三苯甲基改性油溶性碳量子点合成及其在发光器件中的应用

尚金梁; 卫迎迎; 王军丽; 刘旭光; 苗艳勤

doi:10.37188/CJL.20210115

您当前的位置：

首页 >

文章列表页 >

三苯甲基改性油溶性碳量子点合成及其在发光器件中的应用

特邀报告 | 更新时间：2021-09-03

- 三苯甲基改性油溶性碳量子点合成及其在发光器件中的应用
  增强出版
- Synthesis of Triphenylmethyl Modified Oil-soluble Carbon Quantum Dots and Their Applications in Light-emitting Devices
- 发光学报 2021年42卷第8期页码：1257-1266
- 作者机构：
  
  1.太原理工大学　新型碳材料研究院，山西　太原　 030000
  2.太原理工大学　新材料界面科学与工程教育部重点实验室，山西　太原　 030000
- 作者简介：
  
  [ "尚金梁(1994-)，男，山西阳泉人，硕士研究生，2017年于山东理工大学获得学士学位，主要从事碳量子点在发光器件中应用的研究。E-mail: 17836217764@163.com" ]
  [ "刘旭光(1965-)，男，山西翼城人，博士，教授，博士研究生导师，2000年于中国科学院山西煤炭化学研究所获得博士学位，主要从事纳米碳功能材料、碳量子点基光电材料的研究。E-mail: liuxuguang@tyut.edu.cn" ]
  [ "苗艳勤(1987-)，男，山西临县人，博士，副教授，硕士研究生导师，2015年于太原理工大学获得博士学位，主要从事有机发光二极管(OLED)的效率滚降、照明用白光OLED的开发、量子点及钙钛矿发光二极管及其物理、深红及近红外光探测器件的研究。E-mail: miaoyanqin@tyut.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(51972221);山西省回国留学人员科研资助项目(HGKY2019027;2020-051);山西重点研发计划（国际合作）(201903D421087);山西省高等学校优秀青年学术带头人资助项目
- DOI：10.37188/CJL.20210115
  中图分类号： O482.31
- 纸质出版日期：2021-08-01，
  
  收稿日期：2021-03-31，
  
  修回日期：2021-04-16，
扫描看全文
尚金梁, 卫迎迎, 王军丽, 等. 三苯甲基改性油溶性碳量子点合成及其在发光器件中的应用[J]. 发光学报, 2021,42(8):1257-1266.

Jin-liang SHANG, Ying-ying WEI, Jun-li WANG, et al. Synthesis of Triphenylmethyl Modified Oil-soluble Carbon Quantum Dots and Their Applications in Light-emitting Devices[J]. Chinese Journal of Luminescence, 2021,42(8):1257-1266.
尚金梁, 卫迎迎, 王军丽, 等. 三苯甲基改性油溶性碳量子点合成及其在发光器件中的应用[J]. 发光学报, 2021,42(8):1257-1266. DOI： 10.37188/CJL.20210115.

Jin-liang SHANG, Ying-ying WEI, Jun-li WANG, et al. Synthesis of Triphenylmethyl Modified Oil-soluble Carbon Quantum Dots and Their Applications in Light-emitting Devices[J]. Chinese Journal of Luminescence, 2021,42(8):1257-1266. DOI： 10.37188/CJL.20210115.

摘要

碳量子点团聚将导致严重荧光猝灭，大幅降低其发光效率，阻碍了其作为发光材料在显示和照明器件中的应用。通过主客体掺杂方案可有效解决上述问题，但水溶性的碳量子点不能和有机的主体材料相匹配。针对该问题，本文通过在碳量子点表面接枝亲油性的芳香类官能团，保证碳量子点油溶性的同时使其具备一定的载流子传输性能，采用该方案制备出发光峰在533 nm、荧光量子产率为43%的黄色油溶性碳量子点。将该碳量子点分散到聚甲基丙烯酸甲酯中涂敷在紫外发光二极管(365 nm)灯珠表面，制备的光致发光器件发出明亮黄光(560 nm)，最大亮度达到23 000 cd/m

。进一步将该碳量子点掺杂到聚乙烯基咔唑中作为发光层，制备了主客体掺杂的电致发光器件，器件的发射峰位于552 nm，最大亮度达到35.07 cd/m

。上述研究表明，合成油溶性的碳量子点发光材料并将其掺杂到母体材料中作为发光层，可有效抑制碳量子点团聚诱导荧光猝灭问题，对发展高性能碳量子点基发光器件具有重要意义。

Abstract

The aggregation of carbon quantum dots leads to serious fluorescence quenching

which greatly reduces the luminescence efficiency and hinders the application of carbon quantum dots as luminescent materials in display and lighting devices. The host-guest doping scheme can effectively solve the above problems

but the water-soluble carbon quantum dots can not match the organic host materials. In view of this

in this paper

the oil solubility of the carbon quantum dots was guaranteed by grafting the aromatic functional groups with liophilic properties on the surface of the carbon quantum dots

so that the carbon quantum dots had certain carrier transport performance. The yellow oil-soluble carbon quantum dots with a light peak of 533 nm and a fluorescence quantum yield of 43% were prepared by this scheme. The carbon quantum dots were dispersed into polymethyl methacrylate(PMMA) and coated on the surface of UV light emitting diode(365 nm) lamp beads. The photoluminescent devices were prepared with a bright yellow light(560 nm) and a maximum luminance of 23 000 cd/m

.Furthermore

the carbon quantum dots were doped into polyethylene carbazole(PVK) as the luminescent layer to fabricate host-guest doped electroluminescent devices. The emission peak of the devices is 552 nm

and the maximum luminance of the devices reaches 35.07 cd/m

. The above studies indicate that the synthesis of oil-soluble carbon quantum dot luminescent materials and doping them into the parent material as the luminescent layer can effectively suppress the fluorescence quenching induced by carbon quantum dot aggregation

which is of great significance for the development of high-performance carbon quantum dot based luminescent devices.

