Cr3+、Yb3+共掺杂LaSc3(BO3)4近红外荧光粉的发光与器件性能

邬金闽; 黄得财; 梁思思; 徐寿亮; 朱浩淼

doi:10.37188/CJL.20210066

您当前的位置：

首页 >

文章列表页 >

Cr³⁺、Yb³⁺共掺杂LaSc₃(BO₃)₄近红外荧光粉的发光与器件性能

材料合成及性能 | 更新时间：2021-06-18

- Cr³⁺、Yb³⁺共掺杂LaSc₃(BO₃)₄近红外荧光粉的发光与器件性能
- Photoluminescence Properties and Device Performance of Cr³⁺,Yb³⁺ Co-doped LaSc₃(BO₃)₄ Near Infrared Phosphors
- 发光学报 2021年42卷第6期页码：793-803
- 作者机构：
  
  1.福建农林大学材料工程学院, 福建福州　 350002
  2.中国科学院福建物质结构研究所中国科学院功能纳米结构设计与组装重点实验室，福建省纳米材料重点实验室, 福建福州　 350002
  3.中国科学院海西研究院厦门稀土材料研究所，厦门市稀土光电功能材料重点实验室, 福建厦门　 361021
- 作者简介：
  
  [ "邬金闽(1996-)，男，安徽安庆人，硕士研究生，2018年于辽宁石油化工大学获得学士学位，主要从事稀土发光材料的研究。E-mail: xmwujinmin@fjirsm.ac.cn" ]
  [ "朱浩淼(1979-)，男，湖北崇阳人，博士，研究员，2008年于中国科学院福建物质结构研究所获得博士学位，主要从事稀土发光材料的研究。E-mail: zhm@fjirsm.ac.cn" ]
- 基金信息：
  
  国家自然科学基金(11904363)
- DOI：10.37188/CJL.20210066
  中图分类号： O482.31
- 纸质出版日期：2021-06-01，
  
  收稿日期：2021-02-19，
  
  修回日期：2021-03-05，
扫描看全文
邬金闽, 黄得财, 梁思思, 等. Cr³⁺、Yb³⁺共掺杂LaSc₃(BO₃)₄近红外荧光粉的发光与器件性能[J]. 发光学报, 2021,42(6):793-803.

Jin-min WU, De-cai HUANG, Si-si LIANG, et al. Photoluminescence Properties and Device Performance of Cr³⁺,Yb³⁺ Co-doped LaSc₃(BO₃)₄ Near Infrared Phosphors[J]. Chinese Journal of Luminescence, 2021,42(6):793-803.
邬金闽, 黄得财, 梁思思, 等. Cr³⁺、Yb³⁺共掺杂LaSc₃(BO₃)₄近红外荧光粉的发光与器件性能[J]. 发光学报, 2021,42(6):793-803. DOI： 10.37188/CJL.20210066.

Jin-min WU, De-cai HUANG, Si-si LIANG, et al. Photoluminescence Properties and Device Performance of Cr³⁺,Yb³⁺ Co-doped LaSc₃(BO₃)₄ Near Infrared Phosphors[J]. Chinese Journal of Luminescence, 2021,42(6):793-803. DOI： 10.37188/CJL.20210066.

摘要

荧光粉转换型宽带发射近红外LED在食品检测、生物医药、安防监控等领域具有重要的应用价值。本工作介绍了一种具有宽带近红外发射的LaSc

(BO

)

∶Cr

(LSB∶Cr

)荧光粉，在460 nm蓝光激发下，其发射覆盖650~1 200 nm范围，半高宽达到170 nm。在此基础上，通过Yb

共掺，有效提升了其发光性能，其中发射峰半高宽拓宽到223 nm，最高发光量子产率由14%提升至35%，发光热稳定性也得到显著提高。基于荧光粉的发光量子产率、荧光寿命和发光热稳定性等数据分析，发现Yb

共掺杂对材料发光热稳定性的改善主要源于Cr

与Yb

之间的高效能量传递，并且Yb

在基质材料中表现出更好的热稳定性。最后，将LSB∶Cr

荧光粉与蓝光LED芯片结合，制备成近红外LED器件，在60 mA驱动电流下，近红外输出功率达16 mW。以上结果表明，LSB∶Cr

荧光粉是一种潜在的近红外LED用发光材料。

Abstract

Near-infrared phosphor-converted LEDs(NIR pc-LEDs)play an important role in the applications of food analysis

biomedicine

security monitoring

etc

. In this study

a broadband near-infrared phosphor LaSc

(BO

)

∶Cr

(LSB∶Cr

) is presented. Under 460 nm excitation

the emission band of LSB∶Cr

covers the spectral range of 650-1 200 nm with a full width at half maximum (FWHM) of 170 nm. Furthermore

the performance of LSB∶Cr

phosphor is improved by Yb

co-doping

leading to the broadened FWHM(up to 223 nm)

increased photoluminescence quantum yield(PL QY

from 14% to 35%) and reduced PL thermal quenching. Based on the analysis of PL spectrum

PL QYs

PL decay curves and PL thermal stability

it is revealed that the improvement of PL thermal stability by Yb

co-doping principally originates from the efficient energy transfer from Cr

to more thermally stable Yb

emitters. Finally

a NIR pc-LED is fabricated by combining the LSB∶Cr

phosphor with blue LED chip

which exhibits a maximum NIR output power of 16 mW at 60 mA drive current. These results suggest that LSB∶Cr

phosphor is a promising luminescent converter for broadband NIR pc-LED.

