Dy3+掺杂Lu2O3 和Y2O3 单晶光纤下转换荧光测温性能

张娜; 李阳; 尹延如; 王涛; 张健; 贾志泰

doi:10.37188/CJL.20210345

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Dy³⁺掺杂Lu₂O₃ 和Y₂O₃ 单晶光纤下转换荧光测温性能

材料合成及性能 | 更新时间：2022-02-25

- Dy³⁺掺杂Lu₂O₃ 和Y₂O₃ 单晶光纤下转换荧光测温性能
  增强出版
- Down-conversion Luminescence Performance of Dy³⁺ Doped Lu₂O₃ and Y₂O₃ Single Crystal Fibers for Temperature Sensing
- 发光学报 2022年43卷第2期页码：182-191
- 作者机构：
  
  . 山东大学　晶体材料国家重点实验室，山东　济南　250100
- 作者简介：
  
  [ "张娜(1994-)，女，山东济宁人，博士研究生，2017年于山东建筑大学获得学士学位，主要从事单晶光纤的生长表征与稀土掺杂光谱性能的研究。E-mail: sduzhangna@163.com" ]
  [ "李阳(1990-)，女，山东泰安人，博士，副研究员，2018年于山东大学晶体材料研究所获得博士学位，主要从事人工晶体材料的生长与性能的研究。E-mail: yangli@sdu.edu.cn" ]
  [ "尹延如(1988-)，女，山东济南人，博士，实验师，硕士生导师，2017年于山东大学晶体材料研究所获得博士学位，主要从事功能晶体材料的设计与生长的研究。E-mail: yyr@sdu.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(62105181);青岛市博士后应用研究
- DOI：10.37188/CJL.20210345
  中图分类号： O482.31
- 收稿日期：2021-11-04，
  
  修回日期：2021-11-22，
  
  纸质出版日期：2022-02
- 稿件说明：
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张娜, 李阳, 尹延如, 等. Dy³⁺掺杂Lu₂O₃ 和Y₂O₃ 单晶光纤下转换荧光测温性能[J]. 发光学报, 2022,43(2):182-191.

Na ZHANG, Yang LI, Yan-ru YIN, et al. Down-conversion Luminescence Performance of Dy³⁺ Doped Lu₂O₃ and Y₂O₃ Single Crystal Fibers for Temperature Sensing[J]. Chinese journal of luminescence, 2022, 43(2): 182-191.
张娜, 李阳, 尹延如, 等. Dy³⁺掺杂Lu₂O₃ 和Y₂O₃ 单晶光纤下转换荧光测温性能[J]. 发光学报, 2022,43(2):182-191. DOI： 10.37188/CJL.20210345.

Na ZHANG, Yang LI, Yan-ru YIN, et al. Down-conversion Luminescence Performance of Dy³⁺ Doped Lu₂O₃ and Y₂O₃ Single Crystal Fibers for Temperature Sensing[J]. Chinese journal of luminescence, 2022, 43(2): 182-191. DOI： 10.37188/CJL.20210345.

摘要

稀土倍半氧化物单晶光纤材料凭借超高的熔点(~2 400 ℃)、稳定的物化性能以及灵活的结构被认为是极具潜力的高温传感介质。本文采用激光加热基座(LHPG)法，成功生长了透明无开裂Dy

离子掺杂的倍半氧化物单晶光纤Lu

和Y

。依据Dy

离子的

15/2

和

9/2

能级为一对热耦合能级对(TCLs)，测试得到了430~520 nm波长范围内的下转换荧光光谱。荧光强度比(FIR)结果显示，晶体在298~673 K温度范围内的荧光强度具有良好的温度相关性。其中Dy∶Lu

在该范围内的最大相对灵敏度和绝对灵敏度分别为0.97%·K

-1

(315 K)和1.62×10

-4

-1

(673 K)，展现出更为优异的温度传感性能。

Abstract

Rare earth sesquioxide single crystal fibers(SCFs) are considered to be potential high-temperature sensing media due to their ultra-high melting point(~2 400 ℃)

stable physical and chemical properties and flexible structure. The transparent and crack-free Dy

doped Lu

and Y

single crystal fibers(SCFs) were successfully grown by laser heated pedestal growth(LHPG) method. According to the

15/2

and

9/2

energy levels of Dy

ion as a pair of thermally coupled energy levels(TCLs)

the down-conversion luminescence in the wavelength range of 430-520 nm was obtained. The fluorescence intensity ratio(FIR) measurement technique shows that the Dy

doped Lu

and Y

crystals have a good temperature dependence in the temperature range of 298-673 K. The maximum relative sensitivity and absolute sensitivity of Dy∶Lu

in this range are 0.97%·K

-1

(315 K) and 1.62×10

-4

-1

(673 K)

respectively

showing more excellent temperature sensing performance.

关键词

Keywords

references

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