一种高选择性萘甲酰腙铜离子探针合成及其在吸附中的应用

王会镇; 薛松松; 周霞; 刘家琴; 解正峰

doi:10.37188/CJL.20210134

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一种高选择性萘甲酰腙铜离子探针合成及其在吸附中的应用

发光学应用及交叉前沿 | 更新时间：2021-09-13

- 一种高选择性萘甲酰腙铜离子探针合成及其在吸附中的应用
  增强出版
- Synthesis of Highly Selective Copper Ion Probe and Its Application in Adsorption
- 发光学报 2021年42卷第9期页码：1427-1435
- 作者机构：
  
  1.西华大学　理学院，四川　成都　 610039
  2.西南石油大学　化学化工学院，四川　成都　 610500
- 作者简介：
  
  [ "王会镇(1988-)，男，山东寿光人，硕士，实验师，2014年于西南科技大学获得硕士学位，主要从事荧光探针的合成及应用的研究。 E-mail: 578527840@qq.com" ]
  [ "解正峰(1972-)，男，山东东阿人，博士，教授，2011年于西安交通大学获得博士学位，主要从事精细有机功能材料的合成及应用的研究。 E-mail: xiezhf@swpu.edu.cn" ]
- 基金信息：
  
  教育部春晖计划(191630);四川省教育厅项目(18ZB0571)
- DOI：10.37188/CJL.20210134
  中图分类号：
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王会镇, 薛松松, 周霞, 等. 一种高选择性萘甲酰腙铜离子探针合成及其在吸附中的应用[J]. 发光学报, 2021,42(9):1427-1435.

Hui-zhen WANG, Song-song XUE, Xia ZHOU, et al. Synthesis of Highly Selective Copper Ion Probe and Its Application in Adsorption[J]. Chinese Journal of Luminescence, 2021,42(9):1427-1435.
王会镇, 薛松松, 周霞, 等. 一种高选择性萘甲酰腙铜离子探针合成及其在吸附中的应用[J]. 发光学报, 2021,42(9):1427-1435. DOI： 10.37188/CJL.20210134.

Hui-zhen WANG, Song-song XUE, Xia ZHOU, et al. Synthesis of Highly Selective Copper Ion Probe and Its Application in Adsorption[J]. Chinese Journal of Luminescence, 2021,42(9):1427-1435. DOI： 10.37188/CJL.20210134.

摘要

以3-羟基-2-萘甲酰肼和4-二苯氨基苯甲醛为原料，设计合成了一种新型萘甲酰腙铜离子荧光探针L(N'-(4-(二苯胺基)亚苄基)-3-羟基-2-萘酰肼)，并通过,1,H NMR、,13,C NMR、HR-MS、IR和X射线单晶衍射法对L的结构进行了表征。在H,2,O/DMSO(,V∶V,=3∶7,pH=7)溶液体系中，可以高选择性和高灵敏性识别Cu,2+,。通过质谱法、核磁滴定和DFT计算对L与Cu,2+,可能的作用机理进行了研究。通过将L掺杂到聚丙烯酰胺(PAM)中，制备了凝胶(PAML)。研究表明，PAML对Cu,2+,有很好的吸附性能，且不受其他离子的干扰，对水中Cu,2+,去除率可以达到96.99%，并且在紫外灯下通过肉眼很容易进行区分。之后通过SEM-EDS对PAML吸附前后的微观形貌和成分进行了分析。

Abstract

A novel Schiff base fluorescent probe (N'-(4-(diphenylamino)benzylidene)-3-hydroxy-2-Naphtho-hydrazide)(L) was designed and synthesized using 3-hydroxy-2-naphthoic acid hydrazide and 4-diphenylaminobenzaldehyde as raw materials. The structure of L was characterized through,1,H NMR,13,C NMR, HR-MS, IR and X-ray. The study found that probe L showed high sensitivity and selectivity response to copper ions(Cu,2+,) in H,2,O/DMSO(,V,∶,V,=3∶7, pH=7) solution. The possible mechanism of coordination between L and Cu,2+, was studied by HR-MS,1,H NMR and DFT calculation. PAML was prepared by the method of doping L into polyacrylamide(PAM). PAML had high adsorption of Cu,2+, and the removal rate of Cu,2+, by PAML in water reached 96.99%, in addition, the color change could be distinguished by naked eyes under UV lamp. The microscopic morphology of PAML before and after adsorption of Cu,2+, was observed by SEM-EDS.

关键词

酰腙铜离子荧光探针聚丙烯酰胺掺杂

Keywords

Schiff baseCu2+fluorescence probepolyacrylamide(PAM) doping

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