 ): 319 - 322 .

KOJIMA Y , TAKAHASHI A , UMEGAKI T . Synthesis of orange-red-emitting Eu 2+ ,Pr 3+ codoped SrS long afterglow phosphor [J ] . J. Lumin. , 2014 , 146 : 42 - 45 .

WU J P , NEWMAN D , VINEY I V F . Study on relationship of luminescence in CaS∶Eu,Sm and dopants concentration [J ] . J. Lumin. , 2002 , 99 ( 3 ): 237 - 245 .

GUO C F , CHU B L , SU Q . Improving the stability of alkaline earth sulfide-based phosphors [J ] . Appl. Surf. Sci. , 2004 , 225 ( 1-4 ): 198 - 203 .

WU J P , NEWMAN D , VINEY I V F . Structure-dependent photo- and infrared-stimulated luminescence of Eu 2+ and Sm 3+ in CaS∶Eu,Sm [J ] . J. Phys. D: Appl. Phys. , 2002 , 35 ( 10 ): 968 - 972 .

JIA D D . Enhancement of long-persistence by Ce co-doping in CaS∶Eu 2+ ,T m 3+ red phosphor [J ] . J. Electrochem. Soc. , 2006 , 153 ( 11 ): H198 - H201 .

SHEN Y Q , QIU K H , ZHANG W T , et al . Red-emitting enhancement of Bi 4 Si 3 O 12 ∶Sm 3+ phosphor by Pr 3+ co-doping for white LEDs application [J ] . Ceram. Int. , 2017 , 43 ( 12 ): 9158 - 9163 .

李金银 , 彭志雄 , 余丽萍 , 等 . Si,Lu掺杂Ca 0.8 Zn 0.2 TiO 3 ∶Pr 3+ 荧光粉的光学性能改善 [J ] . 发光学报 , 2018 , 39 ( 5 ): 643 - 652 .

LI J Y , PENG Z X , YU L P , et al . Improved luminescence properties of Ca 0.8 Zn 0.2 TiO 3 ∶Pr 3+ phosphors doped with Si and Lu [J ] . Chin. J. Lumin. , 2018 , 39 ( 5 ): 643 - 652 . (in Chinese)

TANG W , SUN Y , YU M , et al . White-light-emitting properties of SrTiO 3 ∶Pr 3+ nanoparticles [J ] . RSC Adv. , 2015 , 5 ( 35 ): 27491 - 27495 .

YU L , HAO J G , LI W , et al . Strong red emission and enhanced electrical properties in Pr-doped SrBi 4 Ti 4 O 15 multifunctional ceramics [J ] . J. Mater. Sci. : Mater. Electron. , 2019 , 30 ( 19 ): 17890 - 17898 .

MA S Z , FENG W L , CHEN R , et al . KSr 4 (BO 3 ) 3 ∶Pr 3+ :a new red-emitting phosphor for blue-pumped white light-emitting diodes [J ] . J. Alloys Compd. , 2017 , 700 : 49 - 53 .

LI H M , PANG R , LUO Y Q , et al . Commendable Pr 3+ -activated Ba 2 Ga 2 GeO 7 phosphor with high-brightness white long-persistent luminescence [J ] . J. Mater. Chem. C , 2019 , 7 ( 22 ): 6698 - 6705 .

PINEL E , BOUTINAUD P , MAHIOU R . What makes the luminescence of Pr 3+ different in CaTiO 3 and CaZrO 3 [J ] . J. Alloys Compd. , 2004 , 380 ( 1-2 ): 225 - 229 .

BOUTINAUD P , SARAKHA L , CAVALLI E , et al . About red afterglow in Pr 3+ doped titanate perovskites [J ] . J. Phys. D: Appl. Phys. , 2009 , 42 ( 4 ): 045106-1-7 .

王洪杰 , 马腾飞 , 张粟 , 等 . Pr 3+ 离子激活的新型长余辉发光材料GdY 1.46 Lu 0.5 Ga 3 Al 2 O 12 ∶0.04Pr 3+ 的发光性质研究 [J ] . 化工新型材料 , 2017 , 45 ( 4 ): 151 - 153 .

WANG H J , MA T F , ZHANG S , et al . Investigation on luminescence property of a novel long afterglow phosphor GdY 1.46 -Lu 0.5 Ga 3 Al 2 O 12 ∶0.04Pr 3+ [J ] . New Chem. Mater. , 2017 , 45 ( 4 ): 151 - 153 . (in Chinese)

BOUTINAUD P , PUTAJ P , MAHIOU R , et al . Quenching of lanthanide emission by intervalence charge transfer in crystals containing closed shell transition metal ions [J ] . Spectrosc. Lett. , 2007 , 40 ( 2 ): 209 - 220 .

BOUTINAUD P , CAVALLI E , BETTINELLI M . Emission quenching induced by intervalence charge transfer in Pr 3+ - or Tb 3+ -doped YNbO 4 and CaNb 2 O 6 [J ] . J. Phys. : Condens. Matter , 2007 , 19 ( 38 ): 386230-1-11 .

