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Ta2O5对碲铋酸盐玻璃光学性能的影响
增强出版Effect of Ta2O5 on Optical Properties of Tellurium Bismuthate Glass
- 发光学报 2022年43卷第3期 页码：371-380
- 作者机构：
1.华东理工大学 材料科学与工程学院，上海 200237
2.浙江大学 材料科学与工程学院，浙江 杭州 310027
- 作者简介：
[ "李佳航(1997-)，男，浙江台州人，硕士研究生，2020年于中国计量大学获得学士学位，主要从事光学玻璃的研究。E-mail: Y30200888@mail.ecust.edu.cn" ]
[ "曾惠丹(1976-)，女，江西吉安人，博士，教授，2004年于中国科学院上海光学精密机械研究所获得博士学位，主要从事光功能材料、无机纳米材料等方向的研究。E-mail: hdzeng@ecust.edu.cn" ]
- 基金信息：国家自然科学基金(51872092;52072122)
DOI：10.37188/CJL.20210382
中图分类号： TQ171.733收稿：2021-12-07，
修回：2021-12-24，
纸质出版：2022-03
- 稿件说明：
移动端阅览
李佳航, 俞佳, 胡美凤, 等. Ta2O5对碲铋酸盐玻璃光学性能的影响[J]. 发光学报, 2022,43(3):371-380.
Jia-hang LI, Jia YU, Mei-feng HU, et al. Effect of Ta2O5 on Optical Properties of Tellurium Bismuthate Glass[J]. Chinese Journal of Luminescence, 2022, 43(3): 371-380.
李佳航, 俞佳, 胡美凤, 等. Ta2O5对碲铋酸盐玻璃光学性能的影响[J]. 发光学报, 2022,43(3):371-380. DOI： 10.37188/CJL.20210382.
Jia-hang LI, Jia YU, Mei-feng HU, et al. Effect of Ta2O5 on Optical Properties of Tellurium Bismuthate Glass[J]. Chinese Journal of Luminescence, 2022, 43(3): 371-380. DOI： 10.37188/CJL.20210382.
摘要
通过高温熔融法制备了一系列(90-
x
)TeO
2
-10Bi
2
O
3
-
x
Ta
2
O
5
(
x
=0%
2%
4%
6%
8%)TBT玻璃样品。拉曼光谱和X射线光电子能谱测试结果显示，随着Ta
2
O
5
的加入，玻璃网络中的［TeO
3
］与［TeO
3+1
］向［TeO
4
］转变，玻璃网络结构更加致密。这解释了差示扫描量热法测试中TBT玻璃的玻璃化转变温度
T
g
随Ta
2
O
5
的含量增加而增加的变化原因。当Ta
2
O
5
从0升高到8%，吸收光谱以及光学带隙方程计算表明，玻璃样品的光学带隙和乌尔巴赫能(Urbach)不断降低。使用
Z
扫描方法测试了各个TeO
2
-Bi
2
O
3
-Ta
2
O
5
玻璃样品的三阶非线性光学特性，结果表明，TBT玻璃的三阶非线性与Ta
2
O
5
的加入量呈正相关。当Ta
2
O
5
的加入量为8%时，其三阶非线性极化率为3.30×10
-20
m
2
·V
-2
(2.36×10
-12
esu)，这表明该组成的碲铋酸盐玻璃在非线性光学领域具备潜在的应用价值。
Abstract
By using differential scanning calorimetry(DSC) method
this research indicates glass transition temperture(
T
g
) of a series of (90-
x
)TeO
2
-10Bi
2
O
3
-
x
Ta
2
O
5
(
x
=0%
2%
4%
6%
8%)(TBT) glass is increased with more Ta
2
O
5
added. The phenomenon of increasing
T
g
is mainly contributed to transformation of [TeO
3
] and [TeO
3+1
] to [TeO
4
] units. And the structure changes result in highly dense glass network structure which is supported by Raman spectroscopy and XPS charactreizations. Based on results of absorption spectrum and optical band gap equation calculation
when Ta
2
O
5
increases from 0 to 8%
the optical band gap and Urbach energy of such glass samples show decresing trends. The third-order nonlinear optical properties of TBT glass demonstrate positive correlation with concentration of Ta
2
O
5
through
Z-
scan measurement. The TBT glass with 8% Ta
2
O
5
has 3.30×10
-20
m
2
·V
-2
(2.36×10
-12
esu) of third-order nonlinear susceptibility. Thus
the outstanding properties of TBT glasses pave a way of nonlinear optical applications.
关键词
Keywords
references
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