关键词

碳量子点发光二极管三苯甲基主客体掺杂发光层亮度

Keywords

carbon quantum dotslight-emitting diodetriphenyl methylhost and guest doped luminescent layerbrightness

references

朱小光. 浅谈LED照明技术的应用[J].硅谷, 2010(6): 27.

ZHU X G. Discussion on the application of LED lighting technology [J].Sil. Val., 2010(6): 27. (in Chinese)

FRANTSUZOV P A, VOLKÁN-KACSÓ S, JANKÓ B. Model of fluorescence intermittency of single colloidal semiconductor quantum dots using multiple recombination centers [J].Phys. Rev. Lett., 2009, 103(20): 207402.

刘博智. 氧化锌锡作电子传输层的CdSe(S)量子点发光二极管[D].杭州: 浙江大学, 2013.

LIU B Z. CdSe(S) OD-LEDS Devices Using ZnSnO as Electron-transporting Laver [D].Hangzhou: Zhejiang University, 2013. (in Chinese)

查朝云. OLED显示技术原理及其发展趋势[J].电子制作, 2016(15): 14-15.

ZHA Z Y. The principle and development trend of OLED display technology [J].Pract. Electron., 2016(15): 14-15. (in Chinese)

LEWINSKI N, COLVIN V, DREZEKR . Cytotoxicity of nanoparticles [J].Small, 2008, 4(1): 26-49.

SUN Y P, ZHOU B, LIN Y, et al. Quantum-sized carbon dots for bright and colorful photoluminescence [J].J. Am. Chem. Soc., 2006, 128(24): 7756-7757.

KRYSMANN M J, KELARAKIS A, DALLASP , et al. Formation mechanism of carbogenic nanoparticles with dual photoluminescence emission [J].J. Am. Chem. Soc., 2011, 134(2): 747-750.

SONG Y B, ZHU S J, ZHANG S T, et al. Investigation from chemical structure to photoluminescent mechanism: a type of carbon dots from the pyrolysis of citric acid and an amine [J].J. Mater. Chem. C, 2015, 3(23): 5976-5984.

ZHANG F, WANG Y L, MIAO Y Q, et al. Optimal nitrogen and phosphorus codoping carbon dots towards white light-emitting device [J].Appl. Phys. Lett., 2016, 109(8): 083103-1-5.

FENG X T, ZHANG F, WANG Y L, et al. Fluorescent carbon quantum dots as single light converter for white LEDs [J].J. Electron. Mater., 2016, 45(6): 2784-2788.

PAULO-MIRASOL S, MARTÍNEZ-FERRERO E, PALOMARES E, et al. Direct white light emission from carbon nanodots(C-dots) in solution processed light emitting diodes [J].Nanoscale, 2019, 11(23): 11315-11321.

ZHANG X Y, ZHANG Y, WANG Y, et al. Color-switchable electroluminescence of carbon dot light-emitting diodes [J].ACS Nano, 2013, 7(12): 11234-11241.

CHEN Y H, ZHENG M T, XIAO Y, et al. A self-quenching-resistant carbon-dot powder with tunable solid-state fluorescence and construction of dual-fluorescence morphologies for white light-emission [J].Adv. Mater., 2016, 28(2): 312-318.

DO S, KWON W, KIM Y H, et al. N, S-induced electronic states of carbon nanodots toward white electroluminescence [J].Adv. Opt. Mater., 2016, 4(2): 276-284.

LUO Z M, QI G Q, CHEN K Y, et al. Microwave-assisted preparation of white fluorescent graphene quantum dots as a novel phosphor for enhanced white-light-emitting diodes [J].Adv. Funct. Mater., 2016, 26(16): 2739-2744.

WANG J L, ZHANG F, WANG Y L, et al. Efficient resistance against solid-state quenching of carbon dots towards white light emitting diodes by physical embedding into silica [J].Carbon, 2018, 126: 426-436.

SONG S H, JANG M H, CHUNG J, et al. Highly efficient light-emitting diode of graphene quantum dots fabricated from graphite intercalation compounds [J].Adv. Opt. Mater., 2014, 2(11): 1016-1023.

WANG F, CHEN Y H, LIU C Y, et al. White light-emitting devices based on carbon dots’ electroluminescence [J].Chem. Commun., 2011, 47(12): 3502-3504.

YUAN F L, WANG Z B, LI X H, et al. Bright multicolor bandgap fluorescent carbon quantum dots for electroluminescent light-emitting diodes [J].Adv. Mater., 2017, 29(3): 1604436-1-6.

XU J C, MIAO Y Q, ZHENG J X, et al. Ultrahigh brightness carbon dot-based blue electroluminescent LEDs by host-guest energy transfer emission mechanism [J].Adv. Opt. Mater., 2018, 6(14): 1800181.

浏览量

251

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

维生素C添加剂改善纯红锡基钙钛矿电致发光性能

煤基碳量子点制备及对环境水中Cr（Ⅵ）的测定

硫醇⁃烯交联增强碳量子点发光效率机理研究

锗合金准二维钙钛矿发光二极管