基于热活化延迟荧光双发射的有机电子给体-受体型材料研究进展

曹云锋; 李旭萍; 卢建军

doi:10.37188/CJL.20210181

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基于热活化延迟荧光双发射的有机电子给体-受体型材料研究进展

材料合成及性能 | 更新时间：2021-09-13

- 基于热活化延迟荧光双发射的有机电子给体-受体型材料研究进展
  增强出版
- Research Progress of Thermally Activated Delayed Fluorescence Materials with Dual-emission Based on Donor-acceptor System
- 发光学报 2021年42卷第9期页码：1386-1395
- 作者机构：
  
  太原理工大学　省部共建煤基能源清洁高效利用国家重点实验室，山西　太原　 030024
- 作者简介：
  
  [ "曹云锋(1996-)，男，河北邯郸人，硕士研究生，2018年于河北科技师范学院获得学士学位，主要从事有机/高分子光功能材料的研究。 E-mail: CYF510776@163.com" ]
  [ "卢建军(1970-)，男，山西太原人，博士，教授，2004年于太原理工大学获得博士学位，主要从事功能高分子材料、有机/高分子光功能材料、高性能纤维、产业用纺织品等方面的应用和研究。 E-mail: lujianjunktz@tyut.edu.cn" ]
- 基金信息：
  
  山西省科技厅重大专项计划项目(MJH2016-04)
- DOI：10.37188/CJL.20210181
  中图分类号： O482.31
- 纸质出版日期：2021-09-01，
  
  收稿日期：2021-05-08，
  
  修回日期：2021-06-06，
- 稿件说明：
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曹云锋, 李旭萍, 卢建军. 基于热活化延迟荧光双发射的有机电子给体-受体型材料研究进展[J]. 发光学报, 2021,42(9):1386-1395.

YUN-FENG CAO, XU-PING LI, JIAN-JUN LU. Research Progress of Thermally Activated Delayed Fluorescence Materials with Dual-emission Based on Donor-acceptor System. [J]. Chinese journal of luminescence, 2021, 42(9): 1386-1395.
曹云锋, 李旭萍, 卢建军. 基于热活化延迟荧光双发射的有机电子给体-受体型材料研究进展[J]. 发光学报, 2021,42(9):1386-1395. DOI： 10.37188/CJL.20210181.

YUN-FENG CAO, XU-PING LI, JIAN-JUN LU. Research Progress of Thermally Activated Delayed Fluorescence Materials with Dual-emission Based on Donor-acceptor System. [J]. Chinese journal of luminescence, 2021, 42(9): 1386-1395. DOI： 10.37188/CJL.20210181.

摘要

基于热活化延迟荧光的双发射有机材料，由于具有两种颜色的发光波长，且至少有一种发射的衰减寿命在微秒级以上，因此在白色有机发光二极管、多功能探针与传感、高质量生物成像、防伪等领域具有很大的应用前景。为了合理地设计基于热活化延迟荧光的双发射有机电子给体-受体型材料，最为关键的是研究分子结构与光物理性质之间的构效关系。本文将基于热活化延迟荧光的双发射有机电子给体-受体型分子，根据其发光属性分为三类:热活化延迟荧光-荧光双发射、热活化延迟荧光-磷光双发射和双热活化延迟荧光发射，进一步对其分子设计原则、发光机制和最新进展做出了简要综述，并展望了其发展前景。

Abstract

The organic thermally activated delayed fluorescence materials with dual-emission characteristics have possessed great application in fields of white organic light emitting diodes

multifunction probes and sensors

high quality bioimagings

anti-counterfeiting and so on

owing to their different wavelengths and at least one long lifetime more than microseconds. Moreover

it is critical to study the structure-property relationships for designing thermally activated delayed fluorescence moleculars with dual-emission based on donor-acceptor system. In this paper

the thermally activated delayed fluorescence materials with dual-emission based on donor-acceptor system are divided into three categories according to their luminescent properties: thermally activated delayed fluorescence-fluorescence dual emission

thermally activated delayed fluorescence-phosphorescent dual emission and dual thermally activated delayed fluorescence emission. The molecular design principle

luminescence mechanism and the progress are reviewed

noting the remaining challenges and directions for future work.

关键词

热活化延迟荧光双发射分子设计发光机制

Keywords

thermally activated delayed fluorescencedual emissionmolecular designluminescence mechanism

references

ZHU L L, QU D H, ZHANG D, et al. Dual-mode tunable viscosity sensitivity of a rotor-based fluorescent dye [J].Tetrahedron, 2010, 66(6):1254-1260.

