浏览全部资源
扫码关注微信
新型中红外激光晶体Er3+/Ho3+/Eu3+∶PbF2的生长和性能
增强出版Growth and Properties of Novel Mid-infrared Laser Crystal Er3+ /Ho3+/Eu3+∶PbF2
- 发光学报 2021年42卷第12期 页码：1852-1862
- 作者机构：
1.广东省晶体与激光技术工程研究中心，广东 广州 510632
2.暨南大学理工学院 光电工程系，广东 广州 510632
- 作者简介：
[ "廖家裕(1996-)，女，广东广州人，硕士研究生，2019年于广州大学获得学士学位，主要从事激光与光电功能晶体材料的研究。E-mail: jyliao@stu2019.jnu.edu.cn" ]
[ "张沛雄(1987-)，男，广东潮州人，博士，副研究员，2016年于中国科学院上海光学精密机械研究所获得博士学位，主要从事激光与光电功能晶体材料的研究。Email: pxzhang@jnu.edu.cn" ]
- 基金信息：国家自然科学基金(51972149;51872307;61935010;51702124);中央高校基本科研业务费专项资金(21620445)
DOI：10.37188/CJL.20210312
中图分类号： O482.31收稿日期：2021-09-28，
修回日期：2021-10-06，
纸质出版日期：2021-12
- 稿件说明：
移动端阅览
廖家裕, 陈鸿玲, 牛晓晨, 等. 新型中红外激光晶体Er3+/Ho3+/Eu3+∶PbF2的生长和性能[J]. 发光学报, 2021,42(12):1852-1862.
Jia-yu LIAO, Hong-ling CHEN, Xiao-chen NIU, et al. Growth and Properties of Novel Mid-infrared Laser Crystal Er3+ /Ho3+/Eu3+∶PbF2[J]. Chinese journal of luminescence, 2021, 42(12): 1852-1862.
廖家裕, 陈鸿玲, 牛晓晨, 等. 新型中红外激光晶体Er3+/Ho3+/Eu3+∶PbF2的生长和性能[J]. 发光学报, 2021,42(12):1852-1862. DOI： 10.37188/CJL.20210312.
Jia-yu LIAO, Hong-ling CHEN, Xiao-chen NIU, et al. Growth and Properties of Novel Mid-infrared Laser Crystal Er3+ /Ho3+/Eu3+∶PbF2[J]. Chinese journal of luminescence, 2021, 42(12): 1852-1862. DOI： 10.37188/CJL.20210312.
摘要
采用垂直布里奇曼法成功生长了Er
3+
/Ho
3+
/Eu
3+
三掺杂PbF
2
的中红外激光晶体。该晶体在980 nm泵浦下，首次获得了从2 600~3 200 nm的宽带中红外发光，其半高宽(FWHM)为300 nm，这是Er
3+
的2.7 μm发射峰(2 600~2 950 nm)和Ho
3+
的2.9 μm发射峰(2 800~3 200 nm)叠加的结果。此外，失活离子Eu
3+
的引入可以有效克服Er
3+
和Ho
3+
离子的自终止瓶颈效应。研究发现，与Er
3+
/Ho
3+
∶PbF
2
晶体相比，Er
3+
/Ho
3+
/Eu
3+
∶PbF
2
晶体具有更高的荧光分支比，在Er
3+
:
4
I
11/2
→
4
I
13/2
跃迁为18.7%和Ho
3+
:
5
I
6
→
5
I
7
跃迁为18.0%；以及有更大的发射截面，在2 745 nm时为0.621×10
-20
cm
2
，在2 905 nm时为0.728×10
-20
cm
2
。这些有利的光谱特性表明，Er
3+
/Ho
3+
/Eu
3+
∶PbF
2
晶体在商用980 nm激光二极管泵浦下，可能是2.6~3.2 μm中红外激光器的一种有前景的材料。
Abstract
In this work
Er
3+
/Ho
3+
/Eu
3+
tri-doped PbF
2
mid-infrared laser crystal was successfully grown using the vertical Bridgman method. As far as we know
it is the first time to obtain a broadband mid-infrared luminescence extending from 2 600 nm to 3 200 nm with a full width at half maximum (FWHM) of 300 nm under 980 nm pump
which is the result of the superposition of the 2.7 μm emission peak of Er
3+
(2 600-2 950 nm) and 2.9 μm emission peak of Ho
3+
(2 800-3 200 nm). What's more
the introduction of deactivation ions Eu
3+
can conquer self-termination bottleneck of both Er
3+
and Ho
3+
ions effectively. It is found that
compared with the Er
3+
/Ho
3+
∶PbF
2
crystal
the Er
3+
/Ho
3+
/Eu
3+
∶PbF
2
crystal has higher fluorescence branching ratio 18.7% of Er
3+
:
4
I
11/2
→
4
I
13/2
transition and 18.0% of Ho
3+
:
5
I
6
→
5
I
7
transition
and larger emission cross section 0.621×10
-20
cm
2
at 2 745 nm and 0.728×10
-20
cm
2
at 2 905 nm. These advantageous spectroscopic characteristics suggest that the Er
3+
/Ho
3+
/Eu
3+
∶PbF
2
crystal may be a promising material for 2.6-3.2 μm mid-infrared lasers under the pump of a commercial 980 nm laser diodes (LDs).
