K2SiF6∶Mn4+荧光玻璃陶瓷及其在激光照明中的应用

司帅晨; 黄霖; 王静

doi:10.37188/CJL.20210176

您当前的位置：

首页 >

文章列表页 >

K₂SiF₆∶Mn⁴⁺荧光玻璃陶瓷及其在激光照明中的应用

特邀报告 | 更新时间：2021-10-17

- K₂SiF₆∶Mn⁴⁺荧光玻璃陶瓷及其在激光照明中的应用
  增强出版
- K₂SiF₆∶Mn⁴⁺ Luminescent Glass Ceramics Applicable to Laser Lighting
- 发光学报 2021年42卷第10期页码：1549-1558
- 作者机构：
  
  1.中山大学化学学院　生物无机与合成化学教育部重点实验室，光电材料与技术国家重点实验室，广东　广州　 510275
  2.中山大学　材料科学与工程学院，广东　广州　 510275
- 作者简介：
  
  [ "司帅晨(1996-)，男，山西晋城人，博士研究生，2017年于中山大学获得学士学位，主要从事荧光玻璃陶瓷的研究。E-mail: sishch@mail2.sysu.edu.cn" ]
  [ "王静(1976-)，男，陕西安康人，博士，教授，博士研究生导师，2004年于中国科学院长春应用化学研究所获得博士学位，主要从事固体无机材料、稀土光谱学、照明、显示与新能源发光材料的基础与应用的研究。E-mail: ceswj@mail.sysu.edu.cn" ]
- 基金信息：
  
  国家自然科学基金和云南省自然科学基金(U1902222);国家自然科学基金(51772336;51702373;51961145101);广东省重点研发计划(2019B010926001);广州市科技计划(202007020005;201807010104;201802020033);广东省自然科学基金(2018A030313919)
- DOI：10.37188/CJL.20210176
  中图分类号： O482.31
- 收稿日期：2021-05-05，
  
  修回日期：2021-05-23，
  
  纸质出版日期：2021-10-01
- 稿件说明：
移动端阅览
司帅晨, 黄霖, 王静. K₂SiF₆∶Mn⁴⁺荧光玻璃陶瓷及其在激光照明中的应用[J]. 发光学报, 2021,42(10):1549-1558.

Shuai-chen SI, Lin HUANG, Jing WANG. K₂SiF₆∶Mn⁴⁺ Luminescent Glass Ceramics Applicable to Laser Lighting[J]. Chinese journal of luminescence, 2021, 42(10): 1549-1558.
司帅晨, 黄霖, 王静. K₂SiF₆∶Mn⁴⁺荧光玻璃陶瓷及其在激光照明中的应用[J]. 发光学报, 2021,42(10):1549-1558. DOI： 10.37188/CJL.20210176.

Shuai-chen SI, Lin HUANG, Jing WANG. K₂SiF₆∶Mn⁴⁺ Luminescent Glass Ceramics Applicable to Laser Lighting[J]. Chinese journal of luminescence, 2021, 42(10): 1549-1558. DOI： 10.37188/CJL.20210176.

摘要

面对市场对高功率高质量照明的强烈需求，开发兼具优良发光性能和稳定性的红色荧光玻璃陶瓷来提高白光显色指数(CRI)显得尤为重要。本文采用低温共烧结法制备了一种镶嵌K

SiF

∶Mn

(KSF)商用红色荧光粉的新型荧光玻璃陶瓷。研究结果表明，共烧结时前驱玻璃熔体对KSF荧光粉的热侵蚀作用较小，荧光粉的发光特性基本得到保持；相比于初始荧光粉，玻璃陶瓷的热猝灭性能得到大幅的改善；构建的激光照明光源在55.56 W/cm

蓝光功率密度激发下，光通量为32.77 lm，色温为5073 K

CRI为74.86，色坐标为(0.341

0.321)。经过系统的热管理优化，KSF荧光玻璃陶瓷可望应用于高功率室内照明领域。

Abstract

Towards the strong market demand for high power

high quality lightings

it is particularly important to develop red fluorescent glass ceramic with excellent optical performance and stability to improve the color rendering index(CRI) of white light. In this work

a glass ceramic embedded with commercial K

SiF

∶Mn

(KSF) red phosphor was prepared

via

a low-temperature co-sintering method. The results show that the thermal erosion effect of the precursor glass melt on KSF phosphor is limited during co-sintering

so the optical properties of the phosphor are retained. Compared with the initial phosphor

the thermal quenching properties of glass ceramics are greatly improved. The fabricated laser lighting source exhibits lumen of 32.77 lm

correlated color temperature of 5 073 K

CRI of 74.86

and chromaticity coordinate of (0.341

0.321)

under the excitation of 55.56 W/cm

blue laser diode(LD) power density. After further optimization of systematic thermal management

KSF fluorescent glass ceramic is expected to be applied in the field of high power indoor lighting.

关键词

Keywords

references

XU Y , CHEN L H , LI Y Z , et al . Phosphor-conversion white light using InGaN ultraviolet laser diode [J]. Appl. Phys. Lett. , 2008 , 92 : 021129-1-3 .