ZHOU C K, TIAN Y, YUAN Z, et al. Precise design of phosphorescent molecular butterflies with tunable photoinduced structural change and dual emission [J].Angew. Chem. Int. Ed., 2015, 54(33):9591-9595.

UOYAMA H, GOUSHI K, SHIZU K, et al. Highly efficient organic light-emitting diodes from delayed fluorescence [J].Nature, 2012, 492(7428):234-238.

LIU X, WANG Y F, LI M, et al. Aromatic-imide-based TADF material as emitter for efficient yellow and white organic light-emitting diodes [J].Org. Electron., 2021, 88:106017-1-9.

刘婷婷, 李淑红, 王文军, 等. 基于器件结构提高TADF-OLED器件的发光性能[J].发光学报, 2020, 41(1):77-85.

LIU T T, LI S H, WANG W J, et al. Enhanced luminescent properties of TADF-OLEDs based on device structure [J].Chin. J. Lumin., 2020, 41(1):77-85. (in Chinese)

LI X P, BARYSHNIKOV G, DENG C, et al. A three-dimensional ratiometric sensing strategy on unimolecular fluorescence-thermally activated delayed fluorescence dual emission [J].Nat. Commun., 2019, 10(1):731-1-9.

LI X P, BARYSHNIKOV G, DING L J, et al. Dual-phase thermally activated delayed fluorescence luminogens:a material for time-resolved imaging independent of probe pretreatment and probe concentration [J].Angew. Chem. Int. Ed., 2020, 59(19):7548-7554.

季宇彬, 张娜, 王亚丽, 等. 热激活延迟荧光分子探针在生物成像中的研究进展[J].中国医药生物技术, 2018, 13(6):532-538.

JI Y B, ZHANG N, WANG Y L, et al. Research progress of thermal activation delayed fluorescence probes for biological imaging [J].Chin. Med. Biotechnol., 2018, 13(6):532-538. (in Chinese)

LI M, WANG Y F, ZHANG D W, et al. Thermally activated delayed fluorescence material-sensitized helicene enantiomer-based OLEDs:a new strategy for improving the efficiency of circularly polarized electroluminescence [J].Sci. China Mater., 2021, 64(4):899-908.

LU J Z, PATTENGALE B, LIU Q H, et al. Donor-acceptor fluorophores for energy-transfer-mediated photocatalysis [J].J. Am Chem. Soc., 2018, 140(42):13719-13725.

PARKER C A, HATCHARD C G. Triplet-singlet emission in fluid solutions. Phosphorescence of eosin [J].Trans. Faraday Soc., 1961, 57:1894-1904.

ENDO A, SATO K, YOSHIMURA K, et al. Efficient up-conversion of triplet excitons into a singlet state and its application for organic light emitting diodes [J].Appl. Phys. Lett., 2011, 98(8):083302-1-3.

YAO L, YANG B, MA Y G. Progress in next-generation organic electroluminescent materials:material design beyond exciton statistics [J].Sci. China Chem., 2014, 57(3):335-345.

马志华, 马荣荣, 董文月, 等. 树枝状热活化延迟荧光材料研究进展[J].发光学报, 2021, doi: 10.37188/CJL.20210099http://doi.org/10.37188/CJL.20210099.

MA Z H, MA R R, DONG W Y, et al. Recent advances on thermally activated delayed fluorescence dendrimers [J].Chin. J. Lumin., 2021, doi: 10.37188/CJL.20210099http://doi.org/10.37188/CJL.20210099. (in Chinese)

周涛, 钱越, 王宏健, 等. 热活化延迟荧光蓝光小分子取代基效应的研究进展[J].化学学报, 2021, 79(5):557-574.

ZHOU T, QIAN Y, WANG H J, et al. Recent advances in substituent effects of blue thermally activated delayed fluorescence small molecules [J].Acta Chim. Sinica, 2021, 79(5):557-574. (in Chinese)

KASHA M. Characterization of electronic transitions in complex molecules [J].Discuss. Faraday Soc., 1950, 9:14-19.

TANAKA H, SHIZU K, NAKANOTANI H, et al. Dual intramolecular charge-transfer fluorescence derived from a phenothiazine-triphenyltriazine derivative [J].J. Phys. Chem. C, 2014, 118(29):15985-15994.

MARGHAD I, KIM D H, TIAN X H, et al. Synthesis by a cost-effective method and electroluminescence of a novel efficient yellowish-green thermally activated delayed fluorescent molecule [J].ACS Omega, 2018, 3(2):2254-2260.

WANG K, ZHENG C J, LIU W, et al. Avoiding energy loss on TADF emitters:controlling the dual conformations of D-A structure molecules based on the pseudoplanar segments [J].Adv. Mater., 2017, 29(47):1701476-1-9.

