植物生长LED用Sr2MgAl22O36∶Mn4+荧光玻璃的制备与发光性质

杨茂林; 郑俊丽; 余丽萍; 廉世勋; 周文理

doi:10.37188/CJL.20210022

您当前的位置：

首页 >

文章列表页 >

植物生长LED用Sr₂MgAl₂₂O₃₆∶Mn⁴⁺荧光玻璃的制备与发光性质

发光学应用及交叉前沿 | 更新时间：2021-05-20

- 植物生长LED用Sr₂MgAl₂₂O₃₆∶Mn⁴⁺荧光玻璃的制备与发光性质
- Preparation and Luminescent Properties of Sr₂MgAl₂₂O₃₆∶Mn⁴⁺ Phosphor-in-glass for Plant Growth LED
- 发光学报 2021年42卷第5期页码：717-723
- 作者机构：
  
  湖南师范大学　化学化工学院，湖南　长沙　 410081
- 作者简介：
  
  [ "杨茂林(1995-)，女，重庆人，硕士研究生,2018年于重庆科技学院获得学士学位，主要从事荧光粉及荧光玻璃的研究。E-mail: 695256997@qq.com" ]
  [ "周文理(1982-)，男，湖南邵东人，博士，副教授,2012年于中山大学获得博士学位，主要从事照明与显示用无机发光材料的研究。E-mail: chemwlzhou@hunnu.edu.cn" ]
- 基金信息：
  
  国家重点研发计划(2016YFB0302403);国家自然科学基金(21501058)
- DOI：10.37188/CJL.20210022
  中图分类号： O482.31
- 收稿日期：2021-01-12，
  
  修回日期：2021-01-20，
  
  纸质出版日期：2021-05-01
- 稿件说明：
移动端阅览
杨茂林, 郑俊丽, 余丽萍, 等. 植物生长LED用Sr₂MgAl₂₂O₃₆∶Mn⁴⁺荧光玻璃的制备与发光性质[J]. 发光学报, 2021,42(5):717-723.

Mao-lin YANG, Jun-li ZHENG, Li-ping YU, et al. Preparation and Luminescent Properties of Sr₂MgAl₂₂O₃₆∶Mn⁴⁺ Phosphor-in-glass for Plant Growth LED[J]. Chinese journal of luminescence, 2021, 42(5): 717-723.
杨茂林, 郑俊丽, 余丽萍, 等. 植物生长LED用Sr₂MgAl₂₂O₃₆∶Mn⁴⁺荧光玻璃的制备与发光性质[J]. 发光学报, 2021,42(5):717-723. DOI： 10.37188/CJL.20210022.

Mao-lin YANG, Jun-li ZHENG, Li-ping YU, et al. Preparation and Luminescent Properties of Sr₂MgAl₂₂O₃₆∶Mn⁴⁺ Phosphor-in-glass for Plant Growth LED[J]. Chinese journal of luminescence, 2021, 42(5): 717-723. DOI： 10.37188/CJL.20210022.

摘要

采用两步烧结法低温制备了Sr

MgAl

∶Mn

-(SiO

-Al

-ZnO-BaO)荧光玻璃(SMA∶Mn

-PiG)。通过X射线衍射、扫描电镜、光致激发和发射光谱、荧光衰减曲线等手段对其物相、成分与发光性能进行了研究。实验结果表明，形成PiG后

SMA∶Mn

荧光粉的物相和元素组成保持不变。不同SAM∶Mn

含量的PiG样品在328 nm光激发下，在661 nm处均显示强的发射带，归属于荧光粉中Mn

的

E→

跃迁，发光光谱与植物光敏色素的红区吸收光谱匹配良好。随着荧光粉含量的增加

SAM∶Mn

-PiG的发光强度逐渐增大。15%SMA∶Mn

-PiG样品的内、外量子效率分别为26%和20%，低于SMA∶Mn

荧光粉的59%和40%。相比于SMA∶Mn

荧光粉，荧光玻璃的吸收效率和热稳定性略有提高。通过与高功率紫外芯片封装

SMA∶Mn

-PiG红光LED器件在100 mA驱动电流下展现了最高的电致发光强度。

Abstract

MgAl

∶Mn

-(SiO

-Al

-ZnO-BaO-B

) phosphor in glass(SMA∶Mn

-PiG) was prepared by a two-step co-sintering technology at low temperature. The phase

