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808 nm激发的NaYF4:Yb/Tm/Ca@NaGdF4:Nd/Yb上转换纳米粒子的制备及其发光性质
Preparation and Luminescent Properties of NaYF4: Yb/Tm/Ca@NaGdF4: Nd/Yb Up-conversion Nanoparticles Excited at 808 nm
- 发光学报 2020年41卷第11期 页码：1358-1366
- 作者机构：
桂林理工大学 材料科学与工程学院, 广西有色金属及特色材料加工重点实验室, 广西 桂林 541004
- 作者简介：
[ "林少伟(1994-), 男, 河南驻马店人, 硕士研究生, 2018年于周口师范学院获得学士学位, 主要从事稀土上转换纳米发光材料方面的研究。E-mail:gllinsw@163.com" ]
[ "欧俊(1963-), 男, 广西桂林人, 博士, 研究员, 2007年于四川大学获得博士学位, 主要从事生物纳米医用功能材料等方面的研究。E-mail:gloujun@glut.edu.cn" ]
- 基金信息：广西重点科研项目(2016GXNSFDA380026)
DOI：10.37188/CJL.20200195
中图分类号： O482.31收稿日期：2020-07-07，
录用日期：2020-8-12，
纸质出版日期：2020-11
- 稿件说明：
移动端阅览
林少伟, 赵婧, 法信蒙, 等. 808 nm激发的NaYF4:Yb/Tm/Ca@NaGdF4:Nd/Yb上转换纳米粒子的制备及其发光性质[J]. 发光学报, 2020,41(11):1358-1366.
Shao-wei LIN, Jing ZHAO, Xin-meng FA, et al. Preparation and Luminescent Properties of NaYF4: Yb/Tm/Ca@NaGdF4: Nd/Yb Up-conversion Nanoparticles Excited at 808 nm[J]. Chinese journal of luminescence, 2020, 41(11): 1358-1366.
林少伟, 赵婧, 法信蒙, 等. 808 nm激发的NaYF4:Yb/Tm/Ca@NaGdF4:Nd/Yb上转换纳米粒子的制备及其发光性质[J]. 发光学报, 2020,41(11):1358-1366. DOI： 10.37188/CJL.20200195.
Shao-wei LIN, Jing ZHAO, Xin-meng FA, et al. Preparation and Luminescent Properties of NaYF4: Yb/Tm/Ca@NaGdF4: Nd/Yb Up-conversion Nanoparticles Excited at 808 nm[J]. Chinese journal of luminescence, 2020, 41(11): 1358-1366. DOI： 10.37188/CJL.20200195.
摘要
采用溶剂热法成功制备了Nd
3+
敏化的掺杂Ca
2+
的NaYF
4
:Yb/Tm/Ca@NaGdF
4
:Nd/Yb核-壳上转换纳米粒子。针对Tm
3+
多光子过程中产生的蓝色及紫外上转换发光，研究了敏化剂Nd
3+
、Yb
3+
的含量以及激发功率等关键因素对荧光性能的影响，并用介孔二氧化硅(mSiO
2
)对其表面进行修饰，得到具有良好亲水性的上转换纳米粒子，通过TEM、XRD、FT-IR和荧光光谱对其形貌、结构和荧光性能进行表征。结果表明，制备的纳米粒子为纯六角相，表面均匀地包覆了一层mSiO
2
，在808 nm近红外光激发下，壳层中Nd
3+
和Yb
3+
的摩尔分数分别为50%和10%时表现出强烈的上转换蓝光(
1
D
2
→
3
F
4
，
1
G
4
→
3
H
6
)和紫外光(
1
I
6
→
3
F
4
，
1
D
2
→
3
H
6
)，在光动力疗法和荧光成像方面具有潜在的应用价值。
Abstract
The Nd
3+
-sensitized Ca
2+
-doped NaYF
4
:Yb/Tm/Ca@NaGdF
4
:Nd/Yb core/shell upconversion nanoparticles were successfully prepared by solvothermal method. The effects of key factors such as the content of sensitizers Nd
3+
and Yb
3+
and the excitation power on the fluorescence performance were studied for the blue light and UV up-conversion emission generated in the Tm
3+
multi-photon process. To obtain up-converting nanoparticles with good hydrophilicity
the UCNPs surface was modified with mesoporous silica(mSiO
2
). Its morphology
structure and fluorescence properties were characterized by TEM
XRD
FT-IR and fluorescence spectroscopy. The results showed that the prepared nanoparticles were pure hexagonal phase
the surface was evenly modified with a layer of mSiO
2
. Then
under the excitation of 808 nm near infrared light
when the mole fraction of Nd
3+
and Yb
3+
in the shell was 50% and 10% respectively
it shows strong up-conversion blue light(
1
D
2
→
3
F
4
1
G
4
→
3
H
6
) and ultraviolet light(
1
I
6
→
3
F
4
1
D
2
→
3
H
6
). The research will have potential application prospects in photodynamic therapy and fluorescence imaging.
关键词
Keywords
references
AUZEL F. Upconversion andanti-stokes processes with F and D ions in solids[J]. Chem. Rev. , 2004, 104(1):139-174.
