Mn<sup>4+</sup>激活荧光粉可用锰源与制备方法

王兆武; 屈巧; 姬海鹏; 郝小非; 李金生

doi:10.37188/CJL.20210412

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Mn⁴⁺激活荧光粉可用锰源与制备方法

特邀综述 | 更新时间：2022-05-23

- Mn⁴⁺激活荧光粉可用锰源与制备方法
  增强出版
- Available Manganese-containing Chemicals and Synthesis Methods for Mn⁴⁺-activated Phosphors
- 发光学报 2022年43卷第5期页码：662-675
- 作者机构：
  
  1.郑州大学材料科学与工程学院　郑州市先进能源催化功能材料制备技术重点实验室，河南　郑州　450001
  2.中国地质科学院　郑州矿产综合利用研究所，河南　郑州　450006
  3.东北大学秦皇岛分校　河北省电介质与电解质功能材料重点实验室，河北　秦皇岛　066004
- 作者简介：
  
  [ "王兆武(1985-)，男，河南新乡人，博士研究生，2015年于河南工业大学获得硕士学位，主要从事Mn4+激活红光荧光粉的研究。E-mail: smithen0504@gs.zzu.edu.cn" ]
  [ "姬海鹏(1989-)，男，河南南阳人，博士，副教授，2017年于中国地质大学(北京)获得博士学位，主要从事固体发光材料的研究。E-mail: jihp@zzu.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(51902291);中国博士后科学基金(2019M662524);河南省博士后科研启动基金(19030025);河南省重点研发与推广专项（科技攻关）(212102210180);河北省电介质与电解质重点实验室开放课题(HKDEFM2021301);河南省青年人才托举工程项目(2022HYTP016)
- DOI：10.37188/CJL.20210412
  中图分类号：
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王兆武, 屈巧, 姬海鹏, 等. Mn⁴⁺激活荧光粉可用锰源与制备方法[J]. 发光学报, 2022,43(5):662-675.

Zhao-wu WANG, Qiao QU, Hai-peng JI, et al. Available Manganese-containing Chemicals and Synthesis Methods for Mn⁴⁺-activated Phosphors[J]. Chinese Journal of Luminescence, 2022,43(5):662-675.
王兆武, 屈巧, 姬海鹏, 等. Mn⁴⁺激活荧光粉可用锰源与制备方法[J]. 发光学报, 2022,43(5):662-675. DOI： 10.37188/CJL.20210412.

Zhao-wu WANG, Qiao QU, Hai-peng JI, et al. Available Manganese-containing Chemicals and Synthesis Methods for Mn⁴⁺-activated Phosphors[J]. Chinese Journal of Luminescence, 2022,43(5):662-675. DOI： 10.37188/CJL.20210412.

摘要

Mn,4+,激活荧光粉可在蓝光激发下发射波长可调的红光，是当前白光发光二极管用荧光粉的研究热点之一。在制备Mn,4+,激活红光荧光粉时，有多种锰源可供选择，如K,2,MnF,6,、KMnO,4,、Mn（HPO,4,）,2,、MnCO,3,、MnO,2,、MnO、Mn（NO,3,）,2,、Mn（CH,3,COO）,2,等。本文综述了文献中在制备Mn,4+,激活氟化物、氟氧化物和氧化物基质红光荧光粉时采用的锰源，列举了相应的制备方法，并总结了采取不同锰源和制备方法对所合成荧光粉的荧光性质（如量子效率）等方面的影响。最后就如何控制Mn,4+,激活荧光粉中锰离子价态等进行了展望。

Abstract

The Mn,4+, activated phosphors can emit wavelength-tunable red luminescence under blue light excitation, which is one of the hotspots in the field of red phosphor for white light-emitting diodes. There are several manganese-containing chemicals that were used as manganese source, including K,2,MnF,6, KMnO,4, Mn(HPO,4,),2, MnCO,3, MnO,2, MnO, Mn(NO,3,),2, and Mn(CH,3,COO),2,. This mini-review summarized the types of these chemicals that have been chosen in literatures as the manganese source for the synthesis of Mn,4+,-doped fluoride, oxyfluoride, and oxide phosphors ,via, different synthesis methods. The influences of choosing different manganese sources and synthesis methods on the photoluminescence properties(for example, the quantum efficiency) of the as-prepared phosphors were summarized. Finally, the methods for controlling the valence state of manganese ions in the as-synthesized phosphors were prospected.

关键词

荧光粉锰离子锰源

Keywords

phosphormanganese ionmanganese-containing chemical

references

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Mn4+激活荧光粉可用锰源与制备方法

Available Manganese-containing Chemicals and Synthesis Methods for Mn4+-activated Phosphors

DOI：10.37188/CJL.20210412

摘要

Abstract

关键词

Keywords

references

Mn⁴⁺激活荧光粉可用锰源与制备方法

Available Manganese-containing Chemicals and Synthesis Methods for Mn⁴⁺-activated Phosphors