碳点在鲁米诺和草酸酯化学发光体系中的研究进展
增强出版Research Advances in Carbon Dot-based Luminol and Peroxyoxalate Chemiluminescent Systems
- 发光学报 2021年42卷第8期 页码：1215-1232
- 作者机构：
1.郑州大学物理学院 材料物理教育部重点实验室，河南 郑州 450052
- 作者简介：
[ "沈成龙(1992-)，男，河南固始人，博士研究生，2017年于郑州大学获得硕士学位，主要从事化学碳纳米材料的合成与应用的研究。E-mail: phyclshen@gmail.com" ]
[ "娄庆(1986-)，男，河南睢县人，博士，副教授，2015年于中国科学院长春光学精密机械与物理研究所获得博士学位，主要从事碳基纳米发光材料与光电器件的研究。E-mail:louqing1986@zzu.edu.cn" ]
[ "单崇新(1977-)，男，河南长垣人，博士，教授，博士研究生导师，2004年于中国科学院长春光学精密机械与物理研究所获得博士学位，国家杰出青年基金获得者，教育部“长江学者奖励计划”特聘教授，主要从事金刚石光电材料与器件的研究。E-mail: cxshan@zzu.edu.cn" ]
- 基金信息：国家自然科学基金(12074348;U2004168;U1804155);中国博士后科学基金(2020M682310);河南省优秀青年基金(212300410078)
DOI：10.37188/CJL.20210171
中图分类号：
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沈成龙, 娄庆, 单崇新. 碳点在鲁米诺和草酸酯化学发光体系中的研究进展[J]. 发光学报, 2021,42(8):1215-1232.
Cheng-long SHEN, Qing LOU, Chong-xin SHAN. Research Advances in Carbon Dot-based Luminol and Peroxyoxalate Chemiluminescent Systems[J]. Chinese Journal of Luminescence, 2021,42(8):1215-1232.
沈成龙, 娄庆, 单崇新. 碳点在鲁米诺和草酸酯化学发光体系中的研究进展[J]. 发光学报, 2021,42(8):1215-1232. DOI： 10.37188/CJL.20210171.
Cheng-long SHEN, Qing LOU, Chong-xin SHAN. Research Advances in Carbon Dot-based Luminol and Peroxyoxalate Chemiluminescent Systems[J]. Chinese Journal of Luminescence, 2021,42(8):1215-1232. DOI： 10.37188/CJL.20210171.
摘要
作为一种无需光、热、声、电、磁激发的自发光现象，化学发光已经在化学分析检测、冷光源、生物成像等领域得到了广泛应用。对于多数化学发光体系而言，其化学发光性质不仅取决于化学反应的底物，更与化学反应中使用的催化剂和发光中间体相关。碳点是一种新型的零维发光碳纳米材料，以其优异的物理化学性质和丰富的结构形貌已在各种化学发光体系中获得了广泛的应用。本文主要从鲁米诺和过氧草酸酯两种常见化学发光体系出发，总结了碳点在鲁米诺和过氧草酸酯化学发光体系中的相关研究进展，探讨了碳点在鲁米诺和过氧草酸酯基化学发光中可能存在的作用机制，以及碳点在鲁米诺和过氧草酸酯化学发光体系中的相关应用。为合成具有特定化学发光性能的纳米材料提供思路，有望推动化学发光纳米材料的进一步发展。
Abstract
As a self-luminescence phenomenon without light, heat, sound, electricity and magnetism excitation, chemiluminescence has been widely used in chemical analysis, cold light source, bioimaging and related fields. For most chemiluminescent systems, their chemiluminescence depends not only on the substrates of chemical reactions, but also on the catalysts and chemiluminescent intermediates. Carbon dots are a new type of zero-dimensional luminescent carbon nanomaterials, which have been widely used in various chemiluminescent systems due to their excellent physicochemical properties, rich structure and morphology. On basis of the chemiluminescent systems of luminol and peroxyoxalate, this paper summarizes the research advances in carbon dot-based luminol and peroxyoxalate chemiluminescent systems, also discusses the possible mechanism and related application of carbon dot-based chemiluminescence in luminol and peroxyoxalate systems, which provides ideas for the synthesis of nanomaterials with specific chemiluminescent properties and promotes the further development of chemiluminescent nanomaterials.
关键词
碳点化学发光鲁米诺过氧草酸酯应用
Keywords
carbon dotschemiluminescenceluminolperoxyoxalateapplication
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