Er3+共掺增强BaSi2O2N2∶Eu2+发光

刘雪晴; 贺帅; 张亮亮; 潘国徽; 武华君; 吴昊; 张家骅

doi:10.37188/CJL.20210145

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Er³⁺共掺增强BaSi₂O₂N₂∶Eu²⁺发光

封面文章 | 更新时间：2021-09-13

- Er³⁺共掺增强BaSi₂O₂N₂∶Eu²⁺发光
  增强出版
- Enhanced Luminescence of BaSi₂O₂N₂∶Eu²⁺ By Co-doping Er³⁺
- 发光学报 2021年42卷第9期页码：1323-1330
- 作者机构：
  
  1.中国科学院长春光学精密机械与物理研究所　发光学及应用国家重点实验室，吉林　长春　 130033
  2.中国科学院大学，北京　 100049
- 作者简介：
  
  [ "刘雪晴(1995-)，女，吉林长春人，硕士研究生，2017年于吉林师范大学获得学士学位，主要从事稀土发光材料方面的研究。 E-mail: 1402994146@qq.com" ]
  [ "张家骅(1965-)，男，黑龙江呼兰人，博士，研究员，博士研究生导师，1997年于中国科学院长春物理研究所获得博士学位，主要从事发光材料与物理方面的研究。 E-mail: zhangjh@ciomp.ac.cn" ]
- 基金信息：
  
  国家自然科学基金(11874055;51772286;11974346;11904361);国家重点研发计划(2016YFB0400605;2016YFB0701003;2017YFB0403104);中国科学院青年创新促进会(2020222);吉林省中青年科技创新领导人才和团队项目(20190101001JH);中国科学院透明光功能无机材料实验室开放课题基金资助项目
- DOI：10.37188/CJL.20210145
  中图分类号： O482.31;O469
- 收稿日期：2021-04-23，
  
  修回日期：2021-04-30，
  
  纸质出版日期：2021-09-01
- 稿件说明：
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刘雪晴, 贺帅, 张亮亮, 等. Er³⁺共掺增强BaSi₂O₂N₂∶Eu²⁺发光[J]. 发光学报, 2021,42(9):1323-1330.

Xue-qing LIU, Shuai HE, Liang-liang ZHANG, et al. Enhanced Luminescence of BaSi₂O₂N₂∶Eu²⁺ By Co-doping Er³⁺[J]. Chinese journal of luminescence, 2021, 42(9): 1323-1330.
刘雪晴, 贺帅, 张亮亮, 等. Er³⁺共掺增强BaSi₂O₂N₂∶Eu²⁺发光[J]. 发光学报, 2021,42(9):1323-1330. DOI： 10.37188/CJL.20210145.

Xue-qing LIU, Shuai HE, Liang-liang ZHANG, et al. Enhanced Luminescence of BaSi₂O₂N₂∶Eu²⁺ By Co-doping Er³⁺[J]. Chinese journal of luminescence, 2021, 42(9): 1323-1330. DOI： 10.37188/CJL.20210145.

摘要

针对Er

共掺增强BaSi

∶Eu

发光效果的内在差异和可能机理进行了研究。通过XRD测试展示了共掺下的晶体结构，分析确认了样品纯度以及生长差异；为进一步研究差异的来源，监控了不同价态掺杂离子的发射光谱，对随Er

含量变化的发射光谱规律性变化进行展示，进而分析得出Er

共掺增强发光的内部物理机理是控制择优取向和对价态进行定向竞争调节；从发光体应用场景的温度范围需求进行了温度特性测试，展示了温度变化下的发射光谱变化。这项研究为调控发光强度、提高量子效率的工作提供了新的思路。

Abstract

This work has studied the effect of co-doping Er

enhanced BaSi

∶Eu

luminescence

mainly focusing on the internal difference and possible mechanism. The Er

co-doped crystal structure was demonstrated through XRD test

and the purity of the sample and the difference in growth were confirmed by analysis. In order to find out the sources of differences

the emission spectra of doped ions with different valence states have been monitored

and the emission spectra of the changes with the content of Er

have been compared. The internal physical mechanism of co-doping Er

enhanced luminescence is seen from the change of the luminescence. The internal physical mechanism of the co-doping Er

enhanced luminescence is to control the crystal texture and adjust the valence state. For practical applications in the future

a temperature characteristic test was carried out to show the emission spectrum changes under temperature variation. This research provides new ideas for the work of regulating the luminous intensity and improving quantum efficiency.

关键词

Keywords

references

GU Y X , ZHANG Q H , LI Y G , et al . Nitridation from core-shell oxides for tunable luminescence of BaSi2O2N2∶Eu2+ LED phosphors [J]. J. Mater. Chem. , 2010 , 20 ( 29 ): 6050 - 6056 .