WANG K, SHI Y Z, ZHENG C J, et al. Control of dual conformations:developing thermally activated delayed fluorescence emitters for highly efficient single-emitter white organic light-emitting diodes [J].ACS Appl. Mater. Interfaces, 2018, 10(37):31515-31525.

LIN J A, LI S W, LIU Z Y, et al. Bending-type electron donor-donor-acceptor triad:dual excited-state charge-transfer coupled structural relaxation [J].Chem. Mater., 2019, 31(15):5981-5992.

LI C S, NOBUYASU R S, WANG Y K, et al. Solution-processable thermally activated delayed fluorescence white OLEDs based on dual-emission polymers with tunable emission colors and aggregation-enhanced emission properties [J].Adv. Opt. Mater., 2017, 5(20):1700435.

LIU Y C, XIE G H, REN Z J, et al. Thermally activated delayed fluorescence polymer emitters with tunable emission from yellow to warm white regulated by triphenylamine derivatives [J].ACS Appl. Polym. Mater., 2019, 1(8):2204-2212.

HUANG R J, KUKHTA N A, WARD J S, et al. Balancing charge-transfer strength and triplet states for deep-blue thermally activated delayed fluorescence with an unconventional electron rich dibenzothiophene acceptor [J].J. Mater. Chem. C, 2019, 7(42):13224-13234.

DE SA DANIEL PEREIRA D, LEE D R, KUKHTA N A, et al. The effect of a heavy atom on the radiative pathways of an emitter with dual conformation, thermally-activated delayed fluorescence and room temperature phosphorescence [J].J. Mater. Chem. C, 2019, 7(34):10481-10490.

LI W L, HUANG Q Y, MAO Z, et al. Selective expression of chromophores in a single molecule:soft organic crystals exhibiting full-colour tunability and dynamic triplet-exciton behaviours [J].Angew. Chem. Int. Ed., 2020, 59(9):3739-3745.

HUANG R J, AVÓ J, NORTHEY T, et al. The contributions of molecular vibrations and higher triplet levels to the intersystem crossing mechanism in metal-free organic emitters [J].J. Mater. Chem. C, 2017, 5(25):6269-6280.

BHATTACHARJEE I, ACHARYA N, BHATIA H, et al. Dual emission through thermally activated delayed fluorescence and room-temperature phosphorescence, and their thermal enhancement via solid-state structural change in a carbazole-quinoline conjugate [J].J. Phys. Chem. Lett., 2018, 9(11):2733-2738.

ZHANG L, LI M, HU T P, et al. Phthalimide-based “D-N-A” emitters with thermally activated delayed fluorescence and isomer-dependent room-temperature phosphorescence properties [J].Chem. Commun., 2019, 55(81):12172-12175.

PASHAZADEH R, PANDER P, BUCINSKAS A, et al. An iminodibenzyl-quinoxaline-iminodibenzyl scaffold as a mechanochromic and dual emitter:donor and bridge effects on optical properties [J].Chem. Commun., 2018, 54(98):13857-13860.

SUN C, RAN X Q, WANG X, et al. Twisted molecular structure on tuning ultralong organic phosphorescence [J].J. Phys. Chem. Lett., 2018, 9(2):335-339.

THOMAS S W, JOLY G D, SWAGER T M. Chemical sensors based on amplifying fluorescent conjugated polymers [J].Chem. Rev., 2007, 107(4):1339-1386.

XU S D, LIU T T, MU Y X, et al. An organic molecule with asymmetric structure exhibiting aggregation-induced emission, delayed fluorescence, and mechanoluminescence [J].Angew. Chem. Int. Ed., 2015, 54(3):874-878.

XIE Z L, CHEN C J, XU S D, et al. White-light emission strategy of a single organic compound with aggregation-induced emission and delayed fluorescence properties [J].Angew. Chem. Int. Ed., 2015, 54(24):7181-7184.

XU B J, MU Y X, MAO Z, et al. Achieving remarkable mechanochromism and white-light emission with thermally activated delayed fluorescence through the molecular heredity principle [J].Chem. Sci., 2016, 7(3):2201-2206.

LUO M K, LI X P, DING L J, et al. Integrating time-resolved imaging information by single-luminophore dual thermally activated delayed fluorescence [J].Angew. Chem. Int. Ed., 2020, 59(39):17018-17025.

TAN J H, CHEN W C, NI S F, et al. Aggregation-state engineering and emission switching in D-A-D' AIEgens featuring dual emission, MCL and white electroluminescence [J].J. Mater. Chem. C, 2020, 8(24):8061-8068.

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