高分子长余辉发光材料研究进展

孙静; 马会利; 安众福; 黄维

doi:10.37188/CJL.20200317

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高分子长余辉发光材料研究进展

特邀综述 | 更新时间：2020-12-10

- 高分子长余辉发光材料研究进展
- Recent Development of Polymers with Long-lived Persistent Luminescence
- 发光学报 2020年41卷第12期页码：1490-1503
- 作者机构：
  
  1.西北工业大学柔性电子研究院, 柔性电子前沿科学中心, 生物医学材料与工程研究院, 陕西西安 710072
  2.太原理工大学新材料界面科学与工程教育部重点实验室, 山西太原 030024
  3.南京工业大学先进材料研究院, 江苏南京 211816
- 作者简介：
  
  [ "孙静(1987-), 女, 山东潍坊人, 博士, 讲师, 2016年于太原理工大学获得博士学位, 主要从事有机光电功能材料的研究。E-mail:sunjing@tyut.edu.cn" ]
  [ "安众福(1985-), 男, 山东日照人, 博士, 教授, 2014年于南京邮电大学获得博士学位, 主要从事有机长余辉材料与应用的研究。E-mail:iamzfan@njtech.edu.cn" ]
  [ "黄维(1963-), 男, 河北唐山人, 博士, 教授, 中国科学院院士, 俄罗斯科学院外籍院士, 亚太材料科学院院士, 东盟工程与技术科学院外籍院士, 巴基斯坦科学院外籍院士, 1992年于北京大学获得博士学位, 中国有机电子学和柔性电子学的主要奠基者。曾两次获得国家自然科学奖二等奖、三次获得高等学校科学研究优秀成果奖(科学技术)自然科学奖一等奖以及何梁何利基金\"科学与技术进步奖\", 成果入围中国\"高等学校十大科技进展\", 主要从事纳米材料与技术和有机电子与器件等的研究。E-mail:iamwhuang@nwpu.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(51673095);国家自然科学基金(21875104);国家自然科学基金(91833304);国家自然科学基金(91833302);陕西省科学技术厅和西北工业大学联合资助项目(2020GXLH-Z-006);江苏省杰出青年基金(BK20180037);山西省自然科学基金(201901D211090)
- DOI：10.37188/CJL.20200317
  中图分类号：
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孙静, 马会利, 安众福, 等. 高分子长余辉发光材料研究进展[J]. 发光学报, 2020,41(12):1490-1503.

Jing SUN, Hui-li MA, Zhong-fu AN, et al. Recent Development of Polymers with Long-lived Persistent Luminescence[J]. Chinese Journal of Luminescence, 2020,41(12):1490-1503.
孙静, 马会利, 安众福, 等. 高分子长余辉发光材料研究进展[J]. 发光学报, 2020,41(12):1490-1503. DOI： 10.37188/CJL.20200317.

Jing SUN, Hui-li MA, Zhong-fu AN, et al. Recent Development of Polymers with Long-lived Persistent Luminescence[J]. Chinese Journal of Luminescence, 2020,41(12):1490-1503. DOI： 10.37188/CJL.20200317.

摘要

高分子长余辉发光材料具有无定态结构、可加工性能好、发光寿命长、成本低廉等优点，对拓展纯有机长余辉发光材料的应用具有重要意义。为了实现高分子发光材料的长余辉发射，当前主要是利用杂原子或者重原子的自旋轨道耦合作用，提高单/三线态激子间的系间窜越能力；高分子基质中的氢键、卤键、离子键等分子内和分子间相互作用为磷光基团提供刚性环境，抑制其三线态激子的非辐射跃迁和猝灭。基于此，本文综述了近年来高分子长余辉发光材料的研究进展，以及在未来发展过程中面临的机遇与挑战。

Abstract

Polymers with long-lived persistent luminescence have exhibited the characteristics of amorphous structure, excellent process properties, long luminescence lifetime and low cost, which were important to develop the potential application for the pure organic long-lived persistent luminescent materials. In order to obtain the polymers with long-lived persistent luminescence, the current method was to utilize the spin-orbit coupling of heteroatom or heavy atom to improve the inter-system crossing channels of singlet and triplet excitons; and polymer matrix with intramolecular and intermolecular interactions of hydrogen bond, halogen bonding, ionic band and so on will provide the rigid environment for phosphorescent groups to restrain the non-radiative transition and quenching of triplet excitons. Based on these, this article reviewed the research progress of polymers with long-lived persistent luminescence in recent years, as well as put forward the opportunities and challenges in the future development process.

关键词

高分子材料长余辉发光无定形态室温磷光

Keywords

polymer materialspersistent luminescenceamorphous stateroom temperature phosphorescence

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