抗聚集诱导荧光猝灭的固态发光碳纳米点：制备、光物理性质及应用

曲彦霏; 李迪; 曲松楠

doi:10.37188/CJL.20210174

您当前的位置：

首页 >

文章列表页 >

抗聚集诱导荧光猝灭的固态发光碳纳米点：制备、光物理性质及应用

特邀报告 | 更新时间：2021-09-03

- 抗聚集诱导荧光猝灭的固态发光碳纳米点：制备、光物理性质及应用
  增强出版
- Solid-state Luminescent Carbon Dots Resistant to Aggregation-induced Fluorescence Quenching: Preparation, Photophysical Properties and Applications
- 发光学报 2021年42卷第8期页码：1141-1154
- 作者机构：
  
  1.中国科学院长春光学精密机械与物理研究所　发光学及应用国家重点实验室，吉林　长春　 130033
  2.中国科学院大学，北京　 100049
  3.吉林大学材料学与工程学院　汽车材料教育部重点实验室，吉林　长春　 130012
  4.澳门大学应用物理与材料研究所　教育部联合重点实验室，中国　澳门　 999078
- 作者简介：
  
  [ "曲彦霏(1996-)，男，吉林白山人，硕士研究生，2018年于吉林大学获得学士学位，主要从事固态发光碳纳米点材料及应用方面的研究。E-mail: 846523613@qq.com" ]
  [ "李迪(1984-)，女，辽宁营口人，博士，副教授，2012年于吉林大学获得博士学位，主要从事碳纳米点发光特性及应用方面的研究。E-mail:dili@jlu.edu.cn" ]
  [ "曲松楠(1981-)，男，吉林长春人，博士，教授，博士研究生导师，2009年于吉林大学获得博士学位，主要从事碳基发光材料及应用方面的研究。E-mail: artqusongnan@163.com" ]
- 基金信息：
  
  优秀青年科学基金项目（港澳）(61922091);国家自然科学基金(61975200);吉林省科技发展计划(20170101191JC;20180101190JC;20170101042JC);澳门大学资助项目(SRG2019-00163-IAPME);吉林大学中央高校基本科研业务费资助项目
- DOI：10.37188/CJL.20210174
  中图分类号： O482.31
- 纸质出版日期：2021-08-01，
  
  收稿日期：2021-05-04，
  
  修回日期：2021-05-18，
- 稿件说明：
移动端阅览
曲彦霏, 李迪, 曲松楠. 抗聚集诱导荧光猝灭的固态发光碳纳米点：制备、光物理性质及应用[J]. 发光学报, 2021,42(8):1141-1154.

YAN-FEI QU, DI LI, SONG-NAN QU. Solid-state Luminescent Carbon Dots Resistant to Aggregation-induced Fluorescence Quenching: Preparation, Photophysical Properties and Applications. [J]. Chinese journal of luminescence, 2021, 42(8): 1141-1154.
曲彦霏, 李迪, 曲松楠. 抗聚集诱导荧光猝灭的固态发光碳纳米点：制备、光物理性质及应用[J]. 发光学报, 2021,42(8):1141-1154. DOI： 10.37188/CJL.20210174.

YAN-FEI QU, DI LI, SONG-NAN QU. Solid-state Luminescent Carbon Dots Resistant to Aggregation-induced Fluorescence Quenching: Preparation, Photophysical Properties and Applications. [J]. Chinese journal of luminescence, 2021, 42(8): 1141-1154. DOI： 10.37188/CJL.20210174.

