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Ta2O5对碲铋酸盐玻璃光学性能的影响
增强出版Effect of Ta2O5 on Optical Properties of Tellurium Bismuthate Glass
- 发光学报 2022年43卷第3期 页码：371-380
- 作者机构：
1.华东理工大学 材料科学与工程学院，上海 200237
2.浙江大学 材料科学与工程学院，浙江 杭州 310027
- 作者简介：
[ "李佳航(1997-)，男，浙江台州人，硕士研究生，2020年于中国计量大学获得学士学位，主要从事光学玻璃的研究。E-mail: Y30200888@mail.ecust.edu.cn" ]
[ "曾惠丹(1976-)，女，江西吉安人，博士，教授，2004年于中国科学院上海光学精密机械研究所获得博士学位，主要从事光功能材料、无机纳米材料等方向的研究。E-mail: hdzeng@ecust.edu.cn" ]
- 基金信息：国家自然科学基金(51872092;52072122)
DOI：10.37188/CJL.20210382
中图分类号： TQ171.733纸质出版日期：2022-03，
收稿日期：2021-12-07，
修回日期：2021-12-24，
- 稿件说明：
移动端阅览
李佳航, 俞佳, 胡美凤, 等. Ta2O5对碲铋酸盐玻璃光学性能的影响[J]. 发光学报, 2022,43(3):371-380.
JIA-HANG LI, JIA YU, MEI-FENG HU, et al. Effect of Ta2O5 on Optical Properties of Tellurium Bismuthate Glass. [J]. Chinese journal of luminescence, 2022, 43(3): 371-380.
李佳航, 俞佳, 胡美凤, 等. Ta2O5对碲铋酸盐玻璃光学性能的影响[J]. 发光学报, 2022,43(3):371-380. DOI： 10.37188/CJL.20210382.
JIA-HANG LI, JIA YU, MEI-FENG HU, et al. Effect of Ta2O5 on Optical Properties of Tellurium Bismuthate Glass. [J]. Chinese journal of luminescence, 2022, 43(3): 371-380. DOI： 10.37188/CJL.20210382.
摘要
通过高温熔融法制备了一系列(90-
x
)TeO
2
-10Bi
2
O
3
-
x
Ta
2
O
5
(
x
=0%
2%
4%
6%
8%)TBT玻璃样品。拉曼光谱和X射线光电子能谱测试结果显示，随着Ta
2
O
5
的加入，玻璃网络中的［TeO
3
］与［TeO
3+1
］向［TeO
4
］转变，玻璃网络结构更加致密。这解释了差示扫描量热法测试中TBT玻璃的玻璃化转变温度
T
g
随Ta
2
O
5
的含量增加而增加的变化原因。当Ta
2
O
5
从0升高到8%，吸收光谱以及光学带隙方程计算表明，玻璃样品的光学带隙和乌尔巴赫能(Urbach)不断降低。使用
Z
扫描方法测试了各个TeO
2
-Bi
2
O
3
-Ta
2
O
5
玻璃样品的三阶非线性光学特性，结果表明，TBT玻璃的三阶非线性与Ta
2
O
5
的加入量呈正相关。当Ta
2
O
5
的加入量为8%时，其三阶非线性极化率为3.30×10
-20
m
2
·V
-2
(2.36×10
-12
esu)，这表明该组成的碲铋酸盐玻璃在非线性光学领域具备潜在的应用价值。
Abstract
By using differential scanning calorimetry(DSC) method
this research indicates glass transition temperture(
T
g
) of a series of (90-
x
)TeO
2
-10Bi
2
O
3
-
x
Ta
2
O
5
(
x
=0%
2%
4%
6%
8%)(TBT) glass is increased with more Ta
2
O
5
added. The phenomenon of increasing
T
g
is mainly contributed to transformation of [TeO
3
] and [TeO
3+1
] to [TeO
4
] units. And the structure changes result in highly dense glass network structure which is supported by Raman spectroscopy and XPS charactreizations. Based on results of absorption spectrum and optical band gap equation calculation
when Ta
2
O
5
increases from 0 to 8%
the optical band gap and Urbach energy of such glass samples show decresing trends. The third-order nonlinear optical properties of TBT glass demonstrate positive correlation with concentration of Ta
2
O
5
through
Z-
scan measurement. The TBT glass with 8% Ta
2
O
5
has 3.30×10
-20
m
2
·V
-2
(2.36×10
-12
esu) of third-order nonlinear susceptibility. Thus
the outstanding properties of TBT glasses pave a way of nonlinear optical applications.
关键词
碲酸盐玻璃氧化钽非线性光学
Keywords
tellurite glasstantalum oxidenonlinear optics
references
TAN Z W, LU C. Optical fiber communication technology: present status and prospect [J]. Strateg. Study Chin. Acad. Eng., 2020, 22(3):100-107.