DONG H, SUN L D, YAN C H. Energy transfer in lanthanide upconversion studies for extended optical applications[J]. Chem. Soc. Rev. , 2015, 44(6):1608-1634.
WU M, YAN L, WANG T, et al .. Controlling red color-based multicolor upconversion through selective photon blocking[J]. Adv. Func. Mater. , 2019, 29(25):1804160-1-11.
CHATTERJEE D K, GNANASAMMANDHAN M K, ZHANG Y. Small upconverting fluorescent nanoparticles for biomedical applications[J]. Small , 2010, 6(24):2781-2795.
TSANG M K, CHAN C F, WONG K L, et al .. Comparative studies of upconversion luminescence characteristics and cell bioimaging based on one-step synthesized upconversion nanoparticles capped with different functional groups[J]. J. Lumin. , 2015, 157:172-178.
LIU J N, BU W B, PAN L N, et al .. NIR-triggered anticancer drug delivery by upconverting nanoparticles with integrated azobenzene-modified mesoporous silica[J]. Angew. Chem. Int. Ed. , 2013, 52(16):4375-4379.
TENG B, HAN Y Q, ZHANG X Y, et al .. Phenanthriplatin (Ⅳ) conjugated multifunctional up-converting nanoparticles for drug delivery and biomedical imaging[J]. J. Mater. Chem. B, 2018, 6(31):5059-5068.
HUANG X Y, HAN S Y, HUANG W, et al .. Enhancing solar cell efficiency:the search for luminescent materials as spectral converters[J]. Chem. Soc. Rev. , 2013, 42(1):173-201.
SUN L Y, GAO R Y, PAN T T, et al .. Concentration-regulated photon upconversion and quenching in NaYF 4 :Yb 3+ , Er 3+ nanocrystals:nonexponentiality revisited[J]. Nanoscale , 2019, 11(39):18150-18158.
WANG F, LIU X G. Recent advances in the chemistry of lanthanide-doped upconversion nanocrystals[J]. Chem. Soc. Rev. , 2009, 38(4):976-989.
CHEN G Y, YANG C H, PRASAD P N. Nanophotonics and nanochemistry:controlling the excitation dynamics for frequency up- and down-conversion in lanthanide-doped nanoparticles[J]. Acc. Chem. Res. , 2013, 46(7):1474-1486.
SUYVER J F, GRIMM J, KRÄMER K W, et al .. Highly efficient near-infrared to visible up-conversion process in NaYF 4 :Er 3+ , Yb 3+ [J]. J. Lumin. , 2005, 114(1):53-59.
JIANG T, LIU Y, LIUS S, et al .. Upconversion emission enhancement of Gd 3+ ions induced by surface plasmon field in Au@NaYF 4 nanostructures codoped with Gd 3+ -Yb 3+ -Tm 3+ ions[J]. J. Colloid Interface Sci. , 2012, 377(1):81-87.
YANG Y M, SHAO Q, DENG R R, et al .. In vitro and in vivo uncaging and bioluminescence imaging by using photocaged upconversion nanoparticles[J]. Angew. Chem. Int. Ed. , 2012, 51(13):3125-3129.
SHEN J, CHEN G Y, VU A M, et al .. Engineering the upconversion nanoparticle excitation wavelength:cascade sensitization of tri-doped upconversion colloidal nanoparticles at 800 nm[J]. Adv. Opt. Mater. , 2013, 1(9):644-650.
WANG S, SHEN B, WEI H L, et al .. Comparative investigation of the optical spectroscopic and thermal effect in Nd 3+ -doped nanoparticles[J]. Nanoscale , 2019, 11(21):10220-10228.
WANG Y F, LIU G Y, SUN L D, et al .. Nd 3+ -sensitized upconversion nanophosphors:efficient in vivo bioimaging probes with minimized heating effect[J]. ACS Nano , 2013, 7(8):7200-7206.
HUANG X Y, LIN J. Active-core/active-shell nanostructured design:an effective strategy to enhance Nd 3+ /Yb 3+ cascade sensitized upconversion luminescence in lanthanide-doped nanoparticles[J]. J. Mater. Chem. C, 2015, 3(29):7652-7657.
HUANG X Y. Giant enhancement of upconversion emission in (NaYF 4 :Nd 3+ /Yb 3+ /Ho 3+ )/(NaYF 4 :Nd 3+ /Yb 3+ ) core/shell nanoparticles excited at 808 nm[J]. Opt. Lett. , 2015, 40(15):3599-3602.
LEI L, CHEN D Q, XU J, et al .. Highly intensified upconversion luminescence of Ca 2+ -doped Yb/Er:NaGdF 4 nanocrystals prepared by a solvothermal route[J]. Chem. Asian J. , 2014, 9(3):728-733.
ZHANG X, TIAN G, YIN W Y, et al .. Controllable generation of nitric oxide by near-infrared-sensitized upconversion nanoparticles for tumor therapy[J]. Adv. Funct. Mater. , 2015, 25(20):3049-3056.
POLLNAU M, GAMELIN D R, LVTHI S R, et al .. Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems[J]. Phys. Rev. B, 2000, 61(5):3337-3346.
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