Pr<sup>3+</sup>掺杂Ge-Ga-Se-CsI硫卤玻璃性能及光纤制备

汪俊; 冯赞; 吴国林; 汪金晶; 焦凯; 王弦歌; 刘佳; 梁晓林; 徐铁松; 钟明辉; 肖晶; 赵浙明; 刘自军; 刘永兴; 王训四

doi:10.37188/CJL.20200223

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Pr³⁺掺杂Ge-Ga-Se-CsI硫卤玻璃性能及光纤制备

材料合成及性能 | 更新时间：2020-11-10

- Pr³⁺掺杂Ge-Ga-Se-CsI硫卤玻璃性能及光纤制备
- Pr³⁺ Doped Ge-Ga-Se-CsI Chalcohalide Glass and Fiber Preparation
- 发光学报 2020年41卷第11期页码：1343-1350
- 作者机构：
  
  1.宁波大学信息科学与工程学院高等技术研究院红外材料及器件实验室, 浙江宁波 315211
  2.浙江省光电探测材料及器件重点实验室, 浙江宁波 315211
  3.嘉兴学院南湖学院, 浙江嘉兴 314001
- 作者简介：
  
  [ "汪俊(1997-), 男, 安徽泾县人, 硕士研究生, 2019年于淮北师范大学获得学士学位, 主要从事硫系光纤制备及其光学性能方面的研究。E-mail:wangjun93733@163.com" ]
  [ "赵浙明(1982-), 男, 浙江嘉兴人, 博士, 副教授, 硕士研究生导师, 2015年于宁波大学获得博士学位, 主要从事红外非线性光纤的研究。E-mail:zhaozheming_27@sina.com" ]
- 基金信息：
  
  国家自然科学基金(61705091);国家自然科学基金(61875097);国家自然科学基金(61627815);浙江省自然科学基金(LY20F050010);浙江省自然科学基金(LR18F050002)
- DOI：10.37188/CJL.20200223
  中图分类号：
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汪俊, 冯赞, 吴国林, 等. Pr³⁺掺杂Ge-Ga-Se-CsI硫卤玻璃性能及光纤制备[J]. 发光学报, 2020,41(11):1343-1350.

Jun WANG, Zan FENG, Guo-lin WU, et al. Pr³⁺ Doped Ge-Ga-Se-CsI Chalcohalide Glass and Fiber Preparation[J]. Chinese Journal of Luminescence, 2020,41(11):1343-1350.
汪俊, 冯赞, 吴国林, 等. Pr³⁺掺杂Ge-Ga-Se-CsI硫卤玻璃性能及光纤制备[J]. 发光学报, 2020,41(11):1343-1350. DOI： 10.37188/CJL.20200223.

Jun WANG, Zan FENG, Guo-lin WU, et al. Pr³⁺ Doped Ge-Ga-Se-CsI Chalcohalide Glass and Fiber Preparation[J]. Chinese Journal of Luminescence, 2020,41(11):1343-1350. DOI： 10.37188/CJL.20200223.

摘要

采用熔融淬冷法制备了两种浓度的Pr,3+,掺杂GeSe,2,-Ga,2,Se,3,-CsI(GGC)硫卤玻璃。在2.0 μm激光激励下，比较了玻璃片(2 mm)和玻璃柱(6 mm)的荧光发射光谱。用Judd-Ofelt理论计算分析了Pr,3+,掺杂Ge-Ga-Se-CsI硫卤玻璃的强度参数,Ω,i,(,i,=2，4，6)和辐射寿命,τ,rad,等光谱参数。通过拟合衰变曲线，测得了玻璃的荧光寿命值(0.5% Pr,3+,:3.08 ms)。所制备的光纤具备双包层结构，通过截断法得到光纤在7.6 μm处的最低损耗为2.27 dB/cm。

Abstract

Different series of Pr,3+, doped GeSe,2,-Ga,2,Se,3,-CsI(GGC)chalcogenide glass were prepared by a melt-quenching method. Under the excitation of 2.0 μm wavelength, the emission spectra of bulk glass (2 mm) and glass column(6 mm) were compared. The intensity parameter ,Ω,i,(,i,=2, 4, 6) and radiative lifetime ,τ,rad, of Pr,3+, doped Ge-Ga-Se-CsI chalcogenide glass are calculated and analyzed by Judd-Ofelt theory. The fluorescence lifetime of the glass(0.5% Pr ,3+,:3.08 ms) was measured by fitting the decay curve. The fabricated fiber has a double cladding structure, the fiber loss is measured by cut-back method and the minimum loss at 7.6 μm is 2.27 dB/cm.

关键词

硫卤玻璃Judd-Ofelt理论辐射寿命光纤损耗

Keywords

chalcohalide glassJudd-Ofelt theoryradiative lifetimefiber loss

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Pr3+掺杂Ge-Ga-Se-CsI硫卤玻璃性能及光纤制备

Pr3+ Doped Ge-Ga-Se-CsI Chalcohalide Glass and Fiber Preparation

DOI：10.37188/CJL.20200223

摘要

Abstract

关键词

Keywords

references

Pr³⁺掺杂Ge-Ga-Se-CsI硫卤玻璃性能及光纤制备

Pr³⁺ Doped Ge-Ga-Se-CsI Chalcohalide Glass and Fiber Preparation