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武汉理工大学 材料科学与工程学院
收稿:2010-06-04,
修回:2010-9-11,
网络首发:2011-02-22,
纸质出版:2011-02-22
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姬同坤, 姜洪义. Y<sub>2</sub>O<sub>2</sub>S∶Eu, Mg, Ti, Gd 红色长余辉发光材料的热稳定性[J]. 发光学报, 2011,32(2): 122-126
JI Tong-kun, JIANG Hong-yi. Thermal Stability of Red Afterglow Phosphor Y<sub>2</sub>O<sub>2</sub>S ∶ Eu,Mg,Ti,Gd[J]. Chinese Journal of Luminescence, 2011,32(2): 122-126
采用高温固相法制备了Y
2
O
2
S ∶ Eu
Mg
Ti
Gd红色长余辉材料
研究了热处理工艺对材料稳定性的影响。用X射线衍射表征该材料的相组成
用激发光谱、发射光谱、余辉亮度对材料的发光性能进行表征。结果表明:热处理温度在600 ℃以下时
材料的发光性能不变;当热处理温度达到800 ℃时
发光性能缓慢下降;当热处理温度达到1 000 ℃时
主晶相Y
2
O
2
S变成Y
2
O
2
SO
4
和Y
2
O
3
发光性能急剧下降。与铝酸盐及硫化物发光材料相比
Y
2
O
2
S ∶ Eu
Mg
Ti
Gd红色长余辉材料具有较好的热稳定性。
paper
Zhou Wei, Du Haiyai, GaO Bin, et al. Summary of study on non-radioactive persistent red phosphors [J]. J. Beijing Technology and Business University (Natural Science Edition)(北京工商大学学报,自然科学版), 2001, 19 (3):5-8 (in Chinese).[2] Sun Jibing, Wang Hairong, An Yaqin, et al. Progress on long persistence luminescent materials [J]. Rare Metal Mat. Eng. (稀有金属材料与工程), 2008, 37 (2):189-194 (in Chinese).[3] Chen Xuehua, Hu Yihua, Wang Yinhai, et al. Valence-change of Eu and its effect on the luminescent properties of long afterglow phosphor SrAl2O4 ∶ Eu, Dy [J]. Chin. J. Lumin. (发光学报), 2009, 30 (1):40-46 (in Chinese).[4] Lu Hao, Liu Aimei, Xiong Pingfan, et al. Temperature impact on luminescence performances of long-lasting afterglow glass [J]. Chin. J. Lumin. (发光学报), 2009, 30 (4):554-558 (in Chinese).[5] Dongdong Jia, Weiyi Jia, Evans D R, et al. Trapping processes in CaS ∶ Eu2+ ,Tm3+ [J]. J. Appl. Phys., 2000, 88 (6):3402-3407.[6] Yin Shengyu, Chen Donghua, Tang Wanjun, et al. Synthesis of CaTiO3 ∶ Pr persistent phosphors by a modified solid-state reaction [J]. Mater. Sci. Eng. B, 2007, 136 (2-3):193-196.[7] Shen Leijun, Zhao Zengqi, Han Li, et al. Effect of Zn,Cd on the luminescent properties of CaTiO3 ∶ Pr3+ [J]. Chin. J. Lumin.(发光学报), 2007, 28 (1):74-78 (in Chinese).[8] Zhang Ping, Xu Mingxia, Zheng Zhentai, et al. Rapid formation of red long afterglow phosphor Sr3Al2O6 ∶ Eu2+ , Dy3+ by microwave irradiation [J]. Mater. Sci. Eng. B, 2007, 136 (2-3):159-164.[9] Yan Wuzhao, Lin Lin, Chen Yonghu, et al. New red long afterglow aluminate materials doped with Mn4+ [J]. Chin. J. Lumin.(发光学报), 2008, 29 (1):114-118 (in Chinese).[10] Murazaki Y, Arai K, Ichinomiya K. A new long persistence red phosphor [J]. Rare Earths Jpn., 1999, 35 (1):41-45.[11] Zhou Xinmu, Zeng Huihui. Synthesis and characterization of new long lasting red phosphors Y2O2S ∶ Eu, Si, M(M=Mg, Ca, Sr, Ba) [J]. Chin. J. Lumin.(发光学报), 2010, 31 (1):59-63 (in Chinese).[12] Yang Zhiping, Guo Zhi, Wang Wenjie, et al. Synthesis of Y2O2S ∶ Eu3+ , Mg2+ ,Ti4+ red phosphor by flux fusion method and its characteristic [J]. Chin. J. Lumin.(发光学报), 2004, 25 (2):183-187 (in Chinese).[13] Wei Yashu, Zhang Jinchao, Song Li. Study on the firing condition and flux in synthesizing Y2O2S ∶ Eu3+ ,Mg2+ ,Ti4+ red afterglow phosphor [J]. Chin. J. Appl. Chem.(应用化学), 2005, 22 (12):1342-1346 (in Chinese).[14] Yang Zhiping, Guo Zhi, Zhu Shengchao, et al. Effect of Eu3+ molar ratio on the spectra of Y2O2S ∶ Eu3+ ,Mg2+ , Ti4+ red phosphor [J]. Spectroscopy Spect. Anal. (发谱学与光谱分析), 2004, 24 (12):1506-1510 (in Chinese).[15] Wang Yuhua, Wang Zhilong. Characterization of Y2O2S ∶ Eu3+ , Mg2+ , Ti4+ long-lasting phosphor synthesized by flux method [J]. J. Rare Earth, 2006, 24 (1):25-28.[16] Zhang Xiyan, Bai Zhaohui, Guan Xin, et al. Preparation of long persistent phosphorescence SrAl2O4 ∶ Eu2+ ,Dy3+ phosphors by solid state reaction and characterization [J]. Rare Metal Mat. Eng. (稀有金属材料与工程), 2003, 32 (5):379-382 (in Chinese).[17] Zhang Yue, Li Yadong. Synthesis and characterization of monodisperse doped ZnS nanospheres with enhanced thermal stability [J]. J. Phys. Chem. B, 2004, 108 (46):17805-17811.[18] Zhu Hongyang, Yang Haibin, Fu Wuyou, et al. The improvement of thermal stability of BaMgAl10O17 ∶ Eu2+ coated with MgO [J]. Mater. Lett., 2008, 62 (4-5):784-786.[19] Xiao Zhiguo, Luo Xixian. Long Afterglow Phosphors and Its Production [M]. Beijing: Chemical Industry Press, 2005:42 (in Chinese).
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