composition and luminescent properties of PiG samples were investigated by X-ray diffraction(XRD)

scanning electron microscope(SEM)

excitation and photoluminescence spectra

fluorescence decay curve

etc

. Experimental results show that the phase and elemental composition of SMA∶Mn

phosphor were well preserved after forming PiG. Under 328 nm excitation

PiG samples with different SAM∶Mn

content all showed strong emission band peaked at 661 nm due to

E→

transition of Mn

ions. The emission spectrum of SMA∶Mn

-PiG well matches absorption spectra of plant phytochromes. With the increase of phosphor content

the photoluminescence intensity of SAM∶Mn

-PiG gradually increases. Internal quantum efficiency(IQE) and external quantum efficiency(EQE) of 15% SMA∶Mn

-PiG samples are 26% and 20%

respectively

which are lower than 59% and 40% of SMA∶Mn

phosphor. Compared with SMA∶Mn

phosphor

absorption efficiency and thermal stability of SAM∶Mn

-PiG are slightly enhanced. With packaging with high-power UV chip

SMA∶Mn

-PiG red LED device exhibits high electroluminescence intensity

and the highest value is measured at 100 mA.

关键词

Keywords

references

AGARWAL A , GUPTA S D . Impact of light-emitting diodes(LEDs) and its potential on plant growth and development in controlled-environment plant production system [J]. Curr. Biotechnol. , 2016 , 5 ( 1 ): 28 - 43 .

ZHOU Z W , ZHENG J M , SHI R , et al. . Ab initio site occupancy and far-red emission of Mn4+ in cubic-phase La(MgTi)1/2O3 for plant cultivation [J]. ACS Appl. Mater. Interfaces , 2017 , 9 ( 7 ): 6177 - 6185 .

LUO X F , XIE R J . Recent progress on discovery of novel phosphors for solid state lighting [J]. J. Rare Earths , 2020 , 38 ( 5 ): 464 - 473 .

LI X M , ZHOU S S , WEI R F , et al. . Blue-green color-tunable emissions in novel transparent Sr2LuF7∶Eu/Tb glass-ceramics for WLEDs [J]. Chin. Opt. Lett. , 2020 , 18 ( 5 ): 051601 .

YANG Y G , WU F N , YU H J , et al. . Luminescent properties of Y3Al5O12∶Ce3+ phosphor-in-glass for WLEDs [J]. Optik , 2020 , 200 : 163455 .

NAM Y H , CHUNG W J , IM W B . Phosphor in glass using β-SiAlON∶Eu2+,CaAlSiN3∶Eu2+ and Nd-doped silicate glass for enhanced color gamut of white LED [J]. J. Alloys Compd. , 2021 , 851 : 156945 .

CHUNG W J , NAM Y H . Review—a review on phosphor in glass as a high power LED color converter [J]. ECS J. Solid State Sci. Technol. , 2020 , 9 ( 1 ): 016010-1-15 .

ZHENG P , LI S X , WANG L , et al. . Unique color converter architecture enabling phosphor-in-glass(PiG) films suitable for high-power and high-luminance laser-driven white lighting [J]. ACS Appl. Mater. Interfaces , 2018 , 10 ( 17 ): 14930 - 14940 .

CHEN D Q , XIANG W D , LIANG X J , et al. . Advances in transparent glass-ceramic phosphors for white light-emitting diodes—a review [J]. J. Eur. Ceram. Soc. , 2015 , 35 ( 3 ): 859 - 869 .

LEE J S , UNITHRATTIL S , KIM S , et al. . Robust moisture and thermally stable phosphor glass plate for highly unstable sulfide phosphors in high-power white light-emitting diodes [J]. Opt. Lett. , 2013 , 38 ( 17 ): 3298 - 3300 .

