真空紫外光及X射线激发下Pr3+掺杂Ba3La(PO4)3 发光性质

时秋峰; 王磊; 郭海洁; 黄平; 崔彩娥; 黄艳

doi:10.37188/CJL.20210281

您当前的位置：

首页 >

文章列表页 >

真空紫外光及X射线激发下Pr³⁺掺杂Ba₃La(PO₄)₃ 发光性质

材料合成及性能 | 更新时间：2021-11-23

- 真空紫外光及X射线激发下Pr³⁺掺杂Ba₃La(PO₄)₃ 发光性质
  增强出版
- Luminescence Properties of Pr³⁺ Doped in Ba₃La(PO₄)₃ with Vacuum Ultraviolet and X-ray Excitation
- 发光学报 2021年42卷第11期页码：1756-1762
- 作者机构：
  
  1.太原理工大学　物理与光电工程学院，山西　太原　030024
  2.中国科学院高能物理研究所　北京同步辐射装置，北京　100049
- 作者简介：
  
  [ "时秋峰(1983-)，男，河北沧州人，博士，讲师，2014年于北京交通大学光电子技术研究所获得博士学位，主要从事新型发光材料设计与发光机理的研究。E-mail: shiqiufeng@tyut.edu.cn" ]
- 基金信息：
  
  山西省重点研发计划项目(201903D121097)
- DOI：10.37188/CJL.20210281
  中图分类号： O482.31
- 收稿日期：2021-08-26，
  
  修回日期：2021-09-13，
  
  纸质出版日期：2021-11-01
- 稿件说明：
移动端阅览
时秋峰, 王磊, 郭海洁, 等. 真空紫外光及X射线激发下Pr³⁺掺杂Ba₃La(PO₄)₃ 发光性质[J]. 发光学报, 2021,42(11):1756-1762.

Qiu-feng SHI, Lei WANG, Hai-jie GUO, et al. Luminescence Properties of Pr³⁺ Doped in Ba₃La(PO₄)₃ with Vacuum Ultraviolet and X-ray Excitation[J]. Chinese journal of luminescence, 2021, 42(11): 1756-1762.
时秋峰, 王磊, 郭海洁, 等. 真空紫外光及X射线激发下Pr³⁺掺杂Ba₃La(PO₄)₃ 发光性质[J]. 发光学报, 2021,42(11):1756-1762. DOI： 10.37188/CJL.20210281.

Qiu-feng SHI, Lei WANG, Hai-jie GUO, et al. Luminescence Properties of Pr³⁺ Doped in Ba₃La(PO₄)₃ with Vacuum Ultraviolet and X-ray Excitation[J]. Chinese journal of luminescence, 2021, 42(11): 1756-1762. DOI： 10.37188/CJL.20210281.

摘要

4f5d具有大的辐射跃迁速率，是高效快响应闪烁体材料较有前景的发光中心离子。本文采用高温固相法制备了Pr

掺杂Ba

La(PO

)

(BLP)光转换材料，对其物相、真空紫外发光性质、X射线激发发光性质、发光衰减特性和发光热稳定性进行了表征。结果表明，BLP∶Pr

具有高效的Pr

4f5d宽带发光，发光寿命为~15 ns，且具有较好的发光热稳定性。在基质172 nm激发下，存在基质到Pr

4f5d的能量传递，而在X射线激发下可能受表面缺陷影响未发现明显的Pr

4f5d发光。本文研究结果表明，BLP∶Pr

在作为真空紫外到UV-C光转换材料方面具有潜在的应用价值。本研究对于设计新型快响应闪烁体具有一定的指导意义。

Abstract

The radiative transition rate of Pr

4f5d is large

which makes it as a promising luminescence center of fast scintillators. Samples of Ba

La(PO

)

(BLP) activated with Pr

were prepared through high temperature solid state method and characterized by XRD

temperature-dependent luminescence spectra upon VUV-UV and X-ray excitations and decay curves. Efficient and thermal stable Pr

4f5d broad band emission with decay time of ~15 ns was observed. There is energy transfer from host to Pr

4f5d upon excitation at 172 nm

however

the energy transfer is absent upon X-ray excitation which is attributed to influence of defects on surface. The results indicate that BLP∶Pr

could be applied as an efficient VUV to UV-C converting material. In addition

the research is also important for designing novel fast scintillators.

