红色荧光粉Sr3LiSbO6∶Eu3+制备及其发光性质

彭晓; 阳维维; 凌东雄; 吕伟

doi:10.37188/CJL.20200371

您当前的位置：

首页 >

文章列表页 >

红色荧光粉Sr₃LiSbO₆∶Eu³⁺制备及其发光性质

材料合成及性能 | 更新时间：2021-04-23

- 红色荧光粉Sr₃LiSbO₆∶Eu³⁺制备及其发光性质
- Preparation and Luminescence Properties of Red Sr₃LiSbO₆∶Eu³⁺ Phosphor
- 发光学报 2021年42卷第4期页码：455-461
- 作者机构：
  
  1.深圳大学物理与光电工程学院，广东　深圳　 518060
  2.东莞理工学院电子工程与智能化学院，广东　东莞　 523808
- 作者简介：
  
  [ "彭晓(1979-)，女，江苏淮安人，博士，副教授，2007年于中国香港理工大学获得博士学位，主要从事生物光子学领域的探针开发及生物应用的研究。E-mail: pengxiaopx@szu.edu.cn" ]
  [ "吕伟(1984-)，男，吉林汪清人，博士，副研究员，2012年于中国科学院长春光学精密机械与物理研究所获得博士学位，主要从事LED用发光材料的研究。E-mail: lvweiluwei@163.com" ]
- 基金信息：
  
  国家自然科学基金面上项目(31771584;51772287);深圳市基础研究项目(JCYJ20170818100153423);深圳大学高端人才科研启动项目(2017000193)
- DOI：10.37188/CJL.20200371
  中图分类号： O482.31
- 收稿日期：2020-12-05，
  
  修回日期：2021-01-13，
  
  纸质出版日期：2021-04-01
- 稿件说明：
移动端阅览
彭晓, 阳维维, 凌东雄, 等. 红色荧光粉Sr₃LiSbO₆∶Eu³⁺制备及其发光性质[J]. 发光学报, 2021,42(4):455-461.

Xiao PENG, Wei-wei YANG, Dong-xiong LING, et al. Preparation and Luminescence Properties of Red Sr₃LiSbO₆∶Eu³⁺ Phosphor[J]. Chinese journal of luminescence, 2021, 42(4): 455-461.
彭晓, 阳维维, 凌东雄, 等. 红色荧光粉Sr₃LiSbO₆∶Eu³⁺制备及其发光性质[J]. 发光学报, 2021,42(4):455-461. DOI： 10.37188/CJL.20200371.

Xiao PENG, Wei-wei YANG, Dong-xiong LING, et al. Preparation and Luminescence Properties of Red Sr₃LiSbO₆∶Eu³⁺ Phosphor[J]. Chinese journal of luminescence, 2021, 42(4): 455-461. DOI： 10.37188/CJL.20200371.

摘要

采用高温固相法制备了Sr

LiSbO

∶Eu

(SLSO∶Eu

)红色荧光粉。系统研究了Eu

浓度对发光强度的影响，并对样品进行了XRD、荧光光谱(PL)、荧光寿命、热稳定性和色坐标分析。结果表明，制备的荧光粉Sr

LiSbO

∶Eu

可被紫外光激发，并在612 nm处表现出较强的红光发射带。研究了样品的浓度猝灭效应，样品的最佳掺杂浓度为0.04%，猝灭主要是因为偶极-偶极相互作用引起的。此外，还探讨了样品的热稳定性，在423 K时的发光强度为室温下的43.1%。最后对样品的荧光寿命和CIE进行了测试。以上结果表明制备的荧光粉Sr

LiSbO

∶Eu

是一种新型LED红色荧光材料。

Abstract

LiSbO

∶Eu

red phosphors were synthesized by high temperature state reaction. The influence of Eu

concentration on the luminous intensity was systematically studied

and the samples were analyzed by XRD

fluorescence spectroscopy(PL)

fluorescence lifetime

thermal stability and color coordinates. The results show that the prepared phosphor Sr

LiSbO

∶Eu

can be excited by ultraviolet light and exhibits a strong red light emission band at 612 nm. The concentration quenching effect of the sample was studied

and the best doping concentration of the sample was 0.04%

which was mainly caused by the dipole-dipole interaction. In addition

the thermal stability of the sample was also discussed. The luminous intensity at 423 K was 43.1% of that at room temperature. Finally

the fluorescence lifetime and CIE of the samples were tested. The above results indicate that the prepared phosphor Sr

LiSbO

∶Eu

has great prospects in the synthesis of LEDs.