YUN B G , HORIKAWA T , HANZAWA H , et al . Preparation and luminescence properties of single-phase BaSi2O2N2∶Eu2+, a bluish-green phosphor for white light-emitting diodes [J]. J. Electrochem. Soc. , 2010 , 157 ( 10 ): J364 .

王灵利 , 倪海勇 , 张秋红 . LED用绿色荧光粉BaSi2N2O2∶Eu2+的发光和封装性能 [J]. 发光学报 , 2012 , 33 ( 5 ): 465 - 469 .

WANG L L , NI H Y , ZHANG Q H . Luminescence and encapsulation properties of BaSi2O2N2 doped with divalent europium [J]. Chin. J. Lumin. , 2012 , 33 ( 5 ): 465 - 469 . (in Chinese)

QIN J L , ZHANG H R , LEI B F , et al . Thermoluminescence and temperature-dependent afterglow properties in BaSi2O2N2∶Eu2+ [J]. J. Am. Ceram. Soc. , 2013 , 96 ( 10 ): 3149 - 3154 .

MA Z D , ZHOU J Y , ZHANG J C , et al . Mechanics-induced triple-mode anticounterfeiting and moving tactile sensing by simultaneously utilizing instantaneous and persistent mechanoluminescence [J]. Mater. Horiz. , 2019 , 6 ( 10 ): 2003 - 2008 .

PETIT R R , MICHELS S E , FENG A , et al . Adding memory to pressure-sensitive phosphors [J]. Light:Sci. Appl. , 2019 , 8 : 124-1-10 .

BOTTERMAN J , VAN DEN EECKHOUT K , DE BAERE I , et al . Mechanoluminescence in BaSi2O2N2∶Eu [J]. Acta Mater. , 2012 , 60 ( 15 ): 5494 - 5500 .

赵春雷 , 胡运生 , 陈凯 , 等 . 白光LED用硅基氮(氧)化物荧光粉的研究进展 [J]. 稀有金属 , 2017 , 41 ( 12 ): 1374 - 1385 .

ZHAO C L , HU Y S , CHEN K , et al . Research progress in silicon-based (oxy) nitride phosphors for phosphor-converted white LED [J]. Chin. J. Rare Met. , 2017 , 41 ( 12 ): 1374 - 1385 . (in Chinese)

PAWLIK T , MICHALIK D , BARZOWSKA J , et al . The influence of synthesis temperature on manufacturing and properties of SrSi2O2N2∶Eu2+ powders [J]. Arch. Metall. Mater. , 2017 , 62 ( 2 ): 687 - 690 .

SONG Y , SONG Y , TODA K , et al . Synthesis and photoluminescence properties of oxynitride phosphors M0.98Si2O2N2∶E http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=21210965&type= http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=21210973&type= http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=21210969&type= (M=Ba, Sr, Ca) using the cellulose assisted liquid phase precursor process [J]. Ceram. Int. , 2016 , 42 ( 8 ): 9667 - 9672 .

HUANG J S , LIU R H , LIU Y H , et al . Effect of fluxes on synthesis and luminescence properties of BaSi2O2N2∶Eu2+ oxynitride phosphors [J]. J. Rare Earths , 2018 , 36 ( 3 ): 225 - 230 .

ADAMCZYK B J , BRIK M G , NAGIRNYI V , et al . Optical properties of SrSi2O2N2∶Eu2+ phosphor enhanced by the addition of carbonate or fluoride reactive agents [J]. J. Alloys Compd. , 2020 , 845 : 155468 .

ADAMCZYK B J , JÜSTEL T , PLEWA J , et al . The influence of Na2CO3 flux on photoluminescence properties of SrSi2O2N2∶Eu2+ phosphor [J]. Ceram. Int. , 2017 , 43 ( 15 ): 12381 - 12387 .

HUO J S , LÜ W , SHAO B Q , et al . Enhanced luminescence intensity of CaSi2O2N2∶Eu2+ phosphor by using flux in the preparation process and incorporating Gd3+ ions [J]. J. Lumin. , 2016 , 180 : 46 - 50 .

LI H L , CHEN H , YANG L , et al . Facile synthesis and systematic study of Eu2+ doped SrSi2O2N2 green-emitting phosphor based on a new method [J]. J. Lumin. , 2018 , 194 : 661 - 666 .

谢安 , 王宇威 , 张裕骏 , 等 . 两步反应法制备硅基氮氧化物荧光材料SrSi2O2N2∶Eu2+及其发光性能研究 [J]. 中国科学:物理学力学天文学 , 2014 , 44 ( 7 ): 712 - 719 .

XIE A , WANG Y W , ZHANG Y J , et al . Structure and photoluminescence properties of SrSi2O2N2∶Eu2+ phosphors prepared by two-step solid state reaction using Sr2SiO4∶Eu2+ as a precursor [J]. Sci. Sinica-Phys. Mech. Astron. , 2014 , 44 ( 7 ): 712 - 719 . (in Chinese)

WU D , FU L , HE S A , et al . Significantly enhanced luminescence efficiency and thermal stability of BaSi2O2N2∶Eu2+ phosphor by doping a very small amount of SiC [J]. Ceram. Int. , 2020 , 46 ( 16 ): 25382 - 25391 .