BOUTINAUD P , PINEL E , OUBAHA M , et al . Making red emitting phosphors with Pr 3+ [J ] . Opt. Mater. , 2006 , 28 ( 1-2 ): 9 - 13 .

LIU Z W , LIU Y L , ZHANG J X , et al . Long afterglow in Pr 3+ and Li + co-doped CaZrO 3 [J ] . Opt. Commun. , 2005 , 251 ( 4-6 ): 388 - 392 .

CHU M H , JIANG D P , ZHAO C J , et al . Long-lasting phosphorescence properties of pyrochlore La 2 Ti 2 O 7 ∶Pr 3+ phosphor [J ] . Chin. Phys. Lett. , 2010 , 27 : 4 .

DIALLO P T , BOUTINAUD P , MAHIOU R , et al . Red luminescence in Pr 3+ -doped calcium titanates [J ] . Phys. Status Solidi (a) , 1997 , 160 ( 1 ): 255 - 263 .

BOUTINAUD P , PINEL E , MAHIOU R . Luminescence and afterglow in CaTiO 3 ∶Pr 3+ films deposited by spray pyrolysis [J ] . Opt. Mater. , 2008 , 30 ( 7 ): 1033 - 1038 .

CHEN R , GAO Y T , GAO Y M . Synthesis and luminescence properties of CaTiO 3 ∶Pr 3+ ,Ni 2+ red phosphor [J ] . Solid State Sci. , 2019 , 89 : 161 - 166 .

WANG B , LIN H , XU J , et al . Design,preparation,and characterization of a novel red long-persistent perovskite phosphor:Ca 3 Ti 2 O 7 ∶Pr 3+ [J ] . Inorg. Chem. , 2015 , 54 ( 23 ): 11299 - 11306 .

JIANG T , ZHU Y F , ZHANG J C , et al . Multistimuli-responsive display materials to encrypt differentiated information in bright and dark fields [J ] . Adv. Funct. Mater. , 2019 , 29 ( 51 ): 1906068-1-10 .

LIN S P , XIONG C W , MA D C , et al . Persistent luminescence found in Mg 2+ and Pr 3+ co-doped LiNbO 3 single crystal [J ] . J. Mater. Chem. C , 2018 , 6 ( 37 ): 10067 - 10072 .

LI L Y , CASTAING V , RYTZ D , et al . Tunable trap depth for persistent luminescence by cationic substitution in Pr 3+ ∶K 1- x Na x NbO 3 perovskites [J ] . J. Am. Ceram. Soc. , 2019 , 102 ( 5 ): 2629 - 2639 .

LIANG Y J , LIU F , CHEN Y F , et al . Red/near-infrared/short-wave infrared multi-band persistent luminescence in Pr 3+ -doped persistent phosphors [J ] . Dalton Trans. , 2017 , 46 ( 34 ): 11149 - 11153 .

XIONG P X , PENG M Y , QIN K X , et al . Visible to near-infrared persistent luminescence and mechanoluminescence from Pr 3+ -doped LiGa 5 O 8 for energy storage and bioimaging [J ] . Adv. Opt. Mater. , 2019 , 7 ( 24 ): 1901107-1-11 .

TIAN X Y , LIAN S X , JI C Y , et al . Enhanced photoluminescence and ultrahigh temperature sensitivity from NaF flux assisted CaTiO 3 ∶Pr 3+ red emitting phosphor [J ] . J. Alloys Compd. , 2019 , 784 : 628 - 640 .

ZHANG R J , SONG Z , HE L Z , et al . Improvement of red-emitting afterglow properties via tuning electronic structure in perovskite-type (Ca 1- x Na x ) [Ti 1- x Nb x ] O 3 ∶Pr 3+ compounds [J ] . J. Alloys Compd. , 2017 , 729 : 663 - 670 .

TIAN S Y , LIU B T , ZHAO L , et al . Red photo-stimulated luminescence from deep traps of BaZrGe 3 O 9 ∶Pr 3+ for optical imaging application [J ] . J. Alloys Compd. , 2019 , 800 : 224 - 230 .

NOTO L L , PITALE S S , GUSOWKI M A , et al . Afterglow enhancement with In 3+ codoping in CaTiO 3 ∶Pr 3+ red phosphor [J ] . Powder Technol. , 2013 , 237 : 141 - 146 .

YANG L Q , CAI Z Y , YANG L Q , et al . Solid state synthesis,luminescence and afterglow enhancements of CaTiO 3 ∶Pr 3+ by Ga 3+ codoping [J ] . J. Lumin. , 2018 , 197 : 339 - 342 .

LI J H , YAN J , WEN D W , et al . Advanced red phosphors for white light-emitting diodes [J ] . J. Mater. Chem. C , 2016 , 4 ( 37 ): 8611 - 8623 .

周文 , 余丽萍 , 廉世勋 , 等 . 前驱溶液的pH值对制备Ca 2 Zn 4 Ti 16 O 38 ∶Pr 3+ ,Na + 发光粉物相、形貌和发光性质的影响 [J ] . 发光学报 , 2010 , 31 ( 5 ): 712 - 718 .

