用于白光LED的GGAG∶Ce复合荧光膜制备和性能

张伟杰; 魏钦华; 唐高; 陈振华; 秦来顺

doi:10.37188/CJL.20200358

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用于白光LED的GGAG∶Ce复合荧光膜制备和性能

材料合成及性能 | 更新时间：2021-04-23

- 用于白光LED的GGAG∶Ce复合荧光膜制备和性能
- Preparation and Properties of GGAG∶Ce Composite Fluorescent Film for White LED
- 发光学报 2021年42卷第4期页码：478-485
- 作者机构：
  
  中国计量大学材料与化学学院，浙江　杭州　 310018
- 作者简介：
  
  [ "张伟杰(1993-)，男，江苏淮安人，硕士研究生，2016年于南通大学获得学士学位，主要从事GGAG∶Ce复合材料的制备及发光性能的研究。E-mail: 1216248705@qq.com" ]
  [ "魏钦华(1985-)，男，浙江宁波人，博士，副教授，硕士研究生导师，2014年于中国科学院上海硅酸盐研究所获得博士学位，主要从事闪烁晶体生长和发光材料的研究。E-mail:weiqinhua1985@163.com" ]
- 基金信息：
  
  国家自然科学基金(11975220;51972291)
- DOI：10.37188/CJL.20200358
  中图分类号： TN312.8;O482.31
- 纸质出版日期：2021-04-01，
  
  收稿日期：2020-11-25，
  
  修回日期：2020-12-24，
- 稿件说明：
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张伟杰, 魏钦华, 唐高, 等. 用于白光LED的GGAG∶Ce复合荧光膜制备和性能[J]. 发光学报, 2021,42(4):478-485.

WEI-JIE ZHANG, QIN-HUA WEI, GAO TANG, et al. Preparation and Properties of GGAG∶Ce Composite Fluorescent Film for White LED. [J]. Chinese journal of luminescence, 2021, 42(4): 478-485.
张伟杰, 魏钦华, 唐高, 等. 用于白光LED的GGAG∶Ce复合荧光膜制备和性能[J]. 发光学报, 2021,42(4):478-485. DOI： 10.37188/CJL.20200358.

WEI-JIE ZHANG, QIN-HUA WEI, GAO TANG, et al. Preparation and Properties of GGAG∶Ce Composite Fluorescent Film for White LED. [J]. Chinese journal of luminescence, 2021, 42(4): 478-485. DOI： 10.37188/CJL.20200358.

摘要

白光LED由于发光效率高、寿命长以及节能环保等优点，已逐渐成为照明行业的主流产品。通常照明用白光LED要求高显色指数和低色温。本文采用Gd

(Al

Ga)

∶Ce (GGAG∶Ce)作为发光粉体、硅胶作为基质材料成功制备了可用于封装白光LED的具有一定透明度的GGAG∶Ce柔性复合荧光膜。通过X射线衍射(XRD)、荧光光谱、扫描电子显微镜(SEM)、变温荧光光谱等手段分析了复合荧光膜的物相、形貌及发光性能。结果表明，该柔性复合荧光膜的主晶相为GGAG∶Ce晶相，荧光膜表面平整度较好、柔性较好。GGAG∶Ce复合荧光膜的主激发峰和发射峰分别位于450 nm和540 nm左右，属于Ce

的5d→4f电子跃迁发光，衰减时间约为40 ns左右。荧光性能表明，复合荧光膜的最佳复合浓度为20%左右，其显色指数达到85.1，色温为6 295 K。变温荧光光谱表明，复合荧光膜具有较好的热稳定性，在白光LED中具有潜在的应用前景。

Abstract

White LED has gradually become a mainstream product in the lighting industry due to its high luminous efficiency

long life

energy saving and environmental protection. Generally

white light LEDs for lighting are required to have high color rendering index and low color temperature. In this paper

the GGAG∶Ce nano-powder was synthesized by chemical co-precipitation method. And the translucent Gd

(Al

Ga)