关键词

近红外荧光粉Cr3+/Yb3+共掺杂能量传递近红外荧光粉转换发光二极管

Keywords

near-infrared phosphorCr3+/Yb3+ co-dopingenergy transfernear-infrared phosphor-converted LED(NIR pc-LED)

references

XIAO Y Z, CHARIPAR N A, SALMAN J, et al. Nanosecond mid-infrared pulse generation via modulated thermal emissivity [J].Light Sci. Appl., 2019, 8:51.

HOVING-BOLINK A H, VEDDER H W, MERKS J W M, et al. Perspective of NIRS measurements early post mortem for prediction of pork quality [J].Meat Sci., 2005, 69(3):417-423.

YANG Y M, AW J, XING B G. Nanostructures for NIR light-controlled therapies [J].Nanoscale, 2017, 9(11):3698-3718.

IGNE B, ZACOUR B M, SHI Z Q, et al. Online monitoring of pharmaceutical materials using multiple NIR sensors—part Ⅰ:blend homogeneity [J].J. Pharm. Innov., 2011, 6(1):47-59.

BARBIERI A, BANDINI E, MONTI F, et al. The rise of near-infrared emitters:organic dyes, porphyrinoids, and transition metal complexes [J].Top. Curr. Chem., 2016, 374(4):47.

FUCHI S, TAKEDA Y. Wideband near-infrared phosphor by stacking Sm3+doped glass underneath Yb3+, Nd3+co-doped glass [J].Phys. Status Solidi (C), 2011, 8(9):2653-2656.

RAJENDRAN V, FANG M H, DE GUZMAN G N, et al. Super broadband near-infrared phosphors with high radiant flux as future light sources for spectroscopy applications [J].ACS Energy Lett., 2018, 3(11):2679-2684.

程丽娟, 刘贵珊, 万国玲, 等. 可见/近红外高光谱成像技术对长枣中葡萄糖含量的无损检测 [J].发光学报, 2019, 40(8):1055-1063.

CHENG L J, LIU G S, WANG G L, et al. Non-destructive detective of glucose contect in Lingwu Jujube by Vis/NIR hyperspectral imaging technology [J].Chin. J. Lumin., 2019, 40(8):1055-1063. (in Chinese)

丁佳兴, 杨晓玉, 房盟盟, 等. 可见/近红外高光谱成像技术对鸡蛋种类无损判别 [J].发光学报, 2018, 39(3):394-402.

DING J X, YANG X Y, FANG M M, et al. Non-destructive discrimination of different kinds egg by Vis/NIR hyperspectral imaging technique [J].Chin. J. Lumin., 2018, 39(3):394-402. (in Chinese)

YE S, SONG E H, MA E, et al. Broadband Cr3+-sensitized upconversion luminescence in La3Ga5GeO14∶Cr3+, Yb3+, Er3+ [J].Opt. Mater. Express, 2014, 4(4):638-648.

UEMURA H, FUCHI S, KATO R, et al. Development of near-infrared absorption spectrometry system by using NIR wideband glass phosphor LED [J].J. Phys. Conf. Ser., 2015, 619:012053-1-4.

LIANG J, DEVAKUMAR B, SUN LL, et al. Full-visible-spectrum lighting enabled by an excellent cyan-emitting garnet phosphor [J].J. Mater. Chem. C, 2020, 8(14):4934-4943.

NISHIMURA S, FUCHI S, TAKEDA Y. Luminescence properties of Tm2O3-doped oxide glasses for NIR wideband light source [J].J. Mater. Sci. Mater. Electron., 2017, 28(10):7157-7162.

RAJENDRAN V, CHANG H, LIU R S. (Invited)Recent progress on broadband near-infrared phosphors-converted light emitting diodes for future miniature spectrometers [J].Opt. Mater. X, 2019, 1:100011.

张亮亮, 张家骅, 郝振东, 等. Cr3+掺杂的宽带近红外荧光粉及其研究进展 [J].发光学报, 2019, 40(12):1449-1459.

ZHANG L L, ZHANG J H, HAO Z D, et al. Recent progress on Cr3+ doped broad band NIR phosphors [J].Chin. J. Lumin., 2019, 40(12):1449-1459. (in Chinese)

MALYSA B, MEIJERINK A, JÜSTEL T. Temperature dependent Cr3+ photoluminescence in garnets of the type X3Sc2Ga3O12(X=Lu, Y, Gd, La) [J].J. Lumin., 2018, 202:523-531.