SAKIDA S, HAYAKAWA S, YOKO T. Part 1.125Te NMR study of tellurite crystals [J]. J. Non-Cryst. Solids, 1999, 243(1):1-12.
NEOV S, KOZHUKHAROV V, GERASIMOVA I, et al. A model for structural recombination in tellurite glasses [J]. J. Phys. C, 2001, 12(13):2475-2485.
JHA A, SHEN S, NAFTALY M. Structural origin of spectral broadening of 1.5-μm emission in Er3+-doped tellurite glasses [J]. Phys. Rev. B, 2000, 62(10):6215-6227.
SHEN S X, JHA A, LIU X B, et al. Tellurite glasses for broadband amplifiers and integrated optics [J]. J. Am. Ceram. Soc., 2002, 85(6):1391-1395.
CHEN F F, XU T F, DAI S X, et al. Linear and non-linear characteristics of tellurite glasses within TeO2-Bi2O3-TiO2 ternary system [J]. Opt. Mater., 2010, 32(9):868-872.
SHARMA R P, GUPTA P K, SINGH R K, et al. Nonlinear laser pulse response in a crystalline lens [J]. Opt. Lett., 2016, 41(7):1423-1426.
SABADEL J C, ARMAND P, CACHAU-HERREILLAT D, et al. Structural and nonlinear optical characterizations of tellurium oxide-based glasses:TeO2-BaO-TiO2 [J]. J. Solid State Chem., 1997, 132(2):411-419.
MILLER R C. Optical second harmonic generation in piezoelectric crystals [J]. Appl. Phys. Lett., 1964, 5(1):17-19.
SADDEEK Y B, ALY K A, SHAABAN K S, et al. Physical properties of B2O3-TeO2-Bi2O3 glass system [J]. J. Non-Cryst. Solids, 2018, 498:82-88.
WANG Y L, DAI S X, CHEN F F, et al. Physical properties and optical band gap of new tellurite glasses within the TeO2-Nb2O5-Bi2O3 system [J]. Mater. Chem. Phys., 2009, 113(1):407-411.
CHEN Y F, NIE Q H, XU T F, et al. A study of nonlinear optical properties in Bi2O3-WO3-TeO2 glasses [J]. J. Non-Cryst. Solids, 2008, 354(29):3468-3472.
CORDEIRO L, SILVA R M, DE PIETRO G M, et al. Thermal and structural properties of tantalum alkali-phosphate glasses [J]. J. Non-Cryst. Solids, 2014, 402:44-48.
董伟霞, 包启富, 顾幸勇, 等. Ta2O5掺杂玻璃/钙长石复合绝缘材料性能的研究 [J]. 材料导报, 2010, 24(S1):496-498, 511.
DONG W X, BAO Q F, GU X Y, et al. Effects of rare-earth tantalum oxide doping on the properties of glass/anorthite compositions [J]. Mater. Rep., 2010, 24(S1):496-498, 511. (in Chinese)
KILIC G, EL AGAWANY F I, ILIK B O, et al. Ta2O5 reinforced Bi2O3-TeO2-ZnO glasses:fabrication,physical,structural characterization,and radiation shielding efficacy [J]. Opt. Mater., 2021, 112:110757.
YAKINE I, CHAGRAOUI A, MOUSSAOUI A, et al. Synthesis and characterization of new amorphous and crystalline phases in Bi2O3-Ta2O5-TeO2 system [J]. J. Mater. Environ. Sci., 2012, 3(4):776-785.
INABA S, FUJINO S, MORINAGA K. Young‘s modulus and compositional parameters of oxide glasses [J]. J. Am. Ceram. Soc., 1999, 82(12):3501-3507.
GAAFAR M S, SHAARANY I, ALHARBI T. Structural investigations on some cadmium-borotellurate glasses using ultrasonic,FT-IR and X-ray techniques [J]. J. Alloys Compd., 2014, 616:625-632.
VEERANNA GOWDA V C. Effect of Bi3+ ions on physical,thermal,spectroscopic and optical properties of Nd3+ doped sodium diborate glasses [J]. Physica B Condens. Matter, 2013, 426:58-64.
GAIKWAD D K, SAYYED M I, BOTEWAD S N, et al. Physical,structural,optical investigation and shielding features of tungsten bismuth tellurite based glasses [J]. J. Non-Cryst. Solids, 2019, 503-504:158-168.
ELKHOSHKHANY N, ABBAS R, EL-MALLAWANY R, et al. Thermal properties of quaternary TeO2-ZnO-Nb2O5-Gd2O3 glasses [J]. Ceram. Int., 2014, 40(8):11985-11994.
