Er3+共掺增强BaSi2O2N2∶Eu2+发光

刘雪晴; 贺帅; 张亮亮; 潘国徽; 武华君; 吴昊; 张家骅

doi:10.37188/CJL.20210145

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Er³⁺共掺增强BaSi₂O₂N₂∶Eu²⁺发光

封面文章 | 更新时间：2021-09-13

- Er³⁺共掺增强BaSi₂O₂N₂∶Eu²⁺发光
  增强出版
- Enhanced Luminescence of BaSi₂O₂N₂∶Eu²⁺ By Co-doping Er³⁺
- 发光学报 2021年42卷第9期页码：1323-1330
- 作者机构：
  
  1.中国科学院长春光学精密机械与物理研究所　发光学及应用国家重点实验室，吉林　长春　 130033
  2.中国科学院大学，北京　 100049
- 作者简介：
  
  [ "刘雪晴(1995-)，女，吉林长春人，硕士研究生，2017年于吉林师范大学获得学士学位，主要从事稀土发光材料方面的研究。 E-mail: 1402994146@qq.com" ]
  [ "张家骅(1965-)，男，黑龙江呼兰人，博士，研究员，博士研究生导师，1997年于中国科学院长春物理研究所获得博士学位，主要从事发光材料与物理方面的研究。 E-mail: zhangjh@ciomp.ac.cn" ]
- 基金信息：
  
  国家自然科学基金(11874055;51772286;11974346;11904361);国家重点研发计划(2016YFB0400605;2016YFB0701003;2017YFB0403104);中国科学院青年创新促进会(2020222);吉林省中青年科技创新领导人才和团队项目(20190101001JH);中国科学院透明光功能无机材料实验室开放课题基金资助项目
- DOI：10.37188/CJL.20210145
  中图分类号： O482.31;O469
- 纸质出版日期：2021-09-01，
  
  收稿日期：2021-04-23，
  
  修回日期：2021-04-30，
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刘雪晴, 贺帅, 张亮亮, 等. Er³⁺共掺增强BaSi₂O₂N₂∶Eu²⁺发光[J]. 发光学报, 2021,42(9):1323-1330.

Xue-qing LIU, Shuai HE, Liang-liang ZHANG, et al. Enhanced Luminescence of BaSi₂O₂N₂∶Eu²⁺ By Co-doping Er³⁺[J]. Chinese Journal of Luminescence, 2021,42(9):1323-1330.
刘雪晴, 贺帅, 张亮亮, 等. Er³⁺共掺增强BaSi₂O₂N₂∶Eu²⁺发光[J]. 发光学报, 2021,42(9):1323-1330. DOI： 10.37188/CJL.20210145.

Xue-qing LIU, Shuai HE, Liang-liang ZHANG, et al. Enhanced Luminescence of BaSi₂O₂N₂∶Eu²⁺ By Co-doping Er³⁺[J]. Chinese Journal of Luminescence, 2021,42(9):1323-1330. DOI： 10.37188/CJL.20210145.

摘要

针对Er

共掺增强BaSi

∶Eu

发光效果的内在差异和可能机理进行了研究。通过XRD测试展示了共掺下的晶体结构，分析确认了样品纯度以及生长差异；为进一步研究差异的来源，监控了不同价态掺杂离子的发射光谱，对随Er

含量变化的发射光谱规律性变化进行展示，进而分析得出Er

共掺增强发光的内部物理机理是控制择优取向和对价态进行定向竞争调节；从发光体应用场景的温度范围需求进行了温度特性测试，展示了温度变化下的发射光谱变化。这项研究为调控发光强度、提高量子效率的工作提供了新的思路。

Abstract

This work has studied the effect of co-doping Er

enhanced BaSi

∶Eu

luminescence

mainly focusing on the internal difference and possible mechanism. The Er

co-doped crystal structure was demonstrated through XRD test

and the purity of the sample and the difference in growth were confirmed by analysis. In order to find out the sources of differences

the emission spectra of doped ions with different valence states have been monitored

and the emission spectra of the changes with the content of Er

have been compared. The internal physical mechanism of co-doping Er

enhanced luminescence is seen from the change of the luminescence. The internal physical mechanism of the co-doping Er

enhanced luminescence is to control the crystal texture and adjust the valence state. For practical applications in the future

a temperature characteristic test was carried out to show the emission spectrum changes under temperature variation. This research provides new ideas for the work of regulating the luminous intensity and improving quantum efficiency.

关键词

稀土发光材料BaSi2O2N2∶Eu2+荧光粉光致发光热稳定性

Keywords

rare earth materialBaSi2O2N2∶Eu2+ phosphorphotoluminescencethermal stability

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