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1. 大连理工大学 物理与光电工程学院
2. 吉林大学电子与信息工程学院 集成光电子学国家重点联合实验室
收稿:2011-03-08,
修回:2011-4-21,
网络首发:2011-09-22,
纸质出版:2011-09-22
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许露, 梁红伟, 刘远达, 李春野, 柳阳, 边继明, 李国兴, 李万程, 吴国光, 杜国同. MOCVD法制备Cu掺杂ZnO薄膜[J]. 发光学报, 2011,32(9): 956-961
XU Lu, LIANG Hong-wei, LIU Yuan-da, LI Chun-ye, LIU Yang, BIAN Ji-ming, LI Guo-xing, LI Wan-cheng, WU Guo-guang, DU Guo-tong. Cu-doped ZnO Thin Film Prepared by Metallorganic Chemical Vapor Deposition[J]. Chinese Journal of Luminescence, 2011,32(9): 956-961
许露, 梁红伟, 刘远达, 李春野, 柳阳, 边继明, 李国兴, 李万程, 吴国光, 杜国同. MOCVD法制备Cu掺杂ZnO薄膜[J]. 发光学报, 2011,32(9): 956-961 DOI:
XU Lu, LIANG Hong-wei, LIU Yuan-da, LI Chun-ye, LIU Yang, BIAN Ji-ming, LI Guo-xing, LI Wan-cheng, WU Guo-guang, DU Guo-tong. Cu-doped ZnO Thin Film Prepared by Metallorganic Chemical Vapor Deposition[J]. Chinese Journal of Luminescence, 2011,32(9): 956-961 DOI:
通过金属有机物化学气相沉积(MOCVD)设备
在
c
-Al
2
O
3
衬底上生长本征和 Cu掺杂ZnO(ZnO:Cu)薄膜。X射线衍射(XRD)谱观察到未掺杂的ZnO和ZnO:Cu样品都呈现出较好的
c
轴择优取向生长。X射线光电子能谱(XPS)表明Cu已掺入到ZnO薄膜中。利用光致发光(PL)测试对本征ZnO和ZnO:Cu进行室温和低温PL测试
在ZnO:Cu样品的低温PL谱中观察到一个强度很强、范围很广的蓝紫光发射峰(Blue-violet发射峰
BV发射峰)
范围在2.8~3.3 eV之间
又进一步通过变温PL测试发现随着温度的升高
BV发射峰峰位发生红移
且80 K时BV发射峰高能边出现自由电子向受主能级(eA
0
)的跃迁发光
并计算了Cu受主离化能。
paper
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