基于CsPbBr<sub>3</sub>纳米晶掺杂硫醇-烯聚合物的荧光太阳集光器制备及集光性能

顾港伟; 郑子达; 张鑫; 张会红; 张晓伟

doi:10.37188/CJL.20210025

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基于CsPbBr₃纳米晶掺杂硫醇-烯聚合物的荧光太阳集光器制备及集光性能

发光学应用及交叉前沿 | 更新时间：2021-05-20

- 基于CsPbBr₃纳米晶掺杂硫醇-烯聚合物的荧光太阳集光器制备及集光性能
- Fabrication and Optical Efficiency of CsPbBr₃ Nanocrystals and Thiol-ene Polymer-based Luminescent Solar Concentrator
- 发光学报 2021年42卷第5期页码：724-732
- 作者机构：
  
  1.宁波大学　信息科学与工程学院，浙江　宁波　 315211
  2.南京大学　固体微结构物理国家重点实验室，江苏　南京　 210093
- 作者简介：
  
  [ "顾港伟(1997-)，男，浙江绍兴人，硕士研究生,2019年于南京理工大学泰州科技学院获得学士学位，主要从事微纳光电子器件的研究。E-mail: 1911082176@nbu.edu.cn" ]
  [ "张晓伟(1987-)，男，河北石家庄人，博士，副教授,2016年于南京大学获得博士学位，主要从事稀土掺杂硅基薄膜发光材料与光电子器件方面的研究。E-mail: zhangxiaowei@nbu.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(61974078;61704094);浙江省自然科学基金(LY21F040002);浙江省教育厅研究基金(Y201940881;Y201737316);浙江省省属高校基本科研业务费专项资金(SJLY2021012);宁波大学研究生科研创新基金(IF2020114)
- DOI：10.37188/CJL.20210025
  中图分类号： O482.31
- 纸质出版日期：2021-05-01，
  
  收稿日期：2021-01-13，
  
  修回日期：2021-01-31，
扫描看全文
顾港伟, 郑子达, 张鑫, 等. 基于CsPbBr₃纳米晶掺杂硫醇-烯聚合物的荧光太阳集光器制备及集光性能[J]. 发光学报, 2021,42(5):724-732.

Gang-wei GU, Zi-da ZHENG, Xin ZHANG, et al. Fabrication and Optical Efficiency of CsPbBr₃ Nanocrystals and Thiol-ene Polymer-based Luminescent Solar Concentrator[J]. Chinese Journal of Luminescence, 2021,42(5):724-732.
顾港伟, 郑子达, 张鑫, 等. 基于CsPbBr₃纳米晶掺杂硫醇-烯聚合物的荧光太阳集光器制备及集光性能[J]. 发光学报, 2021,42(5):724-732. DOI： 10.37188/CJL.20210025.

Gang-wei GU, Zi-da ZHENG, Xin ZHANG, et al. Fabrication and Optical Efficiency of CsPbBr₃ Nanocrystals and Thiol-ene Polymer-based Luminescent Solar Concentrator[J]. Chinese Journal of Luminescence, 2021,42(5):724-732. DOI： 10.37188/CJL.20210025.

摘要

荧光太阳集光器在光伏建筑一体化方面的潜在应用受到了广泛关注。本文采用CsPbBr

纳米晶作为集光器的发光中心，采用硫醇-烯聚合物作为集光器的透明光波导基质。通过荧光发射谱、吸收谱以及荧光寿命谱等对集光性能进行研究，发现将CsPbBr

纳米晶掺入硫醇-烯聚合物后，发光峰位蓝移了11 nm、半高宽展宽了20.4 nm，这可归因于硫醇-烯聚合物基质的介电约束效应。同时，硫醇-烯聚合物基质大幅提高了CsPbBr

纳米晶的发光稳定性。当CsPbBr

纳米晶在硫醇-烯聚合物基质中的掺杂浓度为5.6%时，荧光太阳集光器的集光效率可达8.9%。采用商用的多晶硅太阳能电池耦合在荧光太阳集光器的边缘，在标准AM1.5的太阳光照条件下，器件开路电压为0.47 V，短路电流密度为7.14 mA/cm

，填充因子为24.01%，光电转换效率为2.30%。

Abstract

Luminescent solar concentrator(LSC) attracts extensive attention due to the potential application in the building integrated photovoltaics. In this work

the CsPbBr

nanocrystal is chosen as the luminescent center and the thiol-ene polymer is used for the transparent optical waveguide matrix of LSC. The photoluminescence emission spectra

absorption spectra

and time-resolved emission spectra are performed to evaluate the optical efficiency

respectively. It is found that the emission peak blue-shifts by 11.0 nm and the full width at half maximum(FWHM) widens by 20.4 nm

which can be attributed to the dielectric screen effect of thiol-ene polymer matrix. Meanwhile

the introducing thiol-ene polymer matrix can greatly improve the photoluminescence emission stability of CsPbBr

nanocrystals. When the amount of CsPbBr

nanocrystals in the thiol-ene polymer matrix is 5.6%

the corresponding optical efficiency of LSC can reach 8.9%

which is higher than that of nanocrystals-based LSC reported in most previous studies. Further

the commercial polycrystalline silicon solar cell is designed to install in the edge of an LSC. Under the standard AM1.5 solar simulator

the device demonstrated the attractive attributes of open-circuit voltage of 0.47 V

short-circuit current density of 7.14 mA/cm

fill factor of 24.01%

and high power conversion efficiency up to 2.30%.

关键词

钙钛矿纳米晶硫醇-烯聚合物荧光太阳集光器光致发光集光效率

Keywords

perovskite nanocrystalthiol-ene polymerluminescent solar concentratorphotoluminescenceoptical efficiency

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基于CsPbBr3纳米晶掺杂硫醇-烯聚合物的荧光太阳集光器制备及集光性能

Fabrication and Optical Efficiency of CsPbBr3 Nanocrystals and Thiol-ene Polymer-based Luminescent Solar Concentrator

DOI：10.37188/CJL.20210025

摘要

Abstract

关键词

Keywords

references

基于CsPbBr₃纳米晶掺杂硫醇-烯聚合物的荧光太阳集光器制备及集光性能

Fabrication and Optical Efficiency of CsPbBr₃ Nanocrystals and Thiol-ene Polymer-based Luminescent Solar Concentrator