关键词

Keywords

references

NIKL M , YOSHIKAWA A . Recent R&D trends in inorganic single-crystal scintillator materials for radiation detection [J]. Adv. Opt. Mater. , 2015 , 3 ( 4 ): 463 - 481 .

RONDA C , WIECZOREK H , KHANIN V , et al . Review—scintillators for medical imaging:a tutorial overview [J]. ECS J. Solid State Sci. Technol. , 2016 , 5 ( 1 ): R3121 - R3125 .

DUJARDIN C , AUFFRAY E , BOURRET-COURCHESNE E , et al . Needs, trends, and advances in inorganic scintillators [J]. IEEE Trans. Nucl. Sci. , 2018 , 65 ( 8 ): 1977 - 1997 .

CHEN Q S , WU J , OU X Y , et al . All-inorganic perovskite nanocrystal scintillators [J]. Nature , 2018 , 561 ( 7721 ): 88 - 93 .

IVANOVSKIKH K V , SHI Q F , BETTINELLI M , et al . Unraveling Pr3+ 5d-4f emission in LiLa9(SiO4)6O2 crystals doped with Pr3+ ions [J]. Opt. Mater. , 2018 , 79 : 108 - 114 .

ZHU W J , MA W B , SU Y R , et al . Low-dose real-time X-ray imaging with nontoxic double perovskite scintillators [J]. Light Sci. Appl. , 2020 , 9 ( 1 ): 112-1-10 .

FOSTER C , WU Y T , STAND L , et al . Czochralski growth and scintillation properties of Li+, Na+, and K+ codoped(Lu0.75, Y0.25)3Al5O12∶Pr3+ single crystals [J]. J. Cryst. Growth , 2020 , 532 : 125408-1-7 .

SCHRÖDER F , FISCHER S , JÜSTEL T . X-ray and VUV excitation studies on Pr3+ activated Li2CaSiO4 [J]. J. Lumin. , 2021 , 235 : 118046-1-9 .

CASTAING V , ARROYO E , BECERRO A I , et al . Persistent luminescent nanoparticles:challenges and opportunities for a shimmering future [J]. J. Appl. Phys. , 2021 , 130 ( 8 ): 080902-1-16 .

ZYCH A , DE LANGE M , DE MELLO DONEGÁ C , et al . Analysis of the radiative lifetime of Pr3+ d-f emission [J]. J. Appl. Phys. , 2012 , 112 ( 1 ): 013536-1-12 .

WU Y T , REN G H . Effects of Gd/Lu ratio on the luminescent properties of Pr3+ activated (Gd, Lu)3Ga3Al2O12 [J]. ECS J. Solid State Sci. Technol. , 2013 , 2 ( 3 ): R49 - R55 .

SREEBUNPENG K , CHEWPRADITKUL W , BABIN V , et al . Scintillation response of Y3Al5O12∶Pr3+ single crystal scintillators [J]. Radiat. Meas. , 2013 , 56 : 94 - 97 .

DROZDOWSKI W , BRYLEW K , WOJTOWICZ A J , et al . 33 000 photons per MeV from mixed (Lu0.75Y0.25)3Al5O12∶Pr scintillator crystals [J]. Opt. Mater. Express , 2014 , 4 ( 6 ): 1207 - 1212 .

SREEBUNPENG K , CHEWPRADITKUL W , NIKL M . Intrinsic light yield and light loss coefficient of LuAG∶Pr under excitation with α-and γ-rays [J]. Key Eng. Mater. , 2016 , 675-676 : 768 - 771 .

NARGELAS S , DOSOVITSKIY G , KORZHIK M , et al . Role of inter- and intraconfigurational transitions of Pr3+ ion in nonequilibrium carrier relaxation in garnet-type scintillators [J]. Opt. Mater. , 2021 , 111 : 110676-1-6 .

武彤 , 王玲 , 贺欢 , 等 . Lu3Al5O12基闪烁陶瓷研究进展 [J]. 发光学报 , 2021 , 42 ( 7 ): 917 - 937 .

WU T , WANG L , HE H , et al . Research progress of Lu3Al5O12-based scintillation ceramics [J]. Chin. J. Lumin. , 2021 , 42 ( 7 ): 917 - 937 . (in Chinese)

NIKL M , PEJCHAL J , MIHOKOVA E , et al . Antisite defect-free Lu3(GaxAl1-x)5O12∶Pr scintillator [J]. Appl. Phys. Lett. , 2006 , 88 ( 14 ): 141916-1-3 .

