基于上转换荧光粉的紫外光源设计

陈凤; 陈璐; 刘峰; 张亮亮; 武华君; 吴昊; 王笑军; 张家骅

doi:10.37188/CJL.20200347

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基于上转换荧光粉的紫外光源设计

封面文章 | 更新时间：2021-02-08

- 基于上转换荧光粉的紫外光源设计
- Upconverting Phosphor-based Ultraviolet Light Source
- 发光学报 2021年42卷第2期页码：131-135
- 作者机构：
  
  1.东北师范大学紫外光发射材料与器件教育部重点实验室, 吉林长春 130024
  2.中国科学院长春光学精密机械与物理研究所发光学及应用国家重点实验室, 吉林长春 130033
  3.Department of Physics, Georgia Southern University, Statesboro, GA 30460, USA
- 作者简介：
  
  [ "陈凤(1997-), 女, 吉林四平人, 硕士研究生, 2019年于东北师范大学获得学士学位, 主要从事紫外发光材料的合成和表征的研究。E-mail:chenf484@nenu.edu.cn" ]
  [ "刘峰(1978-), 男, 吉林长春人, 博士, 教授, 2007年于中国科学院长春光学精密机械与物理研究所获得博士学位, 主要从事发光材料与物理方面的研究。E-mail:fengliu@nenu.edu.cn" ]
  [ "张家骅(1965-), 男, 黑龙江呼兰人, 博士, 研究员, 1997年于中国科学院长春物理研究所获得博士学位, 主要从事发光材料与物理方面的研究。E-mail:zhangjh@ciomp.ac.cn" ]
- 基金信息：
  
  吉林省科技发展计划国际科技合作项目(20180414082GH);国家自然科学基金(11774046);国家自然科学基金(11874055);国家自然科学基金(11974346);国家自然科学基金(12074373)
- DOI：10.37188/CJL.20200347
  中图分类号：
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陈凤, 陈璐, 刘峰, 等. 基于上转换荧光粉的紫外光源设计[J]. 发光学报, 2021,42(2):131-135.

Feng CHEN, Lu CHEN, Feng LIU, et al. Upconverting Phosphor-based Ultraviolet Light Source[J]. Chinese Journal of Luminescence, 2021,42(2):131-135.
陈凤, 陈璐, 刘峰, 等. 基于上转换荧光粉的紫外光源设计[J]. 发光学报, 2021,42(2):131-135. DOI： 10.37188/CJL.20200347.

Feng CHEN, Lu CHEN, Feng LIU, et al. Upconverting Phosphor-based Ultraviolet Light Source[J]. Chinese Journal of Luminescence, 2021,42(2):131-135. DOI： 10.37188/CJL.20200347.

摘要

提到荧光粉光转化（Phosphor-converted，PC）类型的光源，人们熟悉的是白光照明或近红外波段的光源，而对紫外波段PC光源的概念比较陌生。本文基于蓝光激发的上转换发光现象，提出了一个新型PC紫外光源的概念。首先选取Lu,2,Pr,0.01,Gd,0.99,Al,2,Ga,3,O,12,上转换荧光粉为展示材料，该材料在450 nm激光辐照下发射位于313 nm的紫外线。随后，采用刮涂工艺将该荧光粉材料制备成荧光陶瓷薄膜。通过蓝光远程激发荧光粉层的方法对荧光薄膜的紫外发射进行了成像演示。目前来看，尽管这个PC设计的光转换效率并不高，但光谱和成像实验显示了其作为紫外光源的可行性。该设计可以为明亮环境下的紫外示踪或指示等应用提供选择。

Abstract

When it mentions phosphor-converted(PC) light source, people would think of white or near-infrared light sources. In contrast, attention on the PC light sources at the other end of the spectrum-the shorter-wavelength ultraviolet region is absent. Taking into account the potential applications of ultraviolet light, the investigation of PC design as an alternative ultraviolet light source will be interesting. Here we introduce a concept of ultraviolet PC light source, in which the ultraviolet emission can be achieved upon a blue-light upconversion excitation. As a proof of concept, we demonstrate the PC design using an ultraviolet-B phosphor, Lu,2,Pr,0.01,Gd,0.99,Al,2,Ga,3,O,12,. Upconversion emission at 313 nm appears from the phosphor upon illumination with a 450 nm laser. Subsequently, we prepare a composite film using the phosphor, and build a transmissive remote phosphor light source. According to the emission and excitation features of the PC light source, we present an ultraviolet imaging demonstration. This study brings the PC light source to the ultraviolet region, which may offer a unique opportunity for some applications of optical tagging or indicator in bright environments.

关键词

荧光粉光转化PC紫外光源Pr3+离子上转换Gd3+发射荧光陶瓷薄膜

Keywords

phosphor-converted(PC)PC ultraviolet light sourceupconversion of Pr3+emission of Gd3+phosphor composition film

references

刘行仁.白光LED固态照明光转换荧光体[J].发光学报, 2007, 28(3):291-301.

LIU X R. Phosphors for white LED solid state lighting[J].Chin. J. Lumin., 2007, 28(3):291-301. (in Chinese)

LIN C C, LIU R S. Advances in phosphors for light-emitting diodes[J].J. Phys. Chem. Lett., 2011, 2(11):1268-1277.

XIA Z G, XU Z H, CHEN M Y, et al.. Recent developments in the new inorganic solid-state LED phosphors[J].Dalton Trans., 2016, 45(28):11214-11232.

刘峰, 潘正伟, 张家骅, 等.基于荧光粉光转换的白光LED固态照明[J].中国稀土学报, 2017, 35(2):171-182.