YOON C B , KIM S , CHOI S W , et al. . Highly improved reliability of amber light emitting diode with Ca-α-SiAlON phosphor in glass formed by gas pressure sintering for automotive applications [J]. Opt. Lett. , 2016 , 41 ( 7 ): 1590 - 1593 .

ZHANG Y , ZHANG X J , ZHANG H R , et al. . Enhanced absorption of Sr3Lu2(BO3)4∶Ce3+, Tb3+ phosphor with energy transfer for UV-pumped white LEDs [J]. J. Alloys Compd. , 2019 , 789 : 215 - 220 .

ZHANG R , LIN H , YU Y L , et al. . A new-generation color converter for high-power white LED:transparent Ce3+:YAG phosphor-in-glass [J]. Laser Photonics Rev. , 2014 , 8 ( 1 ): 158 - 164 .

PARK J Y , LEE W C , CHUNG J W , et al. . Phosphor-in-glass(PiG) plates for blue laser diode driven white-light emission [J]. J. Alloys Compd. , 2020 , 842 : 155922 .

LI H , WANG P , ZHUO Y , et al. . Mapping the glass forming region and making their phosphor-in-glass for application in W-LEDs packaging [J]. J. Am. Ceram. Soc. , 2020 , 103 ( 9 ): 5056 - 5066 .

WANG B , LIN H , HUANG F , et al. . Non-rare-earth BaMgAl10-2xO17∶xMn4+,xMg2+:a narrow-band red phosphor for use as a high-power warm w-LED [J]. Chem. Mater. , 2016 , 28 ( 10 ): 3515 - 3524 .

DENG J K , ZHANG H R , ZHANG X J , et al. . Ultrastable red-emitting phosphor-in-glass for superior high-power artificial plant growth LEDs [J]. J. Mater. Chem. C , 2018 , 6 ( 7 ): 1738 - 1745 .

XIANG J M , ZHOU Z W , ZHENG J M , et al. . Red phosphors A2GdNbO6∶Mn4+ (A=Ca,Sr,Ba) for plant growth LEDs with Emerson enhancement effect [J]. Opt. Mater. , 2020 , 109 : 110344 .

CAO R P , PENG M Y , SONG E H , et al. . High efficiency Mn4+ doped Sr2MgAl22O36 red emitting phosphor for white LED [J]. ECS J. Solid State Sci. Technol. , 2012 , 1 ( 4 ): R123 - R126 .

ARORA A , GOEL A , SHAABAN E R , et al. . Crystallization kinetics of BaO-ZnO-Al2O3-B2O3-SiO2 glass [J]. Phys. B Condens. Matter , 2008 , 403 ( 10-11 ): 1738 - 1746 .

ARORA A , SINGH K , PANDEY O P , et al. . Thermal, structural and crystallization kinetics of SiO2-BaO-ZnO-B2O3-Al2O3 glass samples as a sealant for SOFC [J]. Int. J. Hydrogen Energy , 2011 , 36 ( 22 ): 14948 - 14955 .

ZHANG H M , ZHANG H R , ZHUANG J L , et al. . Effect of H3BO3 flux on the morphology and optical properties of Sr2MgAl22O36∶Mn4+ red phosphors for agricultural light conversion films [J]. Ceram. Int. , 2016 , 42 ( 11 ): 13011 - 13017 .

ZHANG X J , YU J B , WANG J , et al. . Facile preparation and ultrastable performance of single-component white-light-emitting phosphor-in-glass used for high-power warm white LEDs [J]. ACS Appl. Mater. Interfaces , 2015 , 7 ( 51 ): 28122 - 28127 .

ZHU Q Q , XU X , WANG L , et al. . A robust red-emitting phosphor-in-glass(PiG) for use in white lighting sources pumped by blue laser diodes [J]. J. Alloys Compd. , 2017 , 702 : 193 - 198 .

浏览量

204

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

Mn⁴⁺激活氟化物荧光粉水解劣化评价方法

主发射波长大于631 nm的Mn⁴⁺激活氟化物荧光粉

激光照明应用MgO-La₃Si₆N₁₁∶Ce³⁺复合荧光玻璃的制备及性能优化

Ca₂MgTeO₆∶Bi³⁺, Mn⁴⁺材料的发光性能和温度探测