康茹 , 张绍安 , 练惠旺 , 等 . 长余辉纳米诊疗剂的设计策略与应用研究进展 [J]. 发光学报 , 2020 , 41 ( 12 ): 1614 - 1626 .

KANG R , ZHANG S A , LIAN H W , et al . Research progress on design strategy and application of persistent luminescence nanotheranostics [J]. Chin. J. Lumin. , 2020 , 41 ( 12 ): 1614 - 1626 . (in Chinese)

YANG Y M , LI Z Y , ZHANG J Y , et al . X-ray-activated long persistent phosphors featuring strong UVC afterglow emissions [J]. Light Sci. Appl. , 2018 , 7 ( 1 ): 88-1-11 .

PUSTOVAROV V A , IVANOVSKIKH K V , KISELEV S A , et al . Testing performance of Pr3+-doped KLuP2O7 upon UV-, synchrotron X-ray and cathode-ray excitation [J]. Opt. Mater. , 2020 , 108 : 110234-1-8 .

KEIL J N , JENNEBOER H , JÜSTEL T . Temperature dependent luminescence of Pr3+ doped NaCaPO4 [J]. J. Lumin. , 2021 , 238 : 118307-1-7 .

ZHOU W J , GU M , OU Y Y , et al . Concentration-driven selectivity of energy transfer channels and color tunability in Ba3La(PO4)3∶Tb3+, Sm3+ for warm white LEDs [J]. Inorg. Chem. , 2017 , 56 ( 13 ): 7433 - 7442 .

YU R J , MI NOH H , MOON B K , et al . Synthesis and luminescence properties of a novel red-emitting phosphor Ba3La-(PO4)3∶Eu3+ for solid-state lighting [J]. J. Alloys Compd. , 2013 , 576 : 236 - 241 .

HOU D J , LIANG H B , XIE M B , et al . Bright green-emitting, energy transfer and quantum cutting of Ba3Ln(PO4)3∶Tb3+(Ln=La, Gd) under VUV-UV excitation [J]. Opt. Express , 2011 , 19 ( 12 ): 11071 - 11083 .

ZHANG C H , LIANG H B , ZHANG S , et al . Efficient sensitization of Eu3+ emission by Tb3+ in Ba3La(PO4)3 under VUV-UV excitation:energy transfer and tunable emission [J]. J. Phys. Chem. C , 2012 , 116 ( 30 ): 15932 - 15937 .

SHI Q F , HUANG Y , IVANOVSKIKH K V , et al . Luminescence properties and host sensitization study of Ba3La(PO4)3∶Ce3+ with (V)UV and X-ray excitation [J]. J. Alloys Compd. , 2020 , 817 : 152704-1-7 .

LIU W G , ZHU Q , WANG X J , et al . Multi-color luminescence and thermal stability of eulytite-type Ba3La(PO4)3∶Ce3+, Mn2+ phosphors via gel-combustion [J]. J. Alloys Compd. , 2019 , 787 : 495 - 502 .

BARBIER J . Structural refinements of eulytite-type Ca3Bi(PO4)3 and Ba3La(PO4)3 [J]. J. Solid State Chem. , 1992 , 101 ( 2 ): 249 - 256 .

SHANNON R D . Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides [J]. Acta Crystallogr. A , 1976 , 32 ( 5 ): 751 - 767 .

FEOFILOV S P , ZHOU Y , SEO H J , et al . Host sensitization of Gd3+ ions in yttrium and scandium borates and phosphates:application to quantum cutting [J]. Phys. Rev. B , 2006 , 74 ( 8 ): 085101-1-9 .

CARRASCO I , BARTOSIEWICZ K , PICCINELLI F , et al . Structural effects and 5d→4f emission transition shifts induced by Y co-doping in Pr-doped K3Lu1-xYx(PO4)2 [J]. J. Lumin. , 2017 , 189 : 113 - 119 .

浏览量

289

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

Sr₃AlO₄F∶Eu³⁺，Dy³⁺，Na⁺发光材料性能

Eu³⁺、Sm³⁺共掺双钙钛矿Gd₂ZnTiO₆荧光粉的发光性能及其热稳定性

三联吡啶苯桥连β-二酮配体调控3d-4f能量传递及单分子白光研究

夜视成像用Cs₂NaYCl₆∶Sb, Ln荧光粉宽带近红外发光性能