关键词

Keywords

references

LI K , SHANG M M , LIAN H Z , et al . Recent development in phosphors with different emitting colors via energy transfer [J]. J. Mater. Chem. C , 2016 , 4 ( 24 ): 5507 - 5530 .

XIA Z G , LIU Q L . Progress in discovery and structural design of color conversion phosphors for LEDs [J]. Prog. Mater. Sci. , 2016 , 84 : 59 - 117 .

ZHOU Z , ZHOU N , XIA M , et al . Research progress and application prospects of transition metal Mn4+-activated luminescent materials [J]. J. Mater. Chem. C , 2016 , 4 ( 39 ): 9143 - 9161 .

胡盼，丁慧，刘永福，等 . YAG:Ce3+在激光照明应用中的研究进展 [J]. 发光学报， 2020 ， 41 ( 12 ): 1504 - 1528 .

HU P , DING H , LIU Y F , et al . Recent progress of YAG:Ce3+ for white laser diode lighting application [J]. Chin. J. Lumin. , 2020 , 41 ( 12 ): 1504 - 1528 . (in Chinses)

XIA Z G , XU Z H , CHEN M Y , et al . Recent developments in the new inorganic solid-state LED phosphors [J]. Dalton Trans. , 2016 , 45 ( 28 ): 11214 - 11232 .

ZHONG J S , CHEN D Q , YUAN S , et al . Tunable optical properties and enhanced thermal quenching of non-rare-earth double-perovskite (Ba1-xSrx)2YSbO6:Mn4+ red phosphors based on composition modulation [J]. Inorg. Chem. , 2018 , 57 ( 15 ): 8978 - 8987 .

LI Y Q , VAN STEEN J E J , VAN KREVEL J W H , et al . Luminescence properties of red-emitting M2Si5N8:Eu2+(M= Ca, Sr, Ba) LED conversion phosphors [J]. J. Alloys Compd. , 2006 , 417 ( 1-2 ): 273 - 279 .

陈磊，林金填，邱镇民，等 . M2-xSi5N8:xEu(M=Ca，Sr，Ba)荧光粉的结构、发光和热猝灭性能 [J]. 照明工程学报， 2019 ， 30 ( 3 ): 91 - 95 .

CHEN L , LIN J T , QIU Z M , et al . Structure, luminescence and thermal quenching properties of M2-xSi5N8:xEu(M=Ca, Sr, Ba) phosphors [J]. Chin. Illumin. Eng. J. , 2019 , 30 ( 3 ): 91 - 95 . (in Chinses)

赵芳仪，刘小浪，宋振，等 . 超高显色指数、全光谱白光LED封装技术 [J]. 照明工程学报， 2019 ， 30 ( 3 ): 75 - 80 .

ZHAO F Y , LIU X L , SONG Z , et al . Packaging technology for ultra-high color rendering index and full spectrum white LED [J]. Chin. Illumin. Eng. J. , 2019 , 30 ( 3 ): 75 - 80 . (in Chinese)

ZHONG J S , LI J N , LIU M J , et al . Novel cyan-emitting KBaScSi2O7:Eu2+ phosphors with ultrahigh quantum efficiency and excellent thermal stability for WLEDs [J]. J. Am. Ceram. Soc. , 2019 , 102 ( 12 ): 7376 - 7385 .