关键词
Keywords
references
SOBON G , MARTYNKIEN T , TARNOWSKI K , et al . Generation of sub-100 fs pulses tunable from 1 700 to 2 100 nm from a compact frequency-shifted Er-fiber laser [J]. Photon. Res. , 2017 , 5 ( 3 ): 151 - 155 .
SIGRIST M W . Mid-infrared laser-spectroscopic sensing of chemical species [J]. J. Adv. Res. , 2015 , 6 ( 3 ): 529 - 533 .
杨俊彦 , 公发全 , 刘锐 , 等 . 中红外激光在光电对抗领域的应用及进展 [J]. 飞控与探测 , 2020 , 3 ( 6 ): 34 - 42 .
YANG J Y , GONG F Q , LIU R , et al . Application and progress of mid-infrared laser in optoelectronic countermeasure field [J]. Flight Control & Detection , 2020 , 3 ( 6 ): 34 - 42 . (in Chinese)
张振 , 苏良碧 . 掺Er3+晶体近3 μm中红外激光研究进展 [J]. 人工晶体学报 , 2020 , 49 ( 8 ): 1361 - 1368 .
ZHANG Z , SU L B . Research progress of near 3 μm mid-infrared laser based on Er3+ doped single crystals [J]. J. Synth. Cryst. , 2020 , 49 ( 8 ): 1361 - 1368 . (in Chinese)
周华 , 姚传飞 , 贾志旭 , 等 . 中红外可调谐大能量飞秒脉冲激光产生 [J]. 发光学报 , 2020 , 41 ( 4 ): 435 - 441 .
ZHOU H , YAO C F , JIA Z X , et al . Mid-infrared tunable high pulse energy femtosecond pulse laser generation [J]. Chin. J. Lumin. , 2020 , 41 ( 4 ): 435 - 441 . (in Chinese)
SOROKINA I T . Crystalline mid-infrared lasers [M]. SOROKINA I T , VODOPYANOV K L . Solid-State Mid-infrared Laser Sources . Berlin, Heidelberg : Springer , 2003 , 89 ∶ 262 - 358 .
VODOPYANOV K , GANIKHANOV F , MAFFETONE J , et al . ZnGeP2 optical parametric oscillator with 3.8-12.4 μm tunability [J]. Opt. Lett. , 2000 , 25 ( 11 ): 841 - 843 .
ZHANG J H , CASSAN E , ZHANG X L . Enhanced mid-to-near-infrared second harmonic generation in silicon plasmonic microring resonators with low pump power [J]. Photon. Res. , 2014 , 2 ( 5 ): 143 - 149 .
TIKHOMIROV V K , MÉNDEZ-RAMOS J , RODRÍGUEZ V D , et al . Laser and gain parameters at 2.7 μm of Er3+-doped oxyfluoride transparent glass-ceramics [J]. Opt. Mater. , 2006 , 28 ( 10 ): 1143 - 1146 .
彭江涛 , 夏海平 , 汪沛渊 , 等 . Ho3+∶LiYF4晶体的中红外发光特性 [J]. 发光学报 , 2013 , 34 ( 6 ): 702 - 710 .
PENG J T , XIA H P , WANG P Y , et al . Mid-infrared emission properties of Ho3+ doped LiYF4 single crystals [J]. Chin. J. Lumin. , 2013 , 34 ( 6 ): 702 - 710 . (in Chinese)
JACKSON S D . High-power and highly efficient diode-cladding-pumped holmium-doped fluoride fiber laser operating at 2.94 μm [J]. Opt. Lett. , 2009 , 34 ( 15 ): 2327 - 2329 .
