绿色方法合成纳米碳点及对Fe<sup>3+</sup>的特异性荧光检测

张艺; 邢晶晶; 孙思佳; 吴頔; 曾乐勇

doi:10.37188/CJL.20200174

您当前的位置：

首页 >

文章列表页 >

绿色方法合成纳米碳点及对Fe³⁺的特异性荧光检测

材料合成及性能 | 更新时间：2020-10-12

- 绿色方法合成纳米碳点及对Fe³⁺的特异性荧光检测
- Green Synthesis of Carbon Nanodots and Their Application in Specific Fluorescence Detection of Fe³⁺
- 发光学报 2020年41卷第10期页码：1249-1254
- 作者机构：
  
  河北大学化学与环境科学学院, 河北保定 071002
- 作者简介：
  
  [ "张艺(1999-), 女, 河北南和县人, 硕士研究生, 2020年于河北大学获得学士学位, 主要从事纳米碳点的合成及应用的研究。E-mail:1466919053@qq.com" ]
  [ "吴頔(1984-), 女, 辽宁抚顺人, 硕士, 实验师, 2010年于东北林业大学获得硕士学位, 主要从事无机纳米材料制备及应用的研究。E-mail:wudi2137@126.com" ]
  [ "曾乐勇(1981-), 男, 河北新河县人, 博士, 教授, 博士研究生导师, 2010年于中国科学院长春光学精密机械与物理研究所获得博士学位, 主要从事磁/光响应型纳米材料制备及应用的研究。E-mail:zengly@hbu.cn" ]
- 基金信息：
  
  国家自然科学基金(51772074);国家自然科学基金(U1732127)
- DOI：10.37188/CJL.20200174
  中图分类号： 613.71
- 纸质出版日期：2020-10，
  
  收稿日期：2020-06-24，
  
  录用日期：2020-7-16
- 稿件说明：
移动端阅览
张艺, 邢晶晶, 孙思佳, 等. 绿色方法合成纳米碳点及对Fe³⁺的特异性荧光检测[J]. 发光学报, 2020,41(10):1249-1254.

YI ZHANG, JING-JING XING, SI-JIA SUN, et al. Green Synthesis of Carbon Nanodots and Their Application in Specific Fluorescence Detection of Fe³⁺. [J]. Chinese journal of luminescence, 2020, 41(10): 1249-1254.
张艺, 邢晶晶, 孙思佳, 等. 绿色方法合成纳米碳点及对Fe³⁺的特异性荧光检测[J]. 发光学报, 2020,41(10):1249-1254. DOI： 10.37188/CJL.20200174.

YI ZHANG, JING-JING XING, SI-JIA SUN, et al. Green Synthesis of Carbon Nanodots and Their Application in Specific Fluorescence Detection of Fe³⁺. [J]. Chinese journal of luminescence, 2020, 41(10): 1249-1254. DOI： 10.37188/CJL.20200174.

摘要

以黄瓜为原料，采用水热法合成了荧光纳米碳点，实现了对Fe

的特异性荧光检测。利用透射电子显微镜和X射线光电子能谱仪对纳米碳点的形貌和微结构进行了表征，并利用荧光光谱仪对纳米碳点的荧光性能以及加入不同金属离子后的荧光强度变化进行了测量。结果表明，合成的纳米碳点分散性良好，尺寸约为3 nm左右。在365 nm紫外光激发下，其发射峰位于435 nm；当反应温度为200℃、反应时间为12 h时，纳米碳点的荧光性能最佳。Fe

的加入能猝灭纳米碳点的荧光，而其他金属离子不会引起纳米碳点荧光强度和发射峰位置的改变，表明绿色方法合成的纳米碳点实现了对Fe

的特异性荧光检测。

Abstract

Using cucumber as raw material

fluorescent carbon nanodots were synthesized

via

hydrothermal method

by which the specific fluorescent detection of Fe

was achieved. The morphology and microstructure of carbon nanodots were characterized by transmission electron microscope and X-ray photoelectron spectroscope

and the fluorescent performance of carbon nanodots was measured by fluorescent spectroscope. The results indicated that the prepared carbon nanodots showed good dispersity

and the average size was about 3 nm. When the reaction temperature was 200 ℃ and the reaction time was 12 h

the prepared carbon nanodots have the optimum fluorescent performance. Moreover

the introduction of Fe

can quench the fluorescence of carbon nanodots

but other metal ions can not change the fluorescence intensity and emission wavelength of carbon nanodots

which indicates that the prepared carbon nanodots achieve specific fluorescence detection towards Fe

关键词

纳米碳点水热法黄瓜绿色合成Fe3+荧光检测

Keywords

carbon nanodotshydrothermal methodcucumbergreen synthesisFe3+ fluorescent detection

references

SUN Y P, ZHOU B, LIN Y, et al.. Quantum-sized carbon dots for bright and colorful photoluminescence[J]. J. Am. Chem. Soc., 2006, 128(24):7756-7757.

LIM S Y, SHEN W, GAO Z Q. Carbon quantum dots and their applications[J]. Chem. Soc. Rev., 2015, 44(1):362-381.

ZHU S J, MENG Q N, WANG L, et al.. Highly photoluminescent carbon dots for multicolor patterning, sensors, and bioimaging[J]. Angew. Chem. Int. Ed., 2013, 52(14):3953-3957.

ZHENG M, RUAN S B, LIU S, et al.. Self-targeting fluorescent carbon dots for diagnosis of brain cancer cells[J]. ACS Nano, 2015, 9(11):11455-11461.

