基于热活化延迟荧光双发射的有机电子给体-受体型材料研究进展

曹云锋; 李旭萍; 卢建军

doi:10.37188/CJL.20210181

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基于热活化延迟荧光双发射的有机电子给体-受体型材料研究进展

材料合成及性能 | 更新时间：2021-09-13

- 基于热活化延迟荧光双发射的有机电子给体-受体型材料研究进展
  增强出版
- Research Progress of Thermally Activated Delayed Fluorescence Materials with Dual-emission Based on Donor-acceptor System
- 发光学报 2021年42卷第9期页码：1386-1395
- 作者机构：
  
  太原理工大学　省部共建煤基能源清洁高效利用国家重点实验室，山西　太原　 030024
- 作者简介：
  
  [ "曹云锋(1996-)，男，河北邯郸人，硕士研究生，2018年于河北科技师范学院获得学士学位，主要从事有机/高分子光功能材料的研究。 E-mail: CYF510776@163.com" ]
  [ "卢建军(1970-)，男，山西太原人，博士，教授，2004年于太原理工大学获得博士学位，主要从事功能高分子材料、有机/高分子光功能材料、高性能纤维、产业用纺织品等方面的应用和研究。 E-mail: lujianjunktz@tyut.edu.cn" ]
- 基金信息：
  
  山西省科技厅重大专项计划项目(MJH2016-04)
- DOI：10.37188/CJL.20210181
  中图分类号： O482.31
- 纸质出版日期：2021-09-01，
  
  收稿日期：2021-05-08，
  
  修回日期：2021-06-06，
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曹云锋, 李旭萍, 卢建军. 基于热活化延迟荧光双发射的有机电子给体-受体型材料研究进展[J]. 发光学报, 2021,42(9):1386-1395.

Yun-feng CAO, Xu-ping LI, Jian-jun LU. Research Progress of Thermally Activated Delayed Fluorescence Materials with Dual-emission Based on Donor-acceptor System[J]. Chinese Journal of Luminescence, 2021,42(9):1386-1395.
曹云锋, 李旭萍, 卢建军. 基于热活化延迟荧光双发射的有机电子给体-受体型材料研究进展[J]. 发光学报, 2021,42(9):1386-1395. DOI： 10.37188/CJL.20210181.

Yun-feng CAO, Xu-ping LI, Jian-jun LU. Research Progress of Thermally Activated Delayed Fluorescence Materials with Dual-emission Based on Donor-acceptor System[J]. Chinese Journal of Luminescence, 2021,42(9):1386-1395. DOI： 10.37188/CJL.20210181.

摘要

基于热活化延迟荧光的双发射有机材料，由于具有两种颜色的发光波长，且至少有一种发射的衰减寿命在微秒级以上，因此在白色有机发光二极管、多功能探针与传感、高质量生物成像、防伪等领域具有很大的应用前景。为了合理地设计基于热活化延迟荧光的双发射有机电子给体-受体型材料，最为关键的是研究分子结构与光物理性质之间的构效关系。本文将基于热活化延迟荧光的双发射有机电子给体-受体型分子，根据其发光属性分为三类:热活化延迟荧光-荧光双发射、热活化延迟荧光-磷光双发射和双热活化延迟荧光发射，进一步对其分子设计原则、发光机制和最新进展做出了简要综述，并展望了其发展前景。

Abstract

The organic thermally activated delayed fluorescence materials with dual-emission characteristics have possessed great application in fields of white organic light emitting diodes

multifunction probes and sensors

high quality bioimagings

anti-counterfeiting and so on

owing to their different wavelengths and at least one long lifetime more than microseconds. Moreover

it is critical to study the structure-property relationships for designing thermally activated delayed fluorescence moleculars with dual-emission based on donor-acceptor system. In this paper

the thermally activated delayed fluorescence materials with dual-emission based on donor-acceptor system are divided into three categories according to their luminescent properties: thermally activated delayed fluorescence-fluorescence dual emission

thermally activated delayed fluorescence-phosphorescent dual emission and dual thermally activated delayed fluorescence emission. The molecular design principle

luminescence mechanism and the progress are reviewed

noting the remaining challenges and directions for future work.

关键词

热活化延迟荧光双发射分子设计发光机制

Keywords

thermally activated delayed fluorescencedual emissionmolecular designluminescence mechanism

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