WANG Y , LI J F , YOU Z Y , et al . Enhanced 2.7 μm emission and its origin in Nd3+/Er3+ codoped SrGdGa3O7 crystal [J]. J. Quant. Spectrosc. Radiat. Transf. , 2014 , 149 : 253 - 257 .
王敏刚 , 叶斌 , 魏冉 , 等 . Er3+∶CaMoO4单晶的坩埚下降法生长与光谱性能 [J]. 人工晶体学报 , 2015 , 44 ( 10 ): 2626 - 2631 .
WANG M G , YE B , WEI R , et al . Growth and spectral properties of Er3+∶CaMoO4 single crystal by vertical bridgman method [J]. J. Synth. Cryst. , 2015 , 44 ( 10 ): 2626 - 2631 . (in Chinese)
CAI M Z , ZHOU B E , TIAN Y , et al . Broadband mid-infrared 2.8 μm emission in Ho3+/Yb3+-codoped germanate glasses [J]. J. Lumin. , 2016 , 171 : 143 - 148 .
DE SOUSA D F , ZONETTI L F C , BELL MJ V , et al . On the observation of 2.8 μm emission from diode-pumped Er3+ and Yb3+ doped low silica calcium aluminate glasses [J]. Appl. Phys. Lett. , 1999 , 74 ( 7 ): 908 - 910 .
SCHNEIDE J , CARBONNIER C , UNRAU U B . Characterization of a Ho3+ doped fluoride fiber laser with a 3.9-μm emission wavelength [J]. Appl. Opt. , 1997 , 36 ( 33 ): 8595 - 8600 .
ZHOU B , LIN H , YANG D L , et al . Emission of 1.38 μm and gain properties from Ho3+ doped low-phonon-energy gallate bismuth lead oxide glasses for fiber-optic amplifiers [J]. Opt. Lett. , 2010 , 35 ( 2 ): 211 - 213 .
CHICKLIS E P , NAIMAN C S , FOLWEILER R , et al . Stimulated emission in multiply doped Ho3+∶YLF and YAG—a comparison [J]. IEEE J. Quantum Electron. , 1972 , 8 ( 2 ): 225 - 230 .
杨润柏 , 李奕 , 徐楠 , 等 . 碱金属离子对稀土掺杂氟化物上转换荧光的影响 [J]. 发光学报 , 2019 , 40 ( 1 ): 1 - 8 .
YANG R B , LI Y , XU N , et al . Effects of alkali metal ions on upconversion of rare earth doped fluorides [J]. Chin. J. Lumin. , 2019 , 40 ( 1 ): 1 - 8 . (in Chinese)
NICOARA I , LIGHEZAN L , ENCULESCU M , et al . Optical spectroscopy of Yb2+ ions in YbF3-doped CaF2 crystals [J]. J. Cryst. Growth , 2008 , 310 ( 7-9 ): 2026 - 2032 .
YIN J G , HANG Y , HE X H , et al . Transition intensities and excited state relaxation dynamics of Tm3+ in Tm∶PbF2 crystal [J]. Laser Phys. , 2012 , 22 ( 3 ): 609 - 613 .
ZHANG P X , HANG Y , ZHANG L H . Deactivation effects of the lowest excited state of Ho3+ at 2.9 μm emission introduced by Pr3+ ions in LiLuF4 crystal [J]. Opt. Lett. , 2012 , 37 ( 24 ): 5241 - 5243 .
张沛雄 , 李善明 , 杨依伦 , 等 . 中红外氟化物激光晶体的生长和性能优化研究 [J]. 人工晶体学报 , 2021 , 49 ( 8 ): 1369 - 1378 .
ZHANG P X , LI S M , YANG Y L , et al . Growth and performance optimization of mid-infrared fluoride laser crystal [J]. J. Synth. Cryst. , 2021 , 49 ( 8 ): 1369 - 1378 . (in Chinese)
BURTON J A , PRIM R C , SLICHTER W P . The distribution of solute in crystals grown from the Melt. Part I. Theoretical [J]. J. Chem. Phys. , 1953 , 21 ( 11 ): 1987 - 1991 .