ZHOU W , YU L P , LIAN S X , et al . Influence of pH value in precursor solution on the component,morphology and photoluminescence of Ca 2 Zn 4 Ti 16 O 38 ∶Pr 3+ ,Na + phosphor [J ] . Chin. J. Lumin. , 2010 , 31 ( 5 ): 712 - 718 . (in Chinese)

YIN S Y , CHEN D H , TANG W J , et al . Synthesis of CaTiO 3 ∶Pr,Al phosphors by sol-gel method and their luminescence properties [J ] . J. Mater. Sci. , 2007 , 42 ( 8 ): 2886 - 2890 .

夏茂 , 谷智强 , 刘琼 , 等 . 红色长余辉荧光粉Ca 2 Zn 4 Ti 16 O 38 ∶Pr 3+ 的水热辅助合成及发光性质 [J ] . 无机化学学报 , 2015 , 31 ( 2 ): 253 - 259 .

XIA M , GU Z Q , LIU Q , et al . Hydrothermal assisted synthesis and photoluminescence properties of red persistent Ca 2 Zn 4 Ti 16 O 38 ∶Pr 3+ phosphor [J ] . Chin. J. Inorg. Chem. , 2015 , 31 ( 2 ): 253 - 259 . (in Chinese)

YOON S , OTAL E H , MAEGLI A E , et al . Improved persistent luminescence of CaTiO 3 ∶Pr by fluorine substitution and thermochemical treatment [J ] . J. Alloys Compd. , 2014 , 613 : 338 - 343 .

庄逸熙 , 陈敦榕 , 解荣军 . 面向光学信息存储应用的深陷阱长余辉发光材料 [J ] . 激光与光电子学进展 , 2021 , 58 ( 15 ): 1516001-1-24 .

ZHUANG Y X , CHEN D R , XIE R J . Persistent luminescent materials with deep traps for optical information storage [J ] . Laser Optoelectron. Prog. , 2021 , 58 ( 15 ): 1516001-1-24 . (in Chinese)

LIU R S , WANG X J . Phosphor Handbook : Novel phosphors , Synthesis , and Applications [M ] . 3rd ed . New York : CRC Press , 2022 .

LI X S , ZHAO L T . UV or blue light excited red persistent perovskite phosphor with millisecond lifetime for use in AC-LEDs [J ] . Luminescence , 2020 , 35 ( 1 ): 138 - 143 .

WANG L , ZHANG X , HAO Z D , et al . Interionic energy transfer in Y 3 Al 5 O 12 ∶Ce 3+ ,Pr 3+ phosphor [J ] . J. Appl. Phys. , 2010 , 108 ( 9 ): 093515-1-10 .

闫宏 , 宋婷 , 张猛 , 等 . 高性能X射线影像存储12CaO·7Al 2 O 3 ∶Pr 3+ 荧光粉的微结构及光学特性 [J ] . 发光学报 , 2018 , 39 ( 7 ): 895 - 902 .

YAN H , SONG T , ZHANG M , et al . Microstructure and optical properties of 12CaO·7Al 2 O 3 ∶Pr 3+ phosphors for high quality X-ray imaging [J ] . Chin. J. Lumin. , 2018 , 39 ( 7 ): 895 - 902 . (in Chinese)

ABDUKAYUM A , CHEN J T , ZHAO Q , et al . Functional near infrared-emitting Cr 3+ /Pr 3+ co-doped zinc gallogermanate persistent luminescent na noparticles with superlong afterglow for in vivo targeted bioimaging [J ] . J. Am. Chem. Soc. , 2013 , 135 ( 38 ): 14125 - 14133 .

TU D , XU C N , YOSHIDA A , et al . LiNbO 3 ∶Pr 3+ :a multipiezo material with simultaneous piezoelectricity and sensitive piezoluminescence [J ] . Adv. Mater. , 2017 , 29 ( 22 ): 1606914-1-4 .

LI X , HU R , WANG X S , et al . Intense mechanoluminescence and photostimulated luminescence with less afterglow in Pr 3+ /Gd 3+ co-doped LiTaO 3 phosphors [J ] . J. Lumin. , 2021 , 238 : 118222 .

YANG X X , LIU R , XU X H , et al . Effective repeatable mechanoluminescence in heterostructured Li 1- x Na x NbO 3 ∶Pr 3+ [J ] . Small , 2021 , 17 ( 46 ): 2103441 .

LUO H D , BOS A J J , DORENBOS P . Controlled electron-hole trapping and detrapping process in GdAlO 3 by valence band engineering [J ] . J. Phys. Chem. C , 2016 , 120 ( 11 ): 5916 - 5925 .

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DOI：10.37188/CJL.20210414

摘要

Abstract

关键词

Keywords

references

Pr³⁺掺杂红色长余辉发光材料研究进展

Research Progress on Pr³⁺ Doped Red Persistent Luminescent Materials