JR WIERER J J , TSAO J Y , SIZOV D S . Comparison between blue lasers and light-emitting diodes for future solid-state lighting [J]. Laser Photonics Rev. , 2013 , 7 ( 6 ): 963 - 993 .

CHANDRAJIT B , MERVE M W , BERNHARD R . Lighting with laser diodes [J]. Adv. Opt. Technol. , 2013 , 2 ( 4 ): 313 - 321 .

ZHANG R , LIN H , YU Y L , et al . A new-generation color converter for high-power white LED: transparent Ce3+∶YAG phosphor-in-glass [J]. Laser Photonics Rev. , 2014 , 8 ( 1 ): 158 - 164 .

HUANG L , ZHU Y W , ZHANG X J , et al . HF-free hydrothermal route for synthesis of highly efficient narrow-band red emitting phosphor K2Si1-xF6∶xMn4+ for warm white light-emitting diodes [J]. Chem. Mater. , 2016 , 28 ( 5 ): 1495 - 1502 .

SIJBOM H F , VERSTRAETE R , JOOS J J , et al . K2SiF6∶Mn4+ as a red phosphor for displays and warm-white LEDs: a review of properties and perspectives [J]. Opt. Mater. Express , 2017 , 7 ( 9 ): 3332 - 3365 .

ZHANG X J , YU J B , WANG J , et al . All-inorganic light convertor based on phosphor-in-glass engineering for next-generation modular high-brightness white LEDs/LDs [J]. ACS Photonics , 2017 , 4 ( 4 ): 986 - 995 .

ZHANG X J , SI S C , YU J B , et al . Improving the luminous efficacy and resistance to blue laser irradiation of phosphor-in-glass based solid state laser lighting through employing dual-functional sapphire plate [J]. J. Mater. Chem. C , 2019 , 7 ( 2 ): 354 - 361 .

岳相铭 , 林航 , 林世盛 , 等 . La3Si6N11∶Ce3+荧光玻璃陶瓷及其在高功率固态照明中的应用 [J]. 发光学报 , 2020 , 41 ( 12 ): 1529 - 1537 .

YUE X M , LIN H , LIN S S , et al . La3Si6N11∶Ce3+ luminescent glass ceramics applicable to high-power solid-state lighting [J]. Chin. J. Lumin. , 2020 , 41 ( 12 ): 1529 - 1537 . (in Chinese)

ARJOCA S , VÍLLORA E G , INOMATA D , et al . Temperature dependence of Ce∶YAG single-crystal phosphors for high-brightness white LEDs/LDs [J]. Mater. Res. Express , 2015 , 2 ( 5 ): 055503-1-9 .

YAO Q , HU P , SUN P , et al . YAG∶Ce3+ transparent ceramic phosphors brighten the next-generation laser-driven lighting [J]. Adv. Mater. , 2020 , 32 ( 19 ): 1907888 .

胡桃 , 林航 , 高妍 , 等 . 用于高功率白光发光二极管的YAGG∶Ce3+/MMG∶Mn4+荧光玻璃陶瓷的结构与性能 [J]. 硅酸盐学报 , 2018 , 46 ( 11 ): 1551 - 1557 .

HU T , LIN H , GAO Y , et al . Microstructure and luminescent properties of YAGG∶Ce3+/MMG∶Mn4+ embedded glass ceramics for high-power white light emitting diode application [J]. J. Chin. Ceram. Soc. , 2018 , 46 ( 11 ): 1551 - 1557 . (in Chinese)

ZHOU J B , WANG Y F , CHEN Y Y , et al . Single-crystal red phosphors and their core-shell structure for improved water-resistance for laser diodes applications [J]. Angew. Chem. Int. Ed. , 2021 , 60 ( 8 ): 3940 - 3945 .

ZHOU Y Y , YU C K , SONG E H , et al . Three birds with one stone: K2SiF6∶Mn4+ single crystal phosphors for high-power and laser-driven lighting [J]. Adv. Opt. Mater. , 2020 , 8 ( 23 ): 2000976-1-9 .

OSBORNE R A , CHEREPY N J , SEELEY Z M , et al . New red phosphor ceramic K2SiF6∶Mn4+ [J]. Opt. Mater. , 2020 , 107 : 110140 .

YORK-WINEGAR J , HARPER T , BRENNAN C , et al . Structure of SnF2-SnO-P2O5 glasses [J]. Phys. Procedia , 2013 , 44 : 159 - 165 .

LIU H C , MA J H , GONG J H , et al . The structure and properties of SnF2-SnO-P2O5 glasses [J]. J. Non-Cryst. Solids , 2015 , 419 : 92 - 96 .

浏览量

949

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

激光照明应用MgO-La₃Si₆N₁₁∶Ce³⁺复合荧光玻璃的制备及性能优化

面向荧光材料研究的光度学基础

面向器件化的激光照明用荧光材料设计

光斑调控对激光荧光材料性能评价的影响