HAYES W , RUSHWORTH A J , RYAN J F , et al . A Raman-scattering study of disorder in PbF2 at high temperatures [J]. J. Phys. C Solid State Phys. , 1997 , 10 ( 5 ): L111 - L114 .
HATCH S E , PARSONS W F , WEAGLEY R J . Hot-pressed polycrystalline CaF2∶Dy2+ laser [J]. Appl. Phys. Lett. , 1964 , 5 ( 8 ): 153 - 154 .
ZHANG P X , YIN J G , ZHANG B T , et al . Intense 2.8 μm emission of Ho3+ doped PbF2 single crystal [J]. Opt. Lett. , 2014 , 39 ( 14 ): 3942 - 3945 .
TIKHOMIROV V K , FURNISS D , SEDDON A B , et al . Fabrication and characterization of nanoscale,Er3+-doped,ultratransparent oxy-fluoride glass ceramics [J]. Appl. Phys. Lett. , 2002 , 81 ( 11 ): 1937 - 1939 .
HUANG X B , YANG Y H , ZHANG P X , et al . Efficiently strengthen and broaden 3 μm fluorescence in PbF2 crystal by Er3+/Ho3+ as co-luminescence centers and Pr3+ deactivation [J]. J. Alloys Compd. , 2019 , 811 : 152027-1-8 .
JUDD B R . Optical absorption intensities of rare-earth ions [J]. Phys. Rev. , 1962 , 127 ( 3 ): 750 - 761 .
OFELT G S . Intensities of crystal spectra of rare-earth ions [J]. J. Chem. Phys. , 1962 , 37 ( 3 ): 511 - 520 .
沈定中 , 任国浩 . 氟化铅晶体的生长新技术及其Cherenkov辐射效应 [J]. 物理 , 2001 , 30 ( 8 ): 496 - 500 .
SHEN D Z , REN G H . New growth method for lead fluoride crystal with strong Cherenkov effect [J]. Physics , 2001 , 30 ( 8 ): 496 - 500 . (in Chinese)
LIU Y Y , WANG Y , YOU Z Y , et al . Growth,structure and spectroscopic properties of melilite Er∶CaLaGa3O7 crystal for use in mid-infrared laser [J]. J. Alloys Compd. , 2017 , 706 : 387 - 394 .
MA W W , SU L B , XU X D , et al . Effect of erbium concentration on spectroscopic properties and 2.79 μm laser performance of Er∶CaF2 crystals [J]. Opt. Mater. Express , 2016 , 6 ( 2 ): 409 - 415 .
ZHOU B E , WEI T , CAI M Z , et al . Analysis on energy transfer process of Ho3+ doped fluoroaluminate glass sensitized by Yb3+ for mid-infrared 2.85 μm emission [J]. J. Quant. Spectrosc. Radiat. Transfer , 2014 , 149 : 41 - 50 .
FENG L , WANG J , TANG Q , et al . Optical properties of Ho3+ -doped novel oxyfluoride glasses [J]. J. Lumin. , 2017 , 124 ( 2 ): 187 - 194 .
HE W Y , WANG X F , ZHENG J , et al . Optical property of Dy3+ -and Ce3+ -doped Si-B-Na-Sr glasses [J]. J. Am. Ceram. Soc. , 2014 , 97 ( 6 ): 1750 - 1755 .
XU R R , TIAN Y , HU L L , et al . Enhanced emission of 2.7 μm pumped by laser diode from Er3+/Pr3+ co-doped germanate glasses [J]. Opt. Lett. , 2011 , 36 ( 7 ): 1173 - 1175 .
0
浏览量
143
下载量
2
CSCD
- 网络PDF下载
- Meta-XML下载
- BibTeX下载
- Endnote下载
- RefMan 下载
- NoteExpress下载
- NoteFirst下载
关联资源
相关文章
相关作者
相关机构
- 地址：长春市经济技术开发区东南湖大路3888号 邮编：130033
- 联系电话：0431-86176862 Email：fgxbt@126.com
- 本系统由Light学术出版中心、北京北大方正电子有限公司共建 吉ICP备11002662号-17
京公网安备11010802024621 - 本系统建议在Chrome、 IE9+ 以上版本浏览器阅读本站内容，360浏览器请切换至极速模式
- Cookies帮助我们提供服务并提供个性化体验。使用本网站，即表示您同意我们使用Cookies