∶Ce (GGAG∶Ce) flexible composite fluorescent film was prepared successfully by uniformly dispersing the GGAG∶Ce nano-powder into the silica gel matrix

which can be used for white light LEDs. The phase construct

morphology and luminescence properties of the composite fluorescent film were discussed by X-ray diffraction(XRD)

fluorescence spectroscopy

scanning electron microscope(SEM)

and variable temperature fluorescence spectroscopy. The results show that the main crystal phase of composite fluorescent film is GGAG∶Ce crystal phase. The main excitation peak and emission wavelength of the GGAG∶Ce composite fluorescent film are located at 450 nm and 540 nm

respectively

which belong to the 5d → 4f electronic transition of Ce

and the decay time is about 40 ns. Fluorescence performance shows that the optimal composite concentration of the composite fluorescent film is about 20%

its color rendering index reaches 85.1

and its color temperature is 6 295 K. The variable temperature emission spectra present the composite fluorescent film has a good thermostability

which has potential application prospects in white LEDs.

关键词

GGAG∶Ce复合荧光膜白光LED显色指数

Keywords

GGAG∶Cecomposite fluorescent filmwhite LEDcolor rendering index

references

PEAKER A R. Efficiency peaking in red-light-emitting gallium-phosphide diodes [J].Electron. Lett., 1969, 5(9):186-187.

PANKOVE J I, MILLER E A, BERKEYHEISER J E. GaN yellow-light emitting diodes [J].J. Lumin., 1973, 6(1):54-60.

NAKAMURA S, MUKAI T, SENOH M. Candela-class high-brightness InGaN/AlGaN double-heterostructure blue-light-emitting diodes [J].Appl. Phys. Lett., 1994, 64(13):1687-1689.

LEIST J R. The blue laser diode:GaN based light emitters and lasers, by Shuji Nakamura and Gerhard Fasol [J].Opt. Photonics News, 1997, 8(12):53.

KRAMES M R, SHCHEKIN O B, MUELLER-MACH R, et al. Status and future of high-power light-emitting diodes for solid-state lighting [J].J. Disp. Technol., 2007, 3(2):160-175.

唐靓，叶慧琪，肖东. 溶胶-凝胶法制备YAG:Ce，Yb纳米荧光粉及其发光性质研究 [J].发光学报，2018，39(8):1051-1058.

TANG L, YE H Q, XIAO D. YAG:Ce, Yb nano-phosphor synthesized by sol-gel method and its luminescence properties [J].Chin. J. Lumin., 2018, 39(8):1051-1058. (in Chinese)

SCHUBERT E F, KIM J K. Solid-state light sources getting smart [J].Science, 2005, 308(5726):1274-1278.

LEE M J, PARK S H, SONG Y H, et al. Fabrication of phosphor ceramic plate using green-emitting Lu3Al5O12:Ce3+ phosphor for high power LEDs [J].Mater. Lett., 2015, 161:708-711.

沈雪华，陈焕庭，陈赐海，等. 白光LED光谱特性及司辰节律因子 [J].发光学报，2019，40(12):1514-1522.

SHEN X H, CHEN H T, CHEN C H, et al. Spectral characteristics and circadian action factor of white LEDs [J].Chin. J. Lumin., 2019, 40(12):1514-1522. (in Chinese)

李嘉祥，潘拴，刘军林，等. 低色温无荧光粉LED光源的可靠性研究 [J].发光学报，2020，41(3):323-330.

LI J X, PAN S, LIU J L, et al. Reliability of low color temperature phosphor-free LED light source [J].Chin. J. Lumin., 2020, 41(3):323-330. (in Chinese)

孟猛，祁强，丁栋舟，等. 新型闪烁晶体Gd3(Al，Ga)5O12:Ce3+的研究进展 [J].人工晶体学报，2019，48(8):1386-1394.

MENG M, QI Q, DING D Z, et al. Research progress on novel scintillation crystal Gd3(Al, Ga)5O12:Ce3+ [J].J. Synth. Cryst., 2019, 48(8):1386-1394. (in Chinese)

徐兰兰，孙丛婷，薛冬峰. 稀土闪烁晶体研究进展 [J].中国科学:技术科学，2016，46(7):657-673.