摘要

碳点由于其低毒性、易制备、良好的光稳定性及可调的发光等特性有望成为一类理想的新型固态发光材料。然而，由于聚集诱导荧光猝灭(ACQ)效应的存在，使得碳点在固态发光领域的发展受到了限制，因此制备具有抗ACQ效应的固态发光碳点是碳点研究领域的一个重要方向。本文根据固态发光碳点研究的最新进展，从碳核、表面态调控、超分子及聚合物交联增强发光方面分类总结了具有抗ACQ效应固态发光碳点的制备方法及光物理性质，探讨了其实现固态发光的物理机制。此外，还介绍了该类碳点在固态发光领域的应用进展，并对固态发光碳点的发展现状和所面临的问题进行了讨论。

Abstract

Because of their low toxicity

easy preparation

good photostability and color-tunable photoluminescence

carbon dots are expected to be a new kind of ideal solid-state photoluminescent materials. However

due to the aggregation-induced fluorescence quenching(ACQ) effect

the development of carbon dots in the field of solid-state photoluminescence is limited. Preparing solid-state emissive carbon dots featuring anti-ACQ ability is an important topic in the field of carbon dot research. On basis of the latest progress in the study of solid-state emissive carbon dots

this review summarizes the synthesis and photophysical properties of these carbon dots with anti-ACQ ability in terms of core/surface state controlling and supramolecular/polymer crosslink-enhanced emission

and discusses the physical mechanisms for the occurrence of the solid-state emission. Moreover

the application progress of these carbon dots in the field of solid-state photoluminescence is introduced

and the current situation and problems they faced are discussed.

关键词

碳点聚集诱导荧光猝灭固态发光发光二极管

Keywords

carbon dotsaggregation-induced fluorescence quenchingsolid-state luminescencelight emitting diode

references

XU X Y, RAY R, GU Y L, et al. Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments [J].J. Am. Chem. Soc., 2015, 126(40): 12736-12737.

LIU Y, XIAO N, GONG N Q, et al. One-step microwave-assisted polyol synthesis of green luminescent carbon dots as optical nanoprobes [J].Carbon, 2014, 68: 258-264.

BA X X, ZHANG L, YIN Y L, et al. Luminescent carbon dots with concentration-dependent emission in solution and yellow emission in solid state [J].J. Colloid Interface Sci., 2020, 565: 77-85.

TOMSKAYA A E, EGOROVA M N, KAPITONOV A N, et al. Synthesis of luminescent N-doped carbon dots by hydrothermal treatment [J].Phys. Stat. Solidi (B), 2018, 255(1): 1700222-1-5.

HAN S J, CHEN X P, HU Y P, et al. Solid-state N, P-doped carbon dots conquer aggregation-caused fluorescence quenching and couple with europium metal-organic frameworks toward white light-emitting diodes [J].Dyes Pigment., 2021, 187: 109090-1-6.

LI D, LIANG C, USHAKOVA E V, et al. Thermally activated upconversion near-infrared photoluminescence from carbon dots synthesized via microwave assisted exfoliation [J].Small, 2019, 15(50): 1905050-1-7.

QU S N, ZHOU D, LI D, et al. Toward efficient orange emissive carbon nanodots through conjugated sp2-domain controlling and surface charges engineering [J].Adv. Mater., 2016, 28(18): 3516-3521.

WANG L, LI W T, YIN L Q, et al. Full-color fluorescent carbon quantum dots [J].Sci. Adv., 2020, 6(40): eabb6772-1-9.

HU T T, WEN Z Q, WANG C, et al. Temperature-controlled spectral tuning of full-color carbon dots and their strongly fluorescent solid-state polymer composites for light-emitting diodes [J].Nanoscale Adv., 2019, 1, 1413-1420.

MIAO X, QU D, YANG D X, et al. Synthesis of carbon dots with multiple color emission by controlled graphitization and surface functionalization [J].Adv. Mater., 2018, 30(1): 1704740-1-8.

DING H, WEI J S, ZHANG P, et al. Solvent-controlled synthesis of highly luminescent carbon dots with a wide color gamut and narrowed emission peak widths [J].Small, 2018, 14(22): 1800612-1-10.

YUAN F L, HE P, XI Z F, et al. Highly efficient and stable white LEDs based on pure red narrow bandwidth emission triangular carbon quantum dots for wide-color gamut backlight displays [J].Nano Res., 2019, 12(7): 1669-1674.

WANG H J, HOU W Y, HAO Y W, et al. Novel yellow solid-state fluorescent-emitting carbon dots with high quantum yield for white light-emitting diodes [J].Spectroc. Acta A-Mol. Biomolec. Spectr., 2020, 250: 119340-1-8.