LIU F, PAN Z W, ZHANG J H, et al.. White LED-based solid state lighting using phosphors as spectral converters[J].J. Chin. Soc. Rare Earths, 2017, 35(2):171-182. (in Chinese)

解荣军, 李淑星.氮化物荧光粉的前世今生:材料探索和应用的新启示[J].发光学报, 2020, 41(6):646-650.

XIE R J, LI S X. Past and present of nitride phosphors:new inspirations on materials discovery and applications[J].Chin. J. Lumin., 2020, 41(6):646-650. (in Chinese)

RAJENDRAN V, CHANG H, LIU R S. (Invited)Recent progress on broadband near-infrared phosphors-converted light emitting diodes for future miniature spectrometers[J].J. Phys. Chem. Lett., 2019, 2(11):1268-1277.

ZHANG L L, WANG D D, HAO Z D, et al.. Cr3+-doped broadband NIR garnet phosphor with enhanced luminescence and its application in NIR spectroscopy[J].Adv. Opt. Mater., 2019, 7(12):1900185-1-8.

张亮亮, 张家骅, 郝振东, 等. Cr3+掺杂的宽带近红外荧光粉及其研究进展[J].发光学报, 2019, 40(12):1449-1459.

ZHANG L L, ZHANG J H, HAO Z D, et al.. Recent progress on Cr3+ doped broad band NIR phosphors[J].Chin. J. Lumin., 2019, 40(12):1449-1459. (in Chinese)

QIAO J W, ZHOU G J, ZHOU Y Y, et al.. Divalent europium-doped near-infrared-emitting phosphor for light-emitting diodes[J].Nat. Commun., 2019, 10(1):5267-1-7.

JIA Z W, YUAN C X, LIU Y F, et al.. Strategies to approach high performance in Cr3+-doped phosphors for high-power NIR-LED light sources[J].Light Sci. Appl., 2020, 9:86-1-9.

BINTSIS T, LITOPOULOU-TZANETAKI E, ROBINSON R K. Existing and potential applications of ultraviolet light in the food industry-a critical review[J].J. Sci. Food Agric., 2000, 80(6):637-645.

李梦凯, 强志民, 史彦伟, 等.紫外消毒系统有效辐射剂量测试方法研究进展[J].环境科学学报, 2012, 32(3):513-520.

LI M K, QIANG Z M, SHI Y W, et al.. Research progress on the effective dose measurement methods for UV disinfection facilities[J].Acta Sci. Circumst., 2012, 32(3):513-520. (in Chinese)

LIU C, KONG D S, HSU P C, et al.. Rapid water disinfection using vertically aligned MoS2 nanofilms and visible light[J].Nat. Nanotechnol., 2016, 11(12):1098-1104.

SHUR M S, GASKA R. Deep-ultraviolet light-emitting diodes[J].IEEE Trans. Electron Dev., 2010, 57(1):12-25.

CHEN J, LOEB S, KIM J H. LED revolution:fundamentals and prospects for UV disinfection applications[J].Environ. Sci. Water Res. Technol., 2017, 3(2):188-202.

KNEISSL M, SEONG T Y, HAN J, et al.. The emergence and prospects of deep-ultraviolet light-emitting diode technologies[J].Nat. Photonics, 2019, 13(4):233-244.

BLASSE G, BRIL A. Investigation of some Ce3+-activated phosphors[J].J. Chem. Phys., 1967, 47(12):5139-5145.

刘峰, 王笑军.基质中非4f组态的电子态对Pr3+离子发光的影响[J].发光学报, 2017, 38(1):1-6.

LIU F, WANG X J. Effects of non-4f states on Pr3+ luminescence in phosphors[J].Chin. J. Lumin., 2017, 38(1):1-6. (in English)

CAO C Y, QIN W P, ZHANG J S, et al.. Ultraviolet upconversion emissions of Gd3+[J].Opt. Lett., 2008, 33(8):857-859.

LAUBE M, DEN ENGELSEN D, JANSEN T, et al.. On the photo- and cathodoluminescence of LaB3O6:Gd, Bi, Y3Al5O12:Pr, Y3Al5O12:Gd, Lu3Al5O12:Pr, and Lu3Al5O12:Gd[J].ECS J. Solid State Sci. Technol., 2018, 7(12):R206-R214.

SCHUBERT E F, KIM J K. Solid-state light sources getting smart[J].Science, 2005, 308(5726):1274-1278.

KRAMES M R, SHCHEKIN O B, MUELLER-MACH R, et al.. Status and future of high-power light-emitting diodes for solid-state lighting[J].J. Disp. Technol., 2007, 3(2):160-175.

GEORGE N C, DENAULT K A, SESHADRI R. Phosphors for solid-state white lighting[J].Annu. Rev. Mater. Res., 2013, 43:481-501.

YAN S Y, LIU F, ZHANG J H, et al.. Persistent emission of narrowband ultraviolet-B light upon blue-light illumination[J].Phys. Rev. Appl., 2020, 13(4):044051-1-8.

WU H J, HAO Z D, PAN G H, et al.. Phosphor-SiO2 composite films suitable for white laser lighting with excellent color rendering[J].J. Eur. Ceram. Soc., 2020, 40(6):2439-2444.

POLLNAU M, GAMELIN D R, LVTHI S R, et al.. Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems[J].Phys. Rev. B, 2000, 61(5):3337-3346.

HU C H, SUN C L, LI J F, et al.. Visible-to-ultraviolet upconversion in Pr3+:Y2SiO5 crystals[J].Chem. Phys., 2006, 325(2-3):563-566.

WU J H, SONG Y J, HAN B N, et al.. Synthesis and characterization of UV upconversion material Y2SiO5:Pr3+, Li+/TiO2 with enhanced the photocatalytic properties under a xenon lamp[J].RSC Adv., 2015, 5(61):49356-49362.

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