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金属硫族簇基半导体中的Mn2+发光
Luminescence of Mn2+ in Metal Chalcogenide Cluster-based Semiconductors
- 发光学报 2021年42卷第7期 页码：953-975
- 作者机构：
1.苏州科技大学 材料科学与工程学院，江苏 苏州 215009
2.浙江大学化学系 浙江省激发态材料重点实验室，浙江 杭州 310027
- 作者简介：
[ "林坚(1986-)，男，浙江绍兴人，博士，副教授，2017年于苏州大学获得博士学位，主要从事半导体功能材料的合成与光电性能的研究。E-mail: linjian@mail.usts.edu.cn" ]
- 基金信息：国家自然科学基金(22001187);江苏省高等学校自然科学研究项目(20KJB150032)
DOI：10.37188/CJL.20210047
中图分类号： O482.31纸质出版日期：2021-07-01，
收稿日期：2021-01-31，
修回日期：2021-02-26，
扫 描 看 全 文
林坚, 陈德睢, 沈家辉, 等. 金属硫族簇基半导体中的Mn2+发光[J]. 发光学报, 2021,42(7):953-975.
Jian LIN, De-sui CHEN, Jia-hui SHEN, et al. Luminescence of Mn2+ in Metal Chalcogenide Cluster-based Semiconductors[J]. Chinese Journal of Luminescence, 2021,42(7):953-975.
林坚, 陈德睢, 沈家辉, 等. 金属硫族簇基半导体中的Mn2+发光[J]. 发光学报, 2021,42(7):953-975. DOI： 10.37188/CJL.20210047.
Jian LIN, De-sui CHEN, Jia-hui SHEN, et al. Luminescence of Mn2+ in Metal Chalcogenide Cluster-based Semiconductors[J]. Chinese Journal of Luminescence, 2021,42(7):953-975. DOI： 10.37188/CJL.20210047.
摘要
锰离子相对稳定的发光特性及锰掺杂荧光粉的成功使得人们对锰离子发光的研究热情不减。本文综述了Mn
2+
掺杂金属硫族簇基半导体中团簇结构、组分关联的Mn
2+
发光特性。金属硫族簇基半导体具有原子级的精确结构，为探究Mn
2+
发光的精确“构效关系”提供了理想模型。在Mn
2+
掺杂的金属硫族簇基半导体中， Mn
2+
附近键长和团簇组装方式的差异决定了Mn
2+
配位场强的变化，进而影响Mn
2+
发光波长的变化。在Mn
2+
掺杂的金属硫族纳米团簇中，Mn
2+
的聚集形式和聚集体中Mn
2+
的数量决定了Mn-Mn耦合相互作用的大小，直接影响Mn
2+
发光效率、寿命及激发特性。
Abstract
The relatively stable luminescence properties of manganese ions and the success of manganese doped phosphors benefit the continuous study on the luminescence properties of manganese ions. In this paper
cluster structures and component-related luminescence properties of Mn
2+
ions in the Mn
2+
doped metal chalcogenide cluster-based semiconductors are reviewed. Metal chalcogenide cluster-based semiconductors with precisely structure in atomic level
provide an ideal model for exploring the precise "structure-property relationship" corresponding to the luminescence of Mn
2+
ions. In the Mn
2+
doped metal chalcogenide cluster-based semiconductors
the difference of bond length near Mn
2+
ions and the assembly mode of clusters determine the change of Mn
2+
coordination field intensity
further affect the change of Mn
2+
ion emission wavelength. In the Mn
2+
doped metal chalcogenide nanoclusters
the aggregation form of Mn
2+
ions and the number of Mn
2+
ions in the aggregate determine the magnitude of Mn-Mn coupling interactions
which directly affect the luminescence efficiency
lifetime
and excitation characteristics of Mn
2+
ions.
关键词
金属硫族化合物锰掺杂半导体
Keywords
metal chalcogenidesmanganese dopingsemiconductor
references
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