LIU Y, TIAN Y, WANG Y F, et al.. Carbon-dot-based nanosensors for the detection of intracellular redox state[J]. Adv. Mater., 2015, 27(44):7156-7160.

JIANG K, WANG Y H, GAO X L, et al.. Facile, quick, and gram-scale synthesis of ultralong-lifetime room-temperature-phosphorescent carbon dots by microwave irradiation[J]. Angew. Chem. Int. Ed., 2018, 57(21):6216-6220.

DING H, WEI J S, ZHANG P, et al.. Solvent-controlled synthesis of highly luminescent carbon dots with a wide color gamut and narrowed emission peak widths[J]. Small, 2018, 14(22):1800612-1-10.

曲松楠, 孙铭鸿, 田震, 等.氮掺杂碳点的合成与应用[J].发光学报, 2019, 40(5):557-580.

QU S N, SUN M H, TIAN Z, et al.. Synthesis and application of nitrogen-doped carbon dots[J]. Chin. J. Lumin., 2019, 40(5):557-580. (in Chinese)

王诗琪, 涂雨菲, 刘之晓, 等.微波法制备掺氮碳点及其用作探针检测铁离子[J].发光学报, 2019, 40(6):751-757.

WANG S Q, TU Y F, LIU Z X, et al.. Microwave synthesis of nitrogen-doped carbon dots and its application in detection of ferric ions[J]. Chin. J. Lumin., 2019, 40(6):751-757. (in Chinese)

MIAO X, QU D, YANG D X, et al.. Synthesis of carbon dots with multiple color emission by controlled graphitization and surface functionalization[J]. Adv. Mater., 2018, 30(1):1704740-1-8.

JIANG K, SUN S, ZHANG L, et al.. Red, green, and blue luminescence by carbon dots:full-color emission tuning and multicolor cellular imaging[J]. Angew. Chem. Int. Ed., 2015, 54(18):5360-5363.

王靖原, 张越诚, 马红燕, 等.红枣碳量子点"关-开"型荧光探针检测芦丁的研究[J].发光学报, 2018, 39(4):600-607.

WANG J Y, ZHANG Y C, MA H Y, et al.. Synthesized of carbon quantum dots from red dates and as a "off-on" fluorescence probe for high sensitive detection of rutin[J]. Chin. J. Lumin., 2018, 39(4):600-607. (in Chinese)

ATCHUDAN R, EDISON T N J I, ASEER K R, et al.. Highly fluorescent nitrogen-doped carbon dots derived from Phyllanthus acidus utilized as a fluorescent probe for label-free selective detection of Fe3+ ions, live cell imaging and fluorescent ink[J]. Biosens. Bioelectron., 2018, 99:303-311.

LI L S, JIAO X Y, ZHANG Y, et al.. Green synthesis of fluorescent carbon dots from hongcaitai for selective detection of hypochlorite and mercuric ions and cell imaging[J]. Sens. Actuators B Chem., 2018, 263:426-435.

PACQUIAO M R, DE LUNA M D G, THONGSAI N,et al.. Highly fluorescent carbon dots from enokitake mushroom as multi-faceted optical nanomaterials for Cr6+ and VOC detection and imaging applications[J]. Appl. Surf. Sci., 2018, 453:192-203.

ZHAO S J, LAN M H, ZHU X Y, et al.. Green synthesis of bifunctional fluorescent carbon dots from garlic for cellular imaging and free radical scavenging[J]. ACS Appl. Mater. Interfaces, 2015, 7(31):17054-17060.

MATTEVI C, EDA G, AGNOLI S, et al.. Evolution of electrical, chemical, and structural properties of transparent and conducting chemically derived graphene thin films[J]. Adv. Funct. Mater., 2009, 19(6):2577-2583.

GONG K P, DU F, XIA Z H, et al.. Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction[J]. Science, 2009, 323(5915):760-764.

PRATO M, RIGODANZA F, ARCUDI F, et al.. Customizing the electrochemical properties of carbon nanodots by using quinones in bottom-up synthesis[J]. Angew. Chem. Int. Ed., 2018, 57(18):5062-5067.

FENG X, LI Y, HE X W, et al.. A substitution-dependent light-up fluorescence probe for selectively detecting Fe3+ ions and its cell imaging application[J]. Adv. Funct. Mater., 2018, 28(35):1802833-1-8.

ZHU X W, ZHANG Z, XUE Z J, et al.. Understanding the selective detection of Fe3+ based on graphene quantum dots as fluorescent probes:the Ksp of a metal hydroxide-assisted mechanism[J]. Anal. Chem., 2017, 89(22):12054-12058.

浏览量

250

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

KYb₂F₇∶2% Er³⁺荧光材料的制备、发光机制及温度传感性能

生物质基碳点制备及应用研究进展

激光诱导聚二甲基硅氧烷制备石墨烯量子点

碱金属共掺MgSc₂O₄:Er³⁺/Yb³⁺纳米晶的上转换发光性能

绿色方法合成纳米碳点及对Fe3+的特异性荧光检测

Green Synthesis of Carbon Nanodots and Their Application in Specific Fluorescence Detection of Fe3+

DOI：10.37188/CJL.20200174

摘要

Abstract

关键词

Keywords

references

绿色方法合成纳米碳点及对Fe³⁺的特异性荧光检测

Green Synthesis of Carbon Nanodots and Their Application in Specific Fluorescence Detection of Fe³⁺