ZHANG K Y, SHI Y A, JIA Y, et al. Tunable dual fluorescence emissions with high photoluminescence quantum yields modulated by Na ion dispersion method for purely solid state N-doped carbon dots [J].J. Photochem. Photobiol. A-Chem., 2020, 397: 112548-1-7.

YUAN F L, WANG Y K, SHARMA G, et al. Bright high-colour-purity deep-blue carbon dot light-emitting diodes via efficient edge amination [J].Nat. Photonics, 2020, 14: 171-176.

XIE Z, WANG F, LIU CY. Organic-inorganic hybrid functional carbon dot gel glasses [J].Adv. Mater., 2012, 24(13): 1716-1721.

WANG Y, KALYTCHUK S, WANG L Y, et al. Carbon dot hybrids with oligomeric silsesquioxane: solid-state luminophores with high photoluminescence quantum yield and applicability in white light emitting devices [J].Chem. Commun., 2015, 51(14): 2950-2953.

GREEN D C, HOLDEN M A, LEVENSTEIN M A, et al. Controlling the fluorescence and room-temperature phosphorescence behaviour of carbon nanodots with inorganic crystalline nanocomposites [J].Nat. Commun., 2019, 10(1): 206-1-13.

SUN M Y, QU S N, HAO Z D, et al. Towards efficient solid-state photoluminescence based on carbon-nanodots and starch composites [J].Nanoscale, 2014, 6(21): 13076-13081.

ZHOU D, ZHAI Y C, QU S N, et al. Electrostatic assembly guided synthesis of highly luminescent carbon-nanodots@BaSO4 hybrid phosphors with improved stability [J].Small, 2017, 13(6): 1602055-1-10.

TIAN Z, ZHANG X T, LI D, et al. Full-color inorganic carbon dot phosphors for white-light-emitting diodes [J].Adv. Opt. Mater., 2017, 5(19): 1700416-1-9.

WANG A W, HOU Y L, KANG F W, et al. Rare earth-free composites of carbon dots/metal-organic frameworks as white light emitting phosphors [J].J. Mater. Chem. C, 2019, 7(8): 2207-2211.

BHUNIA S K, NANDI S, SHIKLER R, et al. Tuneable light-emitting carbon-dot/polymer flexible films prepared through one-pot synthesis [J].Nanoscale, 2016, 8(6): 3400-3406.

LI H Y, ZHANG Z X, DING J, et al. Diamond-like carbon structure-doped carbon dots: a new class of self-quenching-resistant solid-state fluorescence materials toward light-emitting diodes [J].Carbon, 2019, 149, 342-349.

YOO H J, KWAK B E, KIM D H. Self-quenching origin of carbon dots and the guideline for their solid-state luminescence [J].J. Phys. Chem. C, 2019, 123(44): 27124-27131.

ZHOU D, JING P T, WANG Y, et al. Carbon dots produced via space-confined vacuum heating: maintaining efficient luminescence in both dispersed and aggregated states [J].Nanoscale Horiz., 2019, 4(2): 388-395.

NIU X Q, SONG T B, XIONG H M. Large scale synthesis of red emissive carbon dots powder by solid state reaction for fingerprint identification [J].Chin. Chem. Lett., 2021, 32(6): 1953-1956.

CHOI Y, KANG B, LEE J, et al. Integrative approach toward uncovering the origin of photoluminescence in dual heteroatom-doped carbon nanodots [J].Chem. Mater., 2016, 28(19): 6840-6847.

SHEN C, WANG J, CAO Y, et al. Facile access to B-doped solid-state fluorescent carbon dots toward light emitting devices and cell imaging agents [J].J. Mater. Chem. C, 2015, 3(26): 6668-6675.

LI D, HAN D, QU SN, et al. Supra-(carbon nanodots) with a strong visible to near-infrared absorption band and efficient photothermal conversion [J].Light Sci. Appl., 2016, 5(7): e16120-1-8.

LI X M, LIU Y L, SONG X F, et al. Intercrossed carbon nanorings with pure surface states as low-cost and environment-friendly phosphors for white-light-emitting diodes [J].Angew. Chem. Int. Ed., 2015, 54(6): 1759-1764.