刘春旭 . La1.6(MoO4)3: <math><mrow><msubsup><mrow><mtext>Eu</mtext></mrow><mrow><mn>0.4</mn></mrow><mrow><mn>3</mn><mo>+</mo></mrow></msubsup></mrow></math> 纳米晶合成及发光特性 [J]. 中国光学 , 2014 , 7 ( 6 ): 931 - 935 .

LIU C X . Synthesis and luminescence properties of La1.6(MoO4)3:Eu3+ nanocrystal [J]. Chin. Opt. , 2014 , 7 ( 6 ): 931 - 935 . (in Chinese)

张家骅，吕伟，郝振东，等 . 利用能量传递实现可调全色单一白光BaMg2Al6Si9O30:Eu2+，Tb3+，Mn2+荧光粉(特邀) [J]. 中国光学， 2012 ， 5 ( 3 ): 203 - 208 .

ZHANG J H , LÜ W , HAO Z D , et al . Color-tunable white-light emitting BaMg2Al6Si9O30:Eu2+, Tb3+, Mn2+ phosphors via energy transfer(Invited) [J]. Chin. Opt. , 2012 , 5 ( 3 ): 203 - 208 . (in Chinese)

孙建红，眭慧东，王紫薇，等 . 铕掺杂纳米二氧化钛透明光触媒乳液的制备及光催化性能研究 [J]. 中国光学， 2017 ， 10 ( 6 ): 760 - 767 .

SUN J H , SUI H D , WANG Z W , et al . Preparation of europium-doped nano-TiO2 transparent photocatalyst emulsion and photocatalytic performance [J]. Chin. Opt. , 2017 , 10 ( 6 ): 760 - 767 . (in Chinese)

孙雷，张毅，胡兴凯，等 . LED用KZn4(BO3)3:Eu3+荧光粉的合成与发光性能研究 [J]. 液晶与显示， 2014 ， 29 ( 6 ): 893 - 900 .

SUN L , ZHANG Y , HU X K , et al . Synthesis and photoluminescence properties of KZn4(BO3)3:Eu3+ red-emitting phosphor [J]. Chin. J. Liq. Cryst. Disp. , 2014 , 29 ( 6 ): 893 - 900 . (in Chinese)

赵文倩，张映辉，付少博，等 . Eu3+掺杂硼酸银玻璃制备、表征及其在白光发光二极管中的应用 [J]. 光学精密工程， 2015 ， 23 ( 10 ): 173 - 178 .

ZHAO W Q , ZHANG Y H , FU S B , et al . Preparation and characterization of Eu3+ doped silver borate glasses and their applications in white light emitting diodes [J]. Opt. Precision Eng. , 2015 , 23 ( 10 ): 173 - 178 . (in Chinese)

DU P , GUO Y , LEE S H , et al . Broad near-ultraviolet and blue excitation band induced dazzling red emissions in Eu3+-activated Gd2MoO6 phosphors for white light-emitting diodes [J]. RSC Adv. , 2017 , 7 ( 6 ): 3170 - 3178 .

ZHONG J S , XU M , CHEN D Q , et al . Novel red-emitting Sr2LaSbO6:Eu3+ phosphor with enhanced 5D0→7F4 transition for warm white light-emitting diodes [J]. Dyes Pigm. , 2017 , 146 : 272 - 278 .

GENG X , XIE Y , MA Y Y , et al . Abnormal thermal quenching and application for w-LEDs:double perovskite Ca2InSbO6:Eu3+ red-emitting phosphor [J]. J. Alloys Compd. , 2020 , 847 : 156249 .

LIU Q , WANG L X , HUANG W T , et al . Thermally stable double perovskite CaLaMgSbO6:Eu3+ phosphors as a tunable LED-phosphor material [J]. Ceram. Int. , 2018 , 44 ( 2 ): 1662 - 1667 .

ZHANG Z J , SUN L L , DEVAKUMAR B , et al . Novel highly luminescent double-perovskite Ca2GdSbO6:Eu3+ red phosphors with high color purity for white LEDs:synthesis, crystal structure, and photoluminescence properties [J]. J. Lumin. , 2020 , 221 : 117105 .

