基于双酚A的希夫碱型锌配位聚合物的合成及发光性能

谷刘园; 屠慧; 朱荔; 姚小泉

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基于双酚A的希夫碱型锌配位聚合物的合成及发光性能

材料合成及性能研究 | 更新时间：2020-08-12

- 基于双酚A的希夫碱型锌配位聚合物的合成及发光性能
- Synthesis and Luminescent Properties of Novel Metal-organic Coordination Polymers Based on Bisphenol A
- 发光学报 2011年32卷第2期页码：127-133
- 作者机构：
  
  1. 南京航空航天大学材料科学与技术学院
  2. 南京医科大学药学院
- 作者简介：
- 基金信息：
  
  江苏省自然科学基金(BK2008386)();教育部留学人员科研基金(M0805-062)资助项目()
- DOI：
  中图分类号： TN383.1;O482.31
- 收稿：2010-06-04，
  
  修回：2010-9-23，
  
  纸质出版：2011
- 稿件说明：
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谷刘园, 屠慧, 朱荔, 姚小泉. 基于双酚A的希夫碱型锌配位聚合物的合成及发光性能[J]. 发光学报, 2011,32(2): 127-133

GU Liu-yuan, TU Hui, ZHU Li, YAO Xiao-quan. Synthesis and Luminescent Properties of Novel Metal-organic Coordination Polymers Based on Bisphenol A[J]. Chinese Journal of Luminescence, 2011,32(2): 127-133
谷刘园, 屠慧, 朱荔, 姚小泉. 基于双酚A的希夫碱型锌配位聚合物的合成及发光性能[J]. 发光学报, 2011,32(2): 127-133 DOI：

GU Liu-yuan, TU Hui, ZHU Li, YAO Xiao-quan. Synthesis and Luminescent Properties of Novel Metal-organic Coordination Polymers Based on Bisphenol A[J]. Chinese Journal of Luminescence, 2011,32(2): 127-133 DOI：

摘要

以双酚A 为原料合成了具有对称的桥联结构的双水杨醛

在此基础上合成了一系列的双希夫碱配体及相应的锌配位聚合物。利用红外吸收光谱、核磁共振等方法研究了化合物的分子结构

利用热重分析研究了配合物的热稳定性

利用紫外吸收、荧光光谱研究了该系列配合物的发光性能

利用循环伏安法测试了配合物的能级带隙。研究结果表明:该系列配合物具有较好的热稳定性

热分解温度为405~443 ℃;发光波长为493~503 nm

属于蓝绿光范围;量子效率和文献报道的相近;能级带隙约为3.04~3.23 eV。

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