基于变色效应的无机稀土发光材料荧光可逆调控及应用

白雪; 徐赞; 字映竹; 肖代文; 付丽香; 何彦妮; 赵和平; 杨钊烁; 宋友艳; HAIDER Asif Ali; 向斐斐; 宋志国; 寸阳珂; 邱建备; 杨正文

doi:10.37188/CJL.20210326

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基于变色效应的无机稀土发光材料荧光可逆调控及应用

封面文章 | 更新时间：2022-04-20

- 基于变色效应的无机稀土发光材料荧光可逆调控及应用
  封面论文增强出版
- Reversible Fluorescence Modulation and Applications Based on Chromic Effect in Inorganic Rare-earth Luminescent Materials
- 发光学报 2022年43卷第4期页码：463-477
- 作者机构：
  
  昆明理工大学　材料科学与工程学院，云南　昆明　650093
- 作者简介：
  
  [ "白雪(1993-)，女，宁夏银川人，博士研究生，2021年于昆明理工大学获得硕士学位，主要从事无机发光材料可逆发光调控的研究。E-mail: bx5660515@163.com" ]
  [ "寸阳珂(1993-)，女，云南腾冲人，博士，2020年于华南理工大学获得博士学位，主要从事光电材料与器件的研究。E-mail: cunyangke@kust.edu.cn" ]
  [ "邱建备(1970-)，男，浙江宁波人，博士，教授，博士生导师，2000年于日本神户大学获得博士学位，主要从事稀土光电功能材料的研究。E-mail: qiu@kust.edu.cn" ]
  [ "杨正文(1979-)，男，云南昭通人，博士，教授，博士生导师，2009年于清华大学获得博士学位，主要从事半导体及稀土发光材料、光子晶体调控光电材料的研究。E-mail: yangzw@kust.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(51762029);云南省应用基础研究重点项目(2018FA026);国家自然科学基金-云南省联合基金重点项目(U2102215)
- DOI：10.37188/CJL.20210326
  中图分类号： O482.31
- 纸质出版日期：2022-04-01，
  
  收稿日期：2021-10-14，
  
  修回日期：2021-10-30，
- 稿件说明：
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白雪, 徐赞, 字映竹, 等. 基于变色效应的无机稀土发光材料荧光可逆调控及应用[J]. 发光学报, 2022,43(4):463-477.

XUE BAI, ZAN XU, YING-ZHU ZI, et al. Reversible Fluorescence Modulation and Applications Based on Chromic Effect in Inorganic Rare-earth Luminescent Materials. [J]. Chinese journal of luminescence, 2022, 43(4): 463-477.
白雪, 徐赞, 字映竹, 等. 基于变色效应的无机稀土发光材料荧光可逆调控及应用[J]. 发光学报, 2022,43(4):463-477. DOI： 10.37188/CJL.20210326.

XUE BAI, ZAN XU, YING-ZHU ZI, et al. Reversible Fluorescence Modulation and Applications Based on Chromic Effect in Inorganic Rare-earth Luminescent Materials. [J]. Chinese journal of luminescence, 2022, 43(4): 463-477. DOI： 10.37188/CJL.20210326.

摘要

无机稀土发光材料在照明、显示、激光和生物医学等领域有着极其广泛的应用。对荧光性能的调控有利于拓展其在温度传感、防伪识别、光开关、光存储等领域的应用。传统的荧光调控方式包括设计核壳结构、改变材料成分控制晶体场、改变稀土离子的掺杂类型或浓度从而控制能量传递等。然而，这些调控方式难以实现荧光性能的可逆调控，限制了其实际应用。对比传统的调控方式，材料在电场、热场或光场等外场刺激下可产生变色效应，通过变色效应可以实现对其荧光性能的可逆调控从而扩展其应用。本文主要综述了在电场、热场和光场刺激下，无机稀土发光材料的变色效应对其荧光性能的可逆调控及应用。

Abstract

Inorganic rare-earth luminescent materials are widely used in lighting

display

laser and biomedicine. The fluorescence modulation is beneficial to expand the applications in temperature sensing

anti-counterfeiting

optical switch

optical storage

et al

. However

the traditional fluorescence modulation methods such as designing the core and shell structure

changing the material composition to control the crystal field

and changing the doping type or concentration of rare earth ions to control the energy transfer are difficult to achieve reversible modulation of fluorescence properties

limiting their practical applications. Compared with these traditional methods

the color of materials can change under external stimulation

such as electric field

thermal field and light field. The reversible fluorescence modulation based on the chromic effect could expand the applications. In this paper

the reversible modulation based on chromic effect under electric field

thermal field or light field stimulation in inorganic rare-earth luminescent materials and their applications were mainly reviewed.

关键词

无机稀土发光材料荧光调控电致变色热致变色光致变色

Keywords

inorganic rare-earth luminescent materialsfluorescence modulationelectrochromicthermochromicphotochromic

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