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1. 太原理工大学 新材料界面科学与工程教育部重点实验室
2. 太原理工大学 新材料工程技术研究中心, 山西 太原 030024
3. 太原理工大学 理学院, 山西 太原 030024
收稿:2010-07-26,
修回:2010-8-31,
网络首发:2011-03-22,
纸质出版:2011-03-22
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宋春丽, 徐阳, 周禾丰, 王华, 李娟, 张存, 张俊萍, 郝玉英, 许并社. 一种新型红光有机电致发光材料的合成与性能[J]. 发光学报, 2011,32(3): 285-289
SONG Chun-li, XU Yang, ZHOU He-feng, WANG Hua, LI Juan, ZHANG Cun, ZHANG Jun-ping, HAO Yu-ying, XU Bing-she. Synthesis and Properties of a Novel Type of Red-light Organic Electroluminescence Material[J]. Chinese Journal of Luminescence, 2011,32(3): 285-289
宋春丽, 徐阳, 周禾丰, 王华, 李娟, 张存, 张俊萍, 郝玉英, 许并社. 一种新型红光有机电致发光材料的合成与性能[J]. 发光学报, 2011,32(3): 285-289 DOI:
SONG Chun-li, XU Yang, ZHOU He-feng, WANG Hua, LI Juan, ZHANG Cun, ZHANG Jun-ping, HAO Yu-ying, XU Bing-she. Synthesis and Properties of a Novel Type of Red-light Organic Electroluminescence Material[J]. Chinese Journal of Luminescence, 2011,32(3): 285-289 DOI:
采用Suzuki耦合反应合成了一种新型的线性双偶极小分子红光有机电致发光材料
即2
7-二噻吩基-9-芴酮(2
7-di(2-thienyl)fluoren-9-one
DTFO)
对其结构及电子性能进行了模拟计算
通过各种测试方法表征了其化学结构
并对其光物理性能、热稳定性及成膜性进行了详细表征。实验结果表明
DTFO为线性近平面交替共轭结构;在光致发光谱中
溶液中DTFO发射的峰值波长为616 nm
固态DTFO为 618 nm;电致发光光谱显示其发光为峰值波长为570 nm的红光发射。此外
DTFO还具有优良的热稳定性和成膜性。
paper
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