DAI D J, WANG Z J, XING Z H, et al. Broad band emission near-infrared material Mg3Ga2GeO8∶Cr3+:substitution of Ga-In, structural modification, luminescence property and application for high efficiency LED [J].J. Alloys Compd., 2019, 806:926-938.

ELZBIECIAK-PIECKA K, DRABIK J, JAQUE D, et al. Cr3+ based nanocrystalline luminescent thermometers operating in a temporal domain [J].Phys. Chem. Chem. Phys., 2020, 22(44):25949-25962.

SHAO Q Y, DING H, YAO L Q, et al. Broadband near-infrared light source derived from Cr3+-doped phosphors and a blue LED chip [J].Opt. Lett., 2018, 43(21):5251-5254.

ZENG H T, ZHOU T L, WANG L, et al. Two-site occupation for exploring ultra-broadband near-infrared phosphor-double-perovskite La2MgZrO6∶Cr3+ [J].Chem. Mater., 2019, 31(14):5245-5253.

SONG E H, WANG J Q, SHI J H, et al. Highly efficient and thermally stable K3AlF6∶Mn4+ as a red phosphor for ultra-high-performance warm white light-emitting diodes [J].ACS Appl. Mater. Interfaces, 2017, 9(10):8805-8812.

SHAO Q Y, DING H, YAO L Q, et al. Photoluminescence properties of a ScBO3∶Cr3+ phosphor and its applications for broadband near-infrared LEDs [J].RSC Adv., 2018, 8(22):12035-12042.

HUANG D C, ZHU H M, DENG Z H, et al. A highly efficient and thermally stable broadband Cr3+-activated double borate phosphor for near-infrared light-emitting diodes [J].J. Mater. Chem. C, 2021, 9(1):164-172.

YAO L Q, SHAO Q Y, XU X X, et al. Broadband emission of single-phase Ca3Sc2Si3O12∶Cr3+/Ln3+(Ln=Nd, Yb, Ce) phosphors for novel solid-state light sources with visible to near-infrared light output [J].Ceram. Int., 2019, 45(11):14249-14255.

HE S, ZHANG L L, WU H, et al. Efficient super broadband NIR Ca2LuZr2Al3O12∶Cr3+, Yb3+garnet phosphor for pc-LED light source toward NIR spectroscopy applications [J].Adv. Opt. Mater., 2020, 8(6):1901684.

YAO L Q, SHAO Q Y, HAN S Y, et al. Enhancing near-infrared photoluminescence intensity and spectral properties in Yb3+ codoped LiScP2O7∶Cr3+ [J].Chem.Mater., 2020, 32(6):2430-2439.

WONG K L, BÜNZLI J C G, TANNER P A, et al. Quantum yield and brightness [J].J. Lumin., 2020, 224:117256.

HE M Y, WANG G F, LIN Z B, et al. Structure of medium temperature phase β-LaSc3(BO3)4 crystal [J].Mater. Res. Innov., 1999, 2(6):345-348.

LIN Z B, HU Z S, HAN X M, et al. Spectral parameters of Nd3+ ion in γ-Nd3+∶LaSc3(BO3)4 crystal [J].Phys. Status Solidi (B), 2002, 231(2):607-612.

SHANNON R D, PREWITT C T. Effective ionic radii in oxides and fluorides [J].Acta Crystallogr. Sect. B Struct. Crystallogr. Cryst. Chem., 1969, 25(5):925-946.

PARTHÉ E, HU S Z. Beta-LaSc3(BO3)4:correction of the crystal structure [J].Mater. Res. Innov., 2016, 7(6):353-354.

TOBY B H. EXPGUI, a graphical user interface for GSAS [J].J. Appl. Crystallogr., 2001, 34(2):210-213.

GRINBERG M, MACFARLANE P I, HENDERSON B, et al. Inhomogeneous broadening of optical transitions dominated by low-symmetry crystal-field components in Cr3+-doped gallogermanates [J].Phys. Rev. B, 1995, 52(6):3917-3929.

RAJENDRAN V, LESNIEWSKI T, MAHLIK S, et al. Ultra-broadband phosphors converted near-infrared light emitting diode with efficient radiant power for spectroscopy applications [J].ACS Photonics, 2019, 6(12):3215-3224.

王超, 王荣彬, 章皓, 等. 缺陷态对LED用荧光材料热稳定性的影响 [J].发光学报, 2020, 41(12):1554-1566.

WANG C, WANG R B, ZHANG H, et al. Effect of defect structure on thermal stability of fluorescent materials for LED applications [J].Chin. J. Lumin., 2020, 41(12):1554-1566. (in Chinese)

浏览量

501

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

基于BaMgSiO₄氧空位缺陷发光的可视化荧光温度传感材料

Ce³⁺⁃Cr³⁺共掺杂Ba₃Sc₄O₉荧光材料的发光性能

稀土离子的多格位占据及能量传递