TIJANI S A, AL-HADEETHI Y, SAMBO I, et al. Shielding of beta and bremsstrahlung radiation with transparent Bi2O3-B2O3-TeO2 glasses in therapeutic nuclear medicine [J]. J. Radiol. Prot., 2018, 38(3):N44-N51.
EL-MALLAWANY R, EL-AGAWANY F I, AL-BURIAHI M S, et al. Optical properties and nuclear radiation shielding capacity of TeO2-Li2O-ZnO glasses [J]. Opt. Mater., 2020, 106:109988-1-9.
王克强. 硅烷摩尔折射度与其分子结构之间关系的探讨 [J]. 有机化学, 1994(3):269-274.
WANG K Q. Studies on the relationship between molar refractions of silane and its molecular structure [J]. Chin. J. Org. Chem., 1994(3):269-274. (in Chinese)
WÓJCIK N A, TAGIARA N S, ALI S, et al. Structure and magnetic properties of BeO-Fe2O3-Al2O3-TeO2 glass-ceramic composites [J]. J. Eur. Ceram. Soc., 2021, 41(10):5214-5222.
JEANSANNETAS B, BLANCHANDIN S, THOMAS P, et al. Glass structure and optical nonlinearities in thallium(Ⅰ) tellurium(Ⅳ) oxide glasses [J]. J. Solid State Chem.,1999, 146(2):329-335.
OGBUU O, DU Q Y, LIN H T, et al. Impact of stoichiometry on structural and optical properties of sputter deposited multicomponent tellurite glass films [J]. J. Am. Ceram. Soc., 2015, 98(6):1731-1738.
DE PIETRO G M, PEREIRA C, GONÇALVES R R, et al. Thermal,structural,and crystallization properties of new tantalum alkali-germanate glasses [J]. J. Am. Ceram. Soc., 2015, 98(7):2086-2093.
NESBITT H W, BANCROFT G M, HENDERSON G S, et al. Bridging,non-bridging and free (O2–) oxygen in Na2O-SiO2 glasses:an X-ray photoelectron spectroscopic (XPS) and nuclear magnetic resonance (NMR) study [J]. J. Non-Cryst. Solids, 2011, 357(1):170-180.
KHATTAK G D, MEKKI A, WENGER L E. Local structure and redox state of copper in tellurite glasses [J]. J. Non-Cryst. Solids, 2004, 337(2):174-181.
魏忆, 李国岗. 高对称性晶体结构中实现Bi3+窄带蓝光发射 [J]. 发光学报, 2021, 42(9):1365-1375.
WEI Y, LI G G. Narrow-band blue emission of Bi3+ based on high crystal structure symmetry [J]. Chin. J. Lumin., 2021, 42(9):1365-1375. (in Chinese)
EL-MALLAWANY R. Tellurite Glass Smart Materials: Applications in Optics and Beyond [M]. Cham: Springer, 2018.
LAKSHMINARAYANA G, KAKY K M, BAKI S O, et al. Physical,structural,thermal,and optical spectroscopy studies of TeO2-B2O3-MoO3-ZnO-R2O(R=Li,Na,and K)/MO(M=Mg,Ca,and Pb) glasses [J]. J. Alloys Compd., 2017, 690:799-816.
UPENDER G, RAMESH S, PRASAD M, et al. Optical band gap,glass transition temperature and structural studies of (100-2x)TeO2-xAg2O-xWO3 glass system [J]. J. Alloys Compd., 2010, 504(2):468-474.
VON BLANCKENHAGEN B, TONOVA D, ULLMANN J. Application of the Tauc-Lorentz formulation to the interband absorption of optical coating materials [J]. Appl. Optics, 2002, 41(16):3137-3141.
WANG J, SHEIK-BAHAE M, SAID A A, et al. Time-resolved Z-scan measurements of optical nonlinearities [J]. J. Opt. Soc. Am. B, 1994, 11(6):1009-1017.
ZENG H D, LIU Z, JIANG Q, et al. Large third-order optical nonlinearity of ZnO-Bi2O3-B2O3 glass-ceramic containing Bi2ZnB2O7 nanocrystals [J]. J. Eur. Ceram. Soc., 2014, 34(16):4383-4388.
HE J L, ZHAN H, LIN A X. Structural property of bismuth-doped tellurite glasses for nonlinear and Raman fiber applications [J]. Opt. Mater., 2019, 96:109280-1-8.
KUMARI S, MOHAN D, YADAV S. Effect of Bi2O3 content on non linear optical properties of TeO2.Bi2O3.B2O3.ZnO glass system [J]. AIP Conf. Proc., 2019, 2093(1):020049-1-4.
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