XU L L, SUN C T, XUE D F. Recent advances in rare earth scintillation crystals [J].Chin. Sci.:Technol. Sci., 2016, 46(7):657-673. (in Chinese)

张烨，陈先强，秦海明，等. 共沉淀法制备Ce掺杂的Gd3(Al，Ga)5O12粉体 [J].无机材料学报，2016，31(10):1151-1155.

ZHANG Y, CHEN X Q, QIN H M, et al. Fabrication of Ce-doped Gd3(Al, Ga)5O12 powders using co-precipitation method [J].J. Inorg. Mater., 2016, 31(10):1151-1155. (in Chinese)

KANG J G, KIM M K, KIM K B. Preparation and luminescence characterization of GGAG:Ce3+, B3+ for a white light-emitting diode [J].Mater. Res. Bull., 2008, 43(8-9):1982-1988.

ZHANG J Y, LUO Z H, JIANG H C, et al. A novel banded structure ceramic phosphor for high-power white LEDs [J].Chem. Commun., 2017, 53(50):6772-6775.

KITAURA M, SATO A, KAMADA K, et al. Phosphorescence of Ce-doped Gd3Al2Ga3O12 crystals studied using luminescence spectroscopy [J].J. Appl. Phys., 2014, 115(8):083517.

WEI Q H, ZHUANG J D, LIU G H, et al. Preparation and luminescence properties of SiO2/Lu2Si2O7:Ce composite starting from mesopore template [J].RSC Adv., 2014, 4(64):33819-33825.

FELLER R K, PURDY G M, ORTIZ-ACOSTA D, et al. Large-scale synthesis of CexLa1-xF3 nanocomposite scintillator materials [J].J. Mater. Chem. C, 2011, 21(15):5716-5722.

LAWRENCE W G, THACKER S, PALAMAKUMBURA S, et al. Quantum dot-organic polymer composite materials for radiation detection and imaging [J].IEEE Trans. Nucl. Sci., 2012, 59(1):215-221.

SEN S, TYAGI M, SHARMA K, et al. Organic-inorganic composite films based on Gd3Ga3Al2O12:Ce scintillator nanoparticles for X-ray imaging applications [J].ACS Appl. Mater. Interfaces, 2017, 9(42):37310-37320.

ZHAO G J, LI T, HE X M, et al. Preparation of gadolinium gallium garnet polycrystalline material by coprecipitation method [J].Mater. Lett., 2002, 56(6):1098-1102.

NISHIURA S, TANABE S, FUJIOKA K, et al. Preparation and optical properties of transparent Ce:YAG ceramics for high power white LED [J].IOP Conf. Ser.:Mater. Sci. Eng., 2009, 1:012031-1-5.

冯大建，丁雨憧，刘军，等. Ce:GAGG闪烁晶体生长与性能研究 [J].压电与声光，2016，38(3):430-432.

FENG D J, DING Y C, LIU J, et al. Study on the growth and scintillation properties of Ce:GAGG crystal [J].Piezoelectr. Acoustoopt., 2016, 38(3):430-432. (in Chinese)

LUO Z H, JIANG H C, JIANG J, et al. Microstructure and optical characteristics of Ce:Gd3(Ga, Al)5O12 ceramic for scintillator application [J].Ceram. Int., 2015, 41(1):873-876.

ZHONG J, CHEN D Q, ZHOU Y, et al. Stable and chromaticity-tunable phosphor-in-glass inorganic color converter for high-power warm white light-emitting diode [J].J. Eur. Ceram. Soc., 2016, 36(7):1705-1713.

YANG C, LIANG X J, DI X X, et al. Facile fabrication and luminescence characteristics of Ce:YAG phosphor glass thick films coated on a glass substrate for white LEDs [J].Ceram. Int., 2016, 42(13):14526-14532.

DI X X, HE X L, JIANG J T, et al. Facile fabrication of Eu3+ activated YAG:Ce3+ glass ceramics exhibiting high thermal stability and tunable luminescence for warm white LEDs [J].J. Mater. Sci.:Mater. Electron., 2017, 28(12):8611-8620.

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