BHARATHY M , ZUR LOYE H C . Crystal growth of A3A'MO6 oxides [J]. J. Chem. Crystallogr. , 2010 , 40 ( 11 ): 945 - 949 .

XIA Z G , ZHOU J , MAO Z Y . Near UV-pumped green-emitting Na3(Y, Sc)Si3O9:Eu2+ phosphor for white-emitting diodes [J]. J. Mater. Chem. C , 2013 , 1 ( 37 ): 5917 - 5924 .

LIU M J , SHEN B , WANG K Y , et al . Highly efficient red-emitting Ca2YSbO6:Eu3+ double perovskite phosphors for warm WLEDs [J]. RSC Adv. , 2019 , 9 ( 36 ): 20742 - 20748 .

LI X H , MILIĆEVIĆ B , DRAMIĆANIN M D , et al . Eu3+-activated Sr3ZnTa2O9 single-component white light phosphors:emission intensity enhancement and color rendering improvement [J]. J. Mater. Chem. C , 2019 , 7 ( 9 ): 2596 - 2603 .

CHENG Q , REN F Q , LIN Q , et al . High quantum efficiency red emitting α-phase La2W2O9:Eu3+ phosphor [J]. J. Alloys Compd. , 2019 , 772 : 905 - 911 .

LI M L , XIA Z G , WANG Z Y . Color-tunable emission and energy transfer studies in GdOBr:Ce3+ Dy3+ phosphor [J]. Opt. Mater. , 2014 , 37 : 446 - 450 .

LIANG J , SUN L L , DEVAKUMAR B , et al . Novel Mn4+-activated LiLaMgWO6 far-red emitting phosphors:high photoluminescence efficiency, good thermal stability, and potential applications in plant cultivation LEDs [J]. RSC Adv. , 2018 , 8 ( 48 ): 27144 - 27151 .

ZHUO Y , HARIYANI S , ARMIJO E , et al . Evaluating thermal quenching temperature in Eu3+-substituted oxide phosphors via machine learning [J]. ACS Appl. Mater. Interfaces , 2020 , 12 ( 5 ): 5244 - 5250 .

CHEN H , LIN H , HUANG Q M , et al . A novel double-perovskite Gd2ZnTiO6:Mn4+ red phosphor for UV-based w-LEDs:structure and luminescence properties [J]. J. Mater. Chem. C , 2016 , 4 ( 12 ): 2374 - 2381 .

MIN X , SUN Y K , KONG L T , et al . Novel pyrochlore-type La2Zr2O7:Eu3+ red phosphors:synthesis, structural, luminescence properties and theoretical calculation [J]. Dyes Pigm. , 2018 , 157 : 47 - 54 .

XIA M , WU X B , ZHONG Y , et al . A novel Na3La(PO4)2/LaPO4:Eu blue-red dual-emitting phosphor with high thermal stability for plant growth lighting [J]. J. Mater. Chem. C , 2019 , 7 ( 8 ): 2385 - 2393 .

ZHU G , CI Z P , SHI Y R , et al . Synthesis, crystal structure and luminescence characteristics of a novel red phosphor Ca19-Mg2(PO4)14:Eu3+ for light emitting diodes and field emission displays [J]. J. Mater. Chem. C , 2013 , 1 ( 37 ): 5960 - 5969 .

WU Y F , NIEN Y T , WANG Y J , et al . Enhancement of photoluminescence and color purity of CaTiO3:Eu phosphor by Li doping [J]. J. Am. Ceram. Soc. , 2012 , 95 ( 4 ): 1360 - 1366 .

浏览量

655

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

一种新型的白光LED用绿色荧光粉Ca₈MgLu(PO₄)₇:Tb³⁺

Zn²⁺掺杂MgGa₂O₄∶Ni²⁺近红外二区发光材料制备、表征及其成像应用研究

杂质Mn⁴⁺发光中心相关的Mg₇Ga₂GeO₁₂∶Tb³⁺多色荧光粉发光性能

Sr₂InP₃O₁₁∶Eu³⁺红色荧光粉的发光性能及占位影响