ZHOU Z J, TIAN P F, LIU X Y, et al. Hydrogen peroxide-treated carbon dot phosphor with a bathochromic-shifted, aggregation-enhanced emission for light-emitting devices and visible light communication [J].Adv. Sci., 2018, 5(8): 1800369-1-8.

TAO Y F, LIN J, WANG D Y, et al. Na+-functionalized carbon dots with aggregation-induced and enhanced cyan emission [J].J. Colloid Interface Sci., 2021, 588: 469-475.

ZHAO Y Y, HE B C, LIU E S, et al. Aluminum-based surface polymerization on carbon dots with aggregation-enhanced luminescence [J].J. Phys. Chem. Lett., 2021, 12(19): 4530-4536.

TANG B Z, ZHAN X W, YU G, et al. Efficient blue emission from siloles [J].J. Mater. Chem., 2001, 11(12): 2974-2978.

YANG H Y, LIU Y L, GUO Z Y, et al. Hydrophobic carbon dots with blue dispersed emission and red aggregation-induced emission [J].Nat. Commun., 2019, 10: 1789-1-11.

MENG T, YUAN T, LI X H, et al. Ultrabroad-band, red sufficient, solid white emission from carbon quantum dot aggregation for single component warm white light emitting diodes with a 91 high color rendering index [J].Chem. Commun., 2019, 55(46): 6531-6534.

FENG T L, ZENG Q S, LU S Y, et al. Color-tunable carbon dots possessing solid-state emission for full-color light-emitting diodes applications [J].ACS Photonics, 2018, 5(2): 502-510.

MENG T, WANG Z F, YUAN T, et al. Gram-scale synthesis of highly efficient rare-earth element-free red/green/blue solid-state bandgap fluorescent carbon quantum rings for white light-emitting diodes [J].Angew. Chem. Int., 2021, 60: 1-7.

ZHU S J, SONG Y B, SHAO J R, et al. Non-conjugated polymer dots with crosslink-enhanced emission in the absence of fluorophore units [J].Angew. Chem. Int. Ed., 2015, 54(49): 14626-14637.

TAO S Y, ZHU S J, FENG T L, et al. Crosslink-enhanced emission effect on luminescence in polymers: advances and perspectives [J].Angew. Chem. Int. Ed., 2020, 59(25): 9826-9840.

ZHU S J, WANG L, ZHOU N, et al. The crosslink enhanced emission(CEE) in non-conjugated polymer dots: from the photoluminescence mechanism to the cellular uptake mechanism and internalization [J].Chem. Commun., 2014, 50(89): 13845-13848.

TAO S Y, LU S Y, GENG Y J, et al. Design of metal-free polymer carbon dots: a new class of room-temperature phosphorescent materials [J].Angew. Chem. Int. Ed., 2018, 57(9): 2393-2398.

TAO S Y, FENG T L, ZHENG C Y, et al. Carbonized polymer dots: a brand new perspective to recognize luminescent carbon-based nanomaterials [J].J. Phys. Chem. Lett., 2019, 10(17): 5182-5188.

KWAK B E, YOO H J, KIM D H. Quenching-resistant polymer carbon dot preserving emission color consistency in solid-state [J].Adv. Opt. Mater., 2019, 7(23): 1900932-1-9.

SHAO J R, ZHU S J, LIU H W, et al. Full-color emission polymer carbon dots with quench-resistant solid-state fluorescence [J].Adv. Sci., 2017, 4(12): 1700395-1-8.

LIU E S, LI D, ZHOU X J, et al. Highly emissive carbon dots in solid state and their applications in light-emitting devices and visible light communication [J].ACS Sustain. Chem. Eng., 2019, 7(10): 9301-9308.

CHEN Y H, ZHENG M T, XIAO Y, et al. A self-quenching-resistant carbon-dot powder with tunable solid-state fluorescence and construction of dual-fluorescence morphologies for white light-emission [J].Adv. Mater., 2016, 28(2): 312-318.

AI L, YANG Y S, WANG B Y, et al. Insights into photoluminescence mechanisms of carbon dots: advances and perspectives [J].Sci. Bull., 2021, 66(8): 839-856.

ZHANG X Q, YANG H Y, WAN Z J, et al. Self-quenching-resistant red emissive carbon dots with high stability for warm white light-emitting diodes with a high color rendering index [J].Adv. Opt. Mater., 2020, 8(15): 2000251.

GE M, HUANG X, NI J X, et al. One-step synthesis of self-quenching-resistant biomass-based solid-state fluorescent carbon dots with high yield for white lighting emitting diodes [J].Dyes Pigment., 2021, 185: 108953-1-7.

CHANG Q, DING Y M, CHENG S, et al. Quench-resistant and stable nanocarbon dot/sheet emitters with tunable solid-state fluorescence via aggregation-induced color switching [J].Nanoscale, 2019, 11(5): 2131-2137.

ZHU J Y, BAI X, CHEN X, et al. Spectrally tunable solid state fluorescence and room-temperature phosphorescence of carbon dots synthesized via seeded growth method [J].Adv. Opt. Mater., 2019, 7(9): 1801599-1-7.

KWON W, KIM Y H, LEE C L, et al. Electroluminescence from graphene quantum dots prepared by amidative cutting of tattered graphite [J].Nano Lett., 2014, 14(3): 1306-1311.

KIM J K, BAE S, YI Y J, et al. Origin of white electroluminescence in graphene quantum dots embedded host/guest polymer light emitting diodes [J].Sci. Rep., 2015, 5: 11032-1-11.

XU J C, MIAO Y Q, ZHENG J X, et al. Carbon dot-based white and yellow electroluminescent light emitting diodes with a record-breaking brightness [J].Nanoscale, 2018, 10(23): 11211-11221.

WANG F, CHEN Y H, LIU C Y, et al. White light-emitting devices based on carbon dots' electroluminescence [J].Chem. Commun., 2011, 47(12): 3502-3504.

XU J C, MIAO Y Q, ZHENG J X, et al. Ultrahigh brightness carbon dot-based blue electroluminescent LEDs by host-guest energy transfer emission mechanism [J].Adv. Opt. Mater., 2018, 6: 1800181-1-5.

ZHANG XY, ZHANG Y, WANG Y, et al. Color-switchable electroluminescence of carbon dot light-emitting diodes [J].ACS Nano, 2013, 7(12): 11234-11241.

YUAN F L, WANG Z B, LI X H, et al. Bright multicolor bandgap fluorescent carbon quantum dots for electroluminescent light-emitting diodes [J].Adv. Mater., 2017, 29(3): 1604436-1-6.

PATHAK P H, FENG X T, HU P F, et al. Visible light communication, networking andsensing: a survey, potential and challenges [J].IEEE Commun. Surv. Tutor., 2015, 17(4): 2047-2077.

SAJJAD MT, MANOUSIADIS PP, OROFINO C, et al. Fluorescent red-emitting BODIPY oligofluorene star-shaped molecules as a color converter material for visible light communications [J].Adv. Opt. Mater., 2015, 3(4): 536-540.

PENG D, LIU X, HUANG M J, et al. A novel monodisperse SiO2@C-dot for the rapid and facile identification of latent fingermarks using self-quenching resistant solid-state fluorescence [J].Dalton Trans., 2018, 47(16): 5823-5830.

WANG H J, YU T T, CHEN H L, et al. A self-quenching-resistant carbon dots powder with tunable solid-state fluorescence and their applications in light-emitting diodes and fingerprints detection [J].Dyes Pigment., 2018, 159: 245-251.

RU Y, SUI L, SONG H Q, et al. Rational design of multicolor-emitting chiral carbonized polymer dots for full-color and white circularly polarized luminescence [J].Angew. Chem. Int. Ed., 2021, 60(25): 14091-14099.

浏览量

852

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

碳点药物载体在肿瘤治疗中的应用进展

菠菜基多色发光碳点及手性荧光膜的制备与性能

高显色指数白光LED用新型单组分固态碳点的制备

碳点基电致发光器件研究进展