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1. 五邑大学 功能材料研究所
2. 华南农业大学 理学院生物材料研究所
3. 中山大学 化学与化学工程学院
收稿:2010-09-08,
修回:2010-12-7,
网络首发:2011-03-22,
纸质出版:2011-03-22
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丁唯嘉, 张梅, 王静, 苏锵. 白光LED用新型绿色荧光粉 Ca<sub>5</sub>(SiO<sub>4</sub>)<sub>2</sub>F<sub>2</sub> ∶ Eu<sup>2+</sup>的发光性能[J]. 发光学报, 2011,32(3): 256-261
DING Wei-jia, ZHANG Mei, WANG Jing, SU Qiang. Luminescence Properties of New Ca<sub>5</sub>(SiO<sub>4</sub>)<sub>2</sub>F<sub>2</sub> ∶ Eu<sup>2+</sup> Green Phosphors for White LEDs[J]. Chinese Journal of Luminescence, 2011,32(3): 256-261
丁唯嘉, 张梅, 王静, 苏锵. 白光LED用新型绿色荧光粉 Ca<sub>5</sub>(SiO<sub>4</sub>)<sub>2</sub>F<sub>2</sub> ∶ Eu<sup>2+</sup>的发光性能[J]. 发光学报, 2011,32(3): 256-261 DOI:
DING Wei-jia, ZHANG Mei, WANG Jing, SU Qiang. Luminescence Properties of New Ca<sub>5</sub>(SiO<sub>4</sub>)<sub>2</sub>F<sub>2</sub> ∶ Eu<sup>2+</sup> Green Phosphors for White LEDs[J]. Chinese Journal of Luminescence, 2011,32(3): 256-261 DOI:
采用高温固相法合成出系列绿色Ca
5-
x
Eu
x
(SiO
4
)
2
F
2
荧光粉
并对其发光特性进行了研究。Eu
2+
离子在Ca
5
(SiO
4
)
2
F
2
基质中可被250~440 nm光有效激发发出绿光
适合作为 UV-LED用绿色荧光粉。浓度猝灭实验结果表明
Eu
2+
离子的最佳掺杂摩尔分数为0.15
通过计算推测出Eu
2+
离子在Ca
5-
x
Eu
x
(SiO
4
)
2
F
2
中的能量转移机制应该为偶极-偶极相互作用。温度猝灭特性表明
450 K时的发射强度约为10 K时的35%。不同温度下Eu
2+
离子的荧光寿命结果表明
随着温度的不断升高
荧光寿命不断缩短。
paper
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