高长径比Eu3+掺杂Y2O3荧光陶瓷纤维的制备及其发光性能

张立振; 王子豪; 黄娇; 唐飞

doi:10.37188/CJL.20210297

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高长径比Eu³⁺掺杂Y₂O₃荧光陶瓷纤维的制备及其发光性能

材料合成及性能 | 更新时间：2021-12-17

- 高长径比Eu³⁺掺杂Y₂O₃荧光陶瓷纤维的制备及其发光性能
  增强出版
- Fabrication and Photoluminescence Properties of Eu³⁺ Doped Y₂O₃ Ceramic Fiber with High Aspect Ratio
- 发光学报 2021年42卷第12期页码：1891-1899
- 作者机构：
  
  1.江苏师范大学物理与电子工程学院　江苏省先进激光材料与器件重点实验室，江苏　徐州　221116
  2.中国人民解放军32506部队，江苏　徐州　221116
- 作者简介：
  
  [ "张立振(1994-)，男，江苏徐州人，硕士研究生，2019年于长春理工大学获得学士学位，主要从事无机发光材料制备及性能的研究。E-mail: 2020201181@jsnu.edu.cn" ]
  [ "唐飞(1985-)，男，江苏淮安人，博士，教授，2013年于中国科学院福建物质结构研究所获得博士学位，主要从事透明陶瓷、高效发光材料及光谱物理等方向的研究。E-mail: ftang@jsnu.edu.cn" ]
- 基金信息：
  
  国家自然科学基金青年项目(51902144);江苏省自然科学基金青年项目(BK20191003);2020年江苏省特聘教授项目;2020年江苏省“中红外激光技术”双创团队
- DOI：10.37188/CJL.20210297
  中图分类号： O482.31
- 纸质出版日期：2021-12，
  
  收稿日期：2021-09-08，
  
  修回日期：2021-09-25，
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张立振, 王子豪, 黄娇, 等. 高长径比Eu³⁺掺杂Y₂O₃荧光陶瓷纤维的制备及其发光性能[J]. 发光学报, 2021,42(12):1891-1899.

Li-zhen ZHANG, Zi-hao WANG, Jiao HUANG, et al. Fabrication and Photoluminescence Properties of Eu³⁺ Doped Y₂O₃ Ceramic Fiber with High Aspect Ratio[J]. Chinese Journal of Luminescence, 2021,42(12):1891-1899.
张立振, 王子豪, 黄娇, 等. 高长径比Eu³⁺掺杂Y₂O₃荧光陶瓷纤维的制备及其发光性能[J]. 发光学报, 2021,42(12):1891-1899. DOI： 10.37188/CJL.20210297.

Li-zhen ZHANG, Zi-hao WANG, Jiao HUANG, et al. Fabrication and Photoluminescence Properties of Eu³⁺ Doped Y₂O₃ Ceramic Fiber with High Aspect Ratio[J]. Chinese Journal of Luminescence, 2021,42(12):1891-1899. DOI： 10.37188/CJL.20210297.

摘要

采用浆料直写(DIW)挤出成型工艺结合高温固相反应烧结技术，成功制备出高长径比稀土Eu

掺杂Y

荧光陶瓷纤维。分别研究了陶瓷膏体的流变性能、陶瓷纤维的相结构和荧光动力学、以及不同温度下陶瓷纤维的荧光光谱演变。研究结果表明，采用羟丙基甲基纤维素(HPMC)水凝胶作为陶瓷膏体的有机助剂，最佳的粉体固含量为55%。烧结温度

1 200 ℃下均可得到纯的陶瓷晶相，随着温度的升高，陶瓷相没有明显变化，但在1 300 ℃下烧结得到的样品荧光寿命最长，可达1.12 ms。进一步表征了该温度下烧结样品的变温光致发光光谱，随着温度从100 K上升至500 K，发光光谱的积分强度没有明显降低，表明所制备的样品具有优异的发光热稳定性。

Abstract

doped Y

ceramic fiber phosphor with high aspect ratio was successfully fabricated by using direct ink writing(DIW) extrusion process combined with high temperature solid-state reaction method. The rheological properties of ceramic paste

phase structure and luminescence kinetic of ceramic fiber

as well as the temperature dependent photoluminescence(PL) spectra were successively investigated. The obtained results indicated that the optimal solid content was 55% for the ceramic paste with HPMC hydrogels as the additive. Pure ceramic phase could be achieved at the sintering temperature of

1 200 ℃. With increasing the temperature to 1 500 ℃

no significant change was observed for the phase structure. From the steady-state and transient PL spectra

the optimum luminescence performance was observed for the sample sintered at 1 300 ℃ with the luminescence lifetime of 1.12 ms. Finally

the temperature dependence of PL spectra was carefully studied

and the luminescence properties were not deteriorated with increasing temperature from 100 K to 500 K. Such a result may indicate an excellent luminescence thermal stability for our ceramic fiber.

关键词

荧光陶瓷纤维(Y0.85La0.10Eu0.05)2O3流变性能光致发光荧光寿命

Keywords

ceramic fiber phosphor(Y0.85La0.10Eu0.05)2O3rheological propertiesphotoluminescenceluminescence lifetime

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