LI X C , DENG C Y , LONG F , et al . Effect of silicon powder content in starting materials on the phase and luminescence properties of SrSi2O2N2∶Eu2+ phosphors [J]. J. Mater. Sci.:Mater. Electron. , 2017 , 28 ( 17 ): 12551 - 12554 .

SONG X F , FU R L , AGATHOPOULOS S , et al . Synthesis of BaSi2O2N2∶Ce3+, Eu2+ phosphors and determination of their luminescence properties [J]. J. Am. Ceram. Soc. , 2011 , 94 ( 2 ): 501 - 507 .

MAJEWSKA N , LEŚNIEWSKI T , MAHLIK S , et al . Study of persistent luminescence and thermoluminescence in SrSi2N2O2∶Eu2+, M3+(M=Ce, Dy, and Nd) [J]. Phys. Chem. Chem. Phys. , 2020 , 22 ( 30 ): 17152 - 17159 .

ZOU Y X , YU L X , GAO Z Y , et al . Synthesis, crystal structure, and photoluminescence of Eu2+, Ce3+, Mn2+ doped oxynitride phosphors [J]. Opt. Mater. , 2019 , 92 : 411 - 417 .

HAO J R , CAO L , WEI Y , et al . Improving photoluminescence and thermal stability of CaSi2O2N2∶Eu2+ phosphors by codoping lanthanide ions (Ln=Sc, La, Gd, Yb, Lu) [J]. Mater. Lett. , 2018 , 211 : 122 - 125 .

KECHELE J A , OECKLER O , STADLER F , et al . Structure elucidation of BaSi2O2N2—a host lattice for rare-earth doped luminescent materials in phosphor-converted (pc)-LEDs [J]. Solid State Sci. , 2009 , 11 ( 2 ): 537 - 543 .

MIYAZAKI H , YOSHIDA S , SUZUKI H , et al . Phosphorescence properties of MSi2O2N2∶Eu(M=Ca, Sr, Ba) mixture-phase phosphors using Si2N2O powder [J]. J. Ceram. Soc. Japan , 2015 , 123 ( 1435 ): 152 - 155 .

LI G G , LIN C C , CHEN W T , et al . Photoluminescence tuning via cation substitution in oxonitridosilicate phosphors:DFT calculations, different site occupations, and luminescence mechanisms [J]. Chem. Mater. , 2014 , 26 ( 9 ): 2991 - 3001 .

SEIBALD M , ROSENTHAL T , OECKLER O , et al . Highly efficient pc-LED phosphors Sr1-xBaxSi2O2N2∶Eu2+(0 x 1)-crystal structures and luminescence properties revisited [J]. Crit. Rev. Solid State Mater. Sci. , 2014 , 39 ( 3 ): 215 - 229 .

CHEN Y , ZHANG J . Investigation on luminescence of bifunctional Y4.67(SiO4)3O∶Ce3+/Tb3+/Eu3+ phosphors [J]. J. Lumin. , 2020 , 218 : 116842 .

HUANG D Y , WEI Y , DANG P P , et al . Tunable color emission in LaScO3∶Bi3+, Tb3+, Eu3+ phosphor [J]. J. Am. Ceram. Soc. , 2020 , 103 ( 5 ): 3273 - 3285 .

ZHANG L L , HAO Z D , ZHANG X , et al . Enhanced ~2 μm emission of Tm3+ in Lu2O3 by addition of a trace amount of Er3+ [J]. Inorg. Chem. , 2017 , 56 ( 21 ): 13062 - 13069 .

WU H , HAO Z D , ZHANG L L , et al . Phonon energy dependent energy transfer upconversion for the red emission in the Er3+/Yb3+ system [J]. J. Phys. Chem. C , 2018 , 122 ( 17 ): 9611 - 9618 .

KIM J S , PARK Y H , KIM S M , et al . Temperature-dependent emission spectra of M2SiO4∶Eu2+(M=Ca, Sr, Ba) phosphors for green and greenish white LEDs [J]. Solid State Commun. , 2005 , 133 ( 7 ): 445 - 448 .

BAGINSKIY I , LIU R S , WANG C L , et al . Temperature dependent emission of strontium-barium orthosilicate (Sr2-xBax)-SiO4∶Eu2+ phosphors for high-power white light-emitting diodes [J]. J. Electrochem. Soc. , 2011 , 158 ( 10 ): P118 .

XIAO W E , ZHANG X , HAO Z D , et al . Blue-emitting K2Al2B2O7∶Eu2+phosphor with high thermal stability and high color purity for near-UV-pumped white light-emitting diodes [J]. Inorg. Chem. , 2015 , 54 ( 